Search results for "CONDENSED MATTER"
showing 10 items of 13918 documents
On the discreet spectrum of fractional quantum hydrogen atom in two dimensions
2019
We consider a fractional generalization of two-dimensional (2D) quantum-mechanical Kepler problem corresponding to 2D hydrogen atom. Our main finding is that the solution for discreet spectrum exists only for $\mu>1$ (more specifically $1 < \mu \leq 2$, where $\mu=2$ corresponds to "ordinary" 2D hydrogenic problem), where $\mu$ is the L\'evy index. We show also that in fractional 2D hydrogen atom, the orbital momentum degeneracy is lifted so that its energy starts to depend not only on principal quantum number $n$ but also on orbital $m$. To solve the spectral problem, we pass to the momentum representation, where we apply the variational method. This permits to obtain approximate analytica…
Fabrication of a Silicide Thermoelectric Module Employing Fractional Factorial Design Principles
2021
AbstractThermoelectric modules can be used in waste heat harvesting, sensing, and cooling applications. Here, we report on the fabrication and performance of a four-leg module based on abundant silicide materials. While previously optimized Mg2Si0.3Sn0.675Bi0.025 is used as the n-type leg, we employ a fractional factorial design based on the Taguchi methods mapping out a four-dimensional parameter space among Mnx-εMoεSi1.75−δGeδ higher manganese silicide compositions for the p-type material. The module is assembled using a scalable fabrication process, using a Cu metallization layer and a Pb-based soldering paste. The maximum power output density of 53 μW cm–2 is achieved at a hot-side temp…
B–T phase diagram of Pd/Fe/Ir(111) computed with parallel tempering Monte Carlo
2017
We use an atomistic spin model derived from density functional theory calculations for the ultra-thin film Pd/Fe/Ir(111) to show that temperature induces coexisting non-zero skyrmion and antiskyrmion densities. We apply the parallel tempering Monte Carlo method in order to reliably compute thermodynamical quantities and the B-T phase diagram in the presence of frustrated exchange interactions. We evaluate the critical temperatures using the topological susceptibility. We show that the critical temperatures depend on the magnetic field in contrast to previous work. In total, we identify five phases: spin spiral, skyrmion lattice, ferromagnetic phase, intermediate region with finite topologic…
Characterizing and Quantifying Frustration in Quantum Many-Body Systems
2011
We present a general scheme for the study of frustration in quantum systems. We introduce a universal measure of frustration for arbitrary quantum systems and we relate it to a class of entanglement monotones via an exact inequality. If all the (pure) ground states of a given Hamiltonian saturate the inequality, then the system is said to be inequality saturating. We introduce sufficient conditions for a quantum spin system to be inequality saturating and confirm them with extensive numerical tests. These conditions provide a generalization to the quantum domain of the Toulouse criteria for classical frustration-free systems. The models satisfying these conditions can be reasonably identifi…
Triggering a transient organo-gelation system in a chemically active solvent
2021
A transient organo-gelation system with spatiotemporal dynamic properties is described. Here, the solvent actively controls a complex set of equilibria that underpin the dynamic assembly event. The observed metastability is due to the in situ formation of a secondary solvent, acting as an antagonist against the primary solvent of the organogel. peerReviewed
The adsorption of water vapor on super absorbent product at low temperatures and low mass.
2006
The adsorption isotherms of water vapor on super absorbent product have the same form of type III isotherm at ambient temperature with the hysteresis phenomena. For temperatures lower than ambient, the isotherms become deformed because of the chains effect. The polymer is characterized by a multilayer adsorption, which occurs before a full-course is complete. During adsorption reactions, the polymer undergoes rearrangement polymeric network, which results from a cooperative diffusion of the water molecules and from a chain spacing followed by an expansion of the polymeric network. Three types of water molecules adsorbed on polymer were identified: strongly dependent water, adsorbed water, a…
CO2-Based Non-ionic Surfactants: Solvent-Free Synthesis of Poly(ethylene glycol)-block-Poly(propylene carbonate) Block Copolymers
2013
Copolymerization of carbon dioxide (CO2) and propylene oxide (PO) is employed to generate amphiphilic polycarbonate block copolymers with a hydrophilic poly(ethylene glycol) (PEG) block and a nonpolar poly(propylene carbonate) (PPC) block. A series of poly(propylene carbonate) (PPC) di- and triblock copolymers, PPC-b-PEG and PPC-b-PEG-b-PPC, respectively, with narrow molecular weight distributions (PDIs in the range of 1.05–1.12) and tailored molecular weights (1500–4500 g mol−1) is synthesized via an alternating CO2/propylene oxide copolymerization, using PEG or mPEG as an initiator. Critical micelle concentrations (CMCs) are determined, ranging from 3 to 30 mg L−1. Non-ionic poly(propylen…
Optical and electrical properties of oriented thin films of oligomer containing betaine-type moiety in side chain
2005
Non-linear optical and electrical properties of polymer films obtained by dipole orientation of active units are reported. Novel polar oligomer with N-(indan-1,3-dion-2-yl)pyridinium betaine (IPB) as a side group is studied. Orientation of polar groups in oligomer thin films causes an increase of the photo-induced change of surface potential on irradiation in the region of photo-induced electron transfer (PIET) where the IPB group exhibits a reversible change of the value and sign of the dipole moment. At longer wavelengths, the value of the surface potential of the oligomer may be determined by transport of photogenerated charge carriers.
Estimation of the mechanical properties of the eye through the study of its vibrational modes.
2017
Measuring the eye's mechanical properties in vivo and with minimally invasive techniques can be the key for individualized solutions to a number of eye pathologies. The development of such techniques largely relies on a computational modelling of the eyeball and, it optimally requires the synergic interplay between experimentation and numerical simulation. In Astrophysics and Geophysics the remote measurement of structural properties of the systems of their realm is performed on the basis of (helio-)seismic techniques. As a biomechanical system, the eyeball possesses normal vibrational modes encompassing rich information about its structure and mechanical properties. However, the integral a…
Grain boundary ridges slow dawn grain boundary motion: In-situ observation
2014
Abstract The impact of grain boundary (GB) ridge on motion of high-angle GB in Zn was studied. The steady-state motion of faceted GB half-loop with [ 10 1 ¯ 0 ] tilt GB and GB ridge was recorded in-situ. The temperatures of faceting–roughening transition were experimentally defined for three GB half-loops. Above the transition temperature GB half-loops had GB “rough-to-rough” ridge with continuously curved GB segments. Below the transition temperature a facet appeared and coexisted with two “facet-to-rough” ridges. For the first time we could extract mobility of “rough-to-rough” and “rough-to-facet” ridges and bring out clearly that GB ridge slows down GB motion. Present removes contradicti…