The adsorption of water vapor on super absorbent product at low temperatures and low mass.

6533b852fe1ef96bd12aabda

RESEARCH PRODUCT

The adsorption of water vapor on super absorbent product at low temperatures and low mass.

M. Bakass J. P. Bellat Gary L. Bertrand A. Mokhlisse

subject

gel Polymers and Plastics Diffusion polymer vapor water 02 engineering and technology 010402 general chemistry 01 natural sciences Condensed Matter::Materials Science Adsorption Polymer chemistry Materials Chemistry Bound water Physics::Chemical Physics Water content Physics::Atmospheric and Oceanic Physics ComputingMilieux_MISCELLANEOUS chemistry.chemical_classification Quantitative Biology::Biomolecules Chemistry isotherm technology industry and agriculture super absorbent General Chemistry Polymer [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology Polyelectrolyte 0104 chemical sciences Surfaces Coatings and Films Condensed Matter::Soft Condensed Matter Hysteresis [ PHYS.PHYS.PHYS-CHEM-PH ] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Chemical engineering adsorption [ CHIM.MATE ] Chemical Sciences/Material chemistry [PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]isobar heat 0210 nano-technology Water vapor

description

The adsorption isotherms of water vapor on super absorbent product have the same form of type III isotherm at ambient temperature with the hysteresis phenomena. For temperatures lower than ambient, the isotherms become deformed because of the chains effect. The polymer is characterized by a multilayer adsorption, which occurs before a full-course is complete. During adsorption reactions, the polymer undergoes rearrangement polymeric network, which results from a cooperative diffusion of the water molecules and from a chain spacing followed by an expansion of the polymeric network. Three types of water molecules adsorbed on polymer were identified: strongly dependent water, adsorbed water, and the water only trapped between the macromolecular chains. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1450–1456, 2006

year	journal	country	edition	language
2006-01-01

https://hal.archives-ouvertes.fr/hal-00467546

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