Search results for "CONDENSED MATTER"
showing 10 items of 13918 documents
High content and dispersion of Gd in bimodal porous silica: T2 contrast agents under ultra-high magnetic fields
2022
Silica-based UVM-7-type bimodal mesoporous materials with high gadolinium content (∞ ≥ Si/Gd ≥ 13) have been synthesized through a one-pot surfactant-assisted procedure from hydroalcoholic solution using a cationic surfactant as template, and starting from atrane complexes of Gd and Si as inorganic precursors. The novel synthetic pathway developed in the study preserves the UVM-7-type architecture while optimizing the dispersion of the Gd-guest species at the nanoscale and even at atomic level. It has been determined that the number of Gd atoms forming clusters is always less than 10. The behaviour under exposure to ultra-high magnetic fields reveals a significant increase in the transversa…
Spin Wave Emission from Vortex Cores under Static Magnetic Bias Fields
2021
We studied the influence of a static in-plane magnetic field on the alternating-field-driven emission of nanoscale spin waves from magnetic vortex cores. Time-resolved scanning transmission X-ray microscopy was used to image spin waves in disk structures of synthetic ferrimagnets and single ferromagnetic layers. For both systems, it was found that an increasing magnetic bias field continuously displaces the wave-emitting vortex core from the center of the disk toward its edge without noticeably altering the spin-wave dispersion relation. In the case of the single-layer disk, an anisotropic lateral expansion of the core occurs at higher magnetic fields, which leads to a directional rather th…
Chiral Magneto-Electrochemistry
2018
Magneto-electrochemistry (MEC) is a unique paradigm in science, where electrochemical experiments are carried out as a function of an applied magnetic field, creating a new horizon of potential scientific interest and technological applications. Over time, detailed understanding of this research domain was developed to identify and rationalize the possible effects exerted by a magnetic field on the various microscopic processes occurring in an electrochemical system. Notably, until a few years ago, the role of spin was not taken into account in the field of magneto-electrochemistry. Remarkably, recent experimental studies reveal that electron transmission through chiral molecules is spin se…
Fragmentations and reactions of protonated O,O-dimethyl ethylphosphonate and some isotopomers produced by electrospray ionisation in an ion trap mass…
2008
Abstract The fragmentation behaviour of protonated O , O -dimethyl ethylphosphonate and its isotopomers deuterated in the α- and β-positions of the ethyl group and their fragment ions, particulary EtP(O)OMe + ( IV ), have been investigated both experimentally in an ion trap mass spectrometer and theoretically by electronic structure calculations at the B3LYP level. Of particular interest is the finding that the phosphonium ion IV eliminates ethene with hydrogen/deuterium loss from both the α-and β-positions. The initial step for both routes involves ethyl migration from P to O to form the ion MeOP + OEt which then loses ethene by two mechanisms, both of which lead to the same products. That…
The NEXT Project: Towards Production and Investigation of Neutron-Rich Heavy Nuclides
2022
The heaviest actinide elements are only accessible in accelerator-based experiments on a one-atom-at-a-time level. Usually, fusion–evaporation reactions are applied to reach these elements. However, access to the neutron-rich isotopes is limited. An alternative reaction mechanism to fusion–evaporation is multinucleon transfer, which features higher cross-sections. The main drawback of this technique is the wide angular distribution of the transfer products, which makes it challenging to catch and prepare them for precision measurements. To overcome this obstacle, we are building the NEXT experiment: a solenoid magnet is used to separate the different transfer products and to focus those of …
6-Amino-2-(pivaloylamino)pyridinium benzoate
2013
In the crystal structure of the title salt, C10H16N3O+·C7H5O2−, the cations and anions are linked to each other via N—H⋯O hydrogen bonds, forming infinite chains running along [010]. The crystal structure also features C—H⋯O and π–π stacking interactions, which assemble the chains into supramolecular layers parallel to (100). The π–π stacking interactions are observed between the pyridine rings of inversion-related cations with a centroid–centroid distance of 3.867 (2) Å. Financial support from the National Science Centre in Kraków (grant No. NCN204 356840) is gratefully acknowledged. Academy Professor Kari Rissanen (Academy of Finland grant Nos. 122350, 140718, 265328 and 263256) and th…
Rhombi-chain Bose-Hubbard model: Geometric frustration and interactions
2018
We explore the effects of geometric frustration within a one-dimensional Bose-Hubbard model using a chain of rhombi subject to a magnetic flux. The competition of tunnelling, self-interaction and magnetic flux gives rise to the emergence of a pair-superfluid (pair-Luttinger liquid) phase besides the more conventional Mott-insulator and superfluid (Luttinger liquid) phases. We compute the complete phase diagram of the model by identifying characteristic properties of the pair-Luttinger liquid phase such as pair correlation functions and structure factors and find that the pair-Luttinger liquid phase is very sensitive to changes away from perfect frustration (half-flux). We provide some propo…
Robustness of asymmetry and coherence of quantum states
2016
Quantum states may exhibit asymmetry with respect to the action of a given group. Such an asymmetry of states can be considered as a resource in applications such as quantum metrology, and it is a concept that encompasses quantum coherence as a special case. We introduce explicitly and study the robustness of asymmetry, a quantifier of asymmetry of states that we prove to have many attractive properties, including efficient numerical computability via semidefinite programming, and an operational interpretation in a channel discrimination context. We also introduce the notion of asymmetry witnesses, whose measurement in a laboratory detects the presence of asymmetry. We prove that properly c…
Analysis of a viscoelastic phase separation model
2020
A new model for viscoelastic phase separation is proposed, based on a systematically derived conservative two-fluid model. Dissipative effects are included by phenomenological viscoelastic terms. By construction, the model is consistent with the second law of thermodynamics, and we study well-posedness of the model, i.e., existence of weak solutions, a weak-strong uniqueness principle, and stability with respect to perturbations, which are proven by means of relative energy estimates. A good qualitative agreement with mesoscopic simulations is observed in numerical tests.
Random vibration mitigation of beams via tuned mass dampers with spring inertia effects
2019
The dynamics of beams equipped with tuned mass dampers is of considerable interest in engineering applications. Here, the purpose is to introduce a comprehensive framework to address the stochastic response of the system under stationary and non-stationary loads, considering inertia effects along the spring of every tuned mass damper applied to the beam. For this, the key step is to show that a tuned mass damper with spring inertia effects can be reverted to an equivalent external support, whose reaction force on the beam depends only on the deflection of the attachment point. On this basis, a generalized function approach provides closed analytical expressions for frequency and impulse res…