Search results for "COMPOSITI"

showing 10 items of 2775 documents

Identification of compounds responsible for the odorant properties of aromatic caramel

2012

Aromatic caramel results from the heat treatment of sugars under specific temperature conditions. Because of its richness in aroma compounds and its pleasant organoleptic properties, caramel is widely used in the food industry. However, the composition of the volatile odorant fraction has not been completely elucidated. The aim of this work was thus to identify the volatile odorant compounds responsible for caramel sensory properties using a multivariate statistical technique. Four aromatic caramels differing in terms of their carbohydrate composition and cooking process were chosen. Odorant compounds were screened by gas chromatography–olfactometry (GC-O) and identified by GC–mass spectrom…

ChromatographybiologyCooking processChemistryOrganolepticfood and beveragesGeneral Chemistrybiology.organism_classificationFrequency detectionPartial least squares regressionFood scienceMultivariate statisticalSugarCarbohydrate compositionAromaFood ScienceFlavour and Fragrance Journal
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Description of the Retention and Peak Profile for Chromolith Columns in Isocratic and Gradient Elution Using Mobile Phase Composition and Flow Rate a…

2014

The effect of the modifier concentration and flow rate on the chromatographic performance of a second generation Chromolith® RP-18e column, under isocratic and gradient elution with acetonitrile-water mixtures, was examined using four sulphonamides as probe compounds. The acetonitrile concentration was varied between 5 and 55% (v/v), and the flow rate between 0.1 and 5.0 mL/min, keeping the other factors constant. The changes in both retention and peak profile were modelled, and used to build simple plots, where the logarithm of the retention factor was represented against the modifier concentration (in gradient elution, against the initial modifier concentration), and the half-widths or wi…

Chromatographyflow programmingChemistryAnalytical chemistryGeneral MedicineReversed-phase chromatographyisocratic elutionFirst generationVolumetric flow ratelcsh:Chemistrymodellingchemistry.chemical_compoundreversed-phase liquid chromatographygradient elutionlcsh:QD1-999ChromolithPhase compositionInteraction kineticsGradient elutionAcetonitrileRetention timeChromatography
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Urban organic aerosol composition in Eastern China differs from North to South: Molecular insight from a liquid chromatography-Orbitrap mass spectrom…

2019

Particulate air pollution in China is influencing human health, ecosystem and climate. However, the chemical composition of particulate aerosol, especially of the organic fraction, is still not well understood. In this study, particulate aerosol samples with a diameter ≤ 2.5 μm (PM2.5) were collected in January 2014 in three cities located in Northeast, East and Southeast China, i.e., Changchun, Shanghai and Guangzhou, respectively. Organic aerosol (OA) in the PM2.5 samples was analyzed by ultrahigh performance liquid chromatography (UHPLC) coupled to high-resolution Orbitrap mass spectrometry in both negative mode (ESI−) and positive mode electrospray ioni…

ChromatographylawChemistryElectrospray ionizationCHONMass spectrumParticulatesMass spectrometryOrbitrapChemical compositionlaw.inventionAerosol
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Evaluation of Chemical Composition of Essential Oils Derived from Different Pelargonium Species Leaves

2019

Abstract Plants have been used for their aromatic and medicinal purposes for centuries. The genus Pelargonium contains about 250-280 species and cultivated around the world for the production of essential oils and absolutes. Pelargonium species are remarkable for their odour diversity, from fresh, lemon and minty scent, through floral, rose, fruity up to spicy and camphoreous smell as well as many health beneficial properties, that is why their essential oils are widely used in perfume, cosmetic, food and pharmaceutical industries. The aim of this study was to determine variability in populations of Pelargonium genus by evaluating their differences in quantitative and qualitative essential …

CitronellolPlant growthEnvironmental EngineeringbiologyPelargoniumbiology.organism_classificationlaw.inventionchemistry.chemical_compoundHorticulturechemistrylawEnvironmental ChemistryCultivarChemical compositionGenus PelargoniumEssential oilGeraniolEcological Chemistry and Engineering S
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Interdonato lemon from Nizza di Sicilia (Italy): chemical composition of hexane extract of lemon peel and histochemical investigation

2015

Considering that the determination of authenticity and of the geographical origin of food is a very challenging issue, in this study we studied by means of histological and histochemical analyses the famous Sicilian lemon known as ‘Interdonato Lemon of Messina PGI’. Since the protected geographical indication Interdonato lemon of Messina possesses high organoleptic properties, the composition of the hexane extract of lemon peel was determined by HRGC and HRGC–MS analyses and compared with that of lemon of different cultivars. The results obtained are informative of the oil’s quality and explain the variation of the lemon essential oil composition. Given the fundamental economic implications…

CitrusOrganolepticCitruPlant ScienceBiology01 natural sciencesBiochemistryEssential oillaw.inventionPlant ExtractAnalytical ChemistryFood sciencechemistry.chemical_compoundlawFood scienceLemon citruChemical compositionEssential oilInternational marketLemon peelHRGC–MS010405 organic chemistryPlant ExtractsHistocytochemistryHistochemical analyseOrganic ChemistryLemon citrus; HRGC–MS; essential oil; food science; histochemical analyses0104 chemical sciencesHexane010404 medicinal & biomolecular chemistryGeographical indicationchemistryGeographic origin
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Seasonal variations of antimicrobial activity and chemical composition of essential oils extracted from three Citrus limon L. Burm. cultivars

2014

In order to investigate the seasonal variations of antimicrobial properties and chemical composition of essential oils (EOs), three different cultivars of Citrus limon L. Burm. spp. (Femminello Santa Teresa, Monachello and Femminello Continella) were collected at 6-week intervals, from December 2012 to April 2013, for a total of four harvests. The EOs were extracted from lemon peel by hydro-distillation. The antimicrobial activity, tested by paper disc diffusion method, was evaluated against common food-related pathogenic bacteria (Listeria monocytogenes, Staphylococcus aureus, Salmonella enterica and Enterobacter spp.). EOs were more effective against Gram-positive than Gram-negative bacte…

CitrusStaphylococcus aureusfoodborne pathogenSettore AGR/13 - Chimica AgrariaEnterobacterMicrobial Sensitivity TestsPlant ScienceSettore MED/42 - Igiene Generale E Applicatamedicine.disease_causeBiochemistryessential oilGas Chromatography-Mass SpectrometryAnalytical Chemistryantibacterial activityAnti-Infective AgentsGram-Negative BacteriaBotanyOils Volatilemedicinechemical compositionCultivarChemical compositionbiologyseasonal variationsOrganic ChemistrySalmonella entericaPathogenic bacteriaEnterobacterAntimicrobialbiology.organism_classificationListeria monocytogenesSettore AGR/03 - Arboricoltura Generale E Coltivazioni ArboreeHorticulturelemon fruitItalyFruitSeasonsGas chromatographyGas chromatography–mass spectrometryAntibacterial activitySettore AGR/16 - Microbiologia Agraria
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The arithmetic decomposition of central Cantor sets

2018

Abstract Every central Cantor set of positive Lebesgue measure is the arithmetic sum of two central Cantor sets of Lebesgue measure zero. Under some mild condition this result can be strengthened by stating that the summands can be chosen to be C s regular if the initial set is of this class.

Class (set theory)Mathematics::Dynamical SystemsLebesgue measureApplied Mathematics010102 general mathematicsZero (complex analysis)Analysi02 engineering and technology01 natural sciencesCentral Cantor setCantor setCombinatoricsSet (abstract data type)Arithmetic progression0202 electrical engineering electronic engineering information engineeringDecomposition (computer science)Palis hypothesiArithmetic decomposition020201 artificial intelligence & image processing0101 mathematicsComputer Science::DatabasesAnalysisMathematicsJournal of Mathematical Analysis and Applications
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Indefinitely stable iron(IV) cage complexes formed in water by air oxidation

2017

In nature, iron, the fourth most abundant element of the Earth's crust, occurs in its stable forms either as the native metal or in its compounds in the +2 or +3 (low-valent) oxidation states. High-valent iron (+4, +5, +6) compounds are not formed spontaneously at ambient conditions, and the ones obtained synthetically appear to be unstable in polar organic solvents, especially aqueous solutions, and this is what limits their studies and use. Here we describe unprecedented iron(IV) hexahydrazide clathrochelate complexes that are assembled in alkaline aqueous media from iron(III) salts, oxalodihydrazide and formaldehyde in the course of a metal-templated reaction accompanied by air oxidation…

ClathrochelateScienceInorganic chemistryFormaldehydeSolid-stateGeneral Physics and Astronomy010402 general chemistryDFT01 natural sciencesArticleGeneral Biochemistry Genetics and Molecular BiologyInorganic Chemistrychemistry.chemical_compoundhigh-valent ironNative metalOorganisk kemiMultidisciplinaryAqueous solution010405 organic chemistryQGeneral ChemistryDecompositionCoordination chemistry3. Good health0104 chemical scienceschemistryCageEarth (classical element)Nature Communications
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The prognostic value of skeletal muscle index on clinical and survival outcomes after cytoreduction and HIPEC for peritoneal metastases from colorect…

2021

BACKGROUND Cytoreductive surgery (CRS) and hypertermic intraperitoneal chemotherapy (HIPEC) represent the most effective strategy to manage peritoneal metastases (PM). This systematic review and meta-analysis aimed to assess the impact of body composition on clinical outcomes in patients with PM. METHODS A systematic literature search was performed using Medline, Web of Science and EMBASE databases from inception to the 20st August 2020. Data were independently extracted by 3 authors. Newcastle-Ottawa Scale was used to assess quality and risk of bias of studies. Pooled analyses were performed using Mantel-Haenszel method to estimate overall effect size with mean differences or odd ratios (O…

Clinical nutritionSarcopeniamedicine.medical_specialtyColorectal cancerSettore MED/18 - CHIRURGIA GENERALEMEDLINESettore MED/49 - SCIENZE TECNICHE DIETETICHE APPLICATEHyperthermic Intraperitoneal ChemotherapyClinical nutritionBody compositionPostoperative ComplicationsClinical outcomesInternal medicineHumansMedicineProspective StudiesMuscle SkeletalPeritoneal NeoplasmsHIPECbusiness.industryPostoperative complicationSkeletal muscleCytoreduction Surgical ProceduresHyperthermia InducedGeneral MedicinePrognosismedicine.diseaseCombined Modality TherapyConfidence intervalSurvival RatePeritoneal metastasesmedicine.anatomical_structureOncologyMeta-analysisSarcopeniaSurgeryColorectal NeoplasmsbusinessEuropean Journal of Surgical Oncology
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A Feature Set Decomposition Method for the Construction of Multi-classifier Systems Trained with High-Dimensional Data

2013

Data mining for the discovery of novel, useful patterns, encounters obstacles when dealing with high-dimensional datasets, which have been documented as the "curse" of dimensionality. A strategy to deal with this issue is the decomposition of the input feature set to build a multi-classifier system. Standalone decomposition methods are rare and generally based on random selection. We propose a decomposition method which uses information theory tools to arrange input features into uncorrelated and relevant subsets. Experimental results show how this approach significantly outperforms three baseline decomposition methods, in terms of classification accuracy.

Clustering high-dimensional databusiness.industryComputer sciencePattern recognitionInformation theorycomputer.software_genreUncorrelatedDecomposition method (queueing theory)Data miningArtificial intelligencebusinessFeature setcomputerClassifier (UML)Curse of dimensionality
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