Search results for "CONDUCTIVITY"
showing 10 items of 1988 documents
Effect of Sheep Wool Fibers on Thermal Insulation and Mechanical Properties of Cement-Based Composites
2019
The use of sheep wool as a filler of cement in order to produce mortar or plaster involves several advantages for environment and energy. Moreover, it is considered as a waste and, therefore, its use is characterized by low cost. The aim of this paper is to evaluate the influence of wool fibers on thermal conductivity and mechanical properties of cement. The samples were prepared using wool fibers, obtained from a breed of Sicilian sheep, with three different lengths (i.e., 1, 6, and 20 mm). Furthermore, in order to evaluate the influence of fiber content, the samples were prepared by varying the fiber weight fraction. The thermal conductivity of the samples was analyzed by using a heat flo…
Hydration of tricalcium aluminate in the presence of various amounts of calcium sulphite hemihydrate : Conductivity tests.
2006
Abstract Hydration of calcium aluminate C3A (3CaO·Al2O3) in the presence of calcium sulphite hemihydrate (CaSO3·0.5H2O), with the molar ratio of substrates close to 1, produces the C3A·CaSO3·11H2O calcium monosulphite aluminate phase. Small amounts of calcium sulphite added to calcium aluminate (the ratio of CaSO3·0.5H2O / C3A equalling 0 : 1) change the rate of C3A hydration and influence the whole reaction. Reaction processes for various ratios of the C3A–CaSO3·0.5H2O mixture were examined in pure distilled water with a considerable amount of liquid W / S = 38–50 (constant W / C3A). Processes in the liquid phase were monitored with conductivity equipment, and the XRD analysis was used to …
Dye-sensitized nanostructured TiO2 film based photoconductor
2008
Grooves were etched in a conductive layer of a conductive, transparent glass, and a nanoporous TiO2 film was deposited on both the conductive and nonconductive area. The width of the grooves was 100 $\mu$m and 150 $\mu$m. A transparent TiO2 film was dye-sensitized, covered with an electrolyte, and sandwiched with a cover glass. The conductivity of the dye-sensitized TiO2 film permeated with electrolyte was studied in the dark and under illumination, and was observed to be dependent on light intensity, wavelength and applied voltage. This study shows that dye-sensitized nanoporous films can be used as a wavelength dependent photoconductor.
Ring diameter effects on determination of field-saturated hydraulic conductivity of different loam soils
2017
Abstract Establishing ring diameter effects on the field-saturated soil hydraulic conductivity, Kfs, determined with ponding infiltrometer methods can help to find a compromise between the need to sample a large area with an individual measurement and the impracticality of using large rings in the field. Five ring sizes (diameter, D = 5.5, 10.9, 16.0, 27.8 and 31.8 cm) were used to determine Kfs by the simplified falling head (SFH) technique in four loamy soils with different salinity (electrical conductivity of saturated extract, ECe = 0.9–29.4 dS/m) and sodicity (exchangeable sodium percentage, ESP = 2.7–81.3%) levels. According to USDA classification, two soils were non-saline, non-sodic…
Self-assembly in surfactant-based liquid mixtures: Bis(2-ethylhexyl)phosphoric acid/bis(2-ethylhexyl)amine systems
2010
Surfactant-based liquid mixtures constitute an interesting class of nanostructured materials with promising potential in specialized applications. Here, structural and conductometric properties of liquid mixtures composed of bis(2-ethylhexyl)amine (BEEA) and bis(2-ethylhexyl)phosphoric acid (HDEHP) have been thoroughly investigated with the aim to correlate structural features with system charge transport capability. The evolution of self-assembled local nanostructures with system composition has been investigated by FT-IR and XRD while the conductometric properties were probed by conventional AC complex impedance. Both pure components exhibit nano-segregation due to their amphiphilic natur…
Spark Plasma Sintering (SPS)-Assisted Synthesis and Thermoelectric Characterization of Magnéli Phase V6O11
2018
The Magneli phase V6O11 was synthesized in gram amounts from a powder mixture of V6O11/V7O13 and vanadium metal, using the spark plasma sintering (SPS) technique. Its structure was determined with synchrotron X-ray powder diffraction data from a phase-pure sample synthesized by conventional solid-state synthesis. A special feature of Magneli-type oxides is a combination of crystallographic shear and intrinsic disorder that leads to relatively low lattice thermal conductivities. SPS prepared V6O11 has a relatively low thermal conductivity of κ = 2.72 ± 0.06 W (m K)-1 while being a n-type conductor with an electrical conductivity of σ = 0.039 ± 0.005 (μΩ m)-1, a Seebeck coefficient of α = -(3…
Transport equations of electrodiffusion processes in the laboratory reference frame.
2006
The transport equations of electrodiffusion processes use three reference frames for defining the fluxes: Fick's reference in diffusion, solvent-fixed reference in transference numbers, and laboratory fluxes in electric conductivity. The convenience of using only one reference frame is analyzed here from the point of view of the thermodynamics of irreversible processes. A relation between the fluxes of ions and solvent and the electric current density is deduced first from a mass and volume balance. This is then used to show that (i) the laboratory and Fick's diffusion coefficients are identical and (ii) the transference numbers of both the solvent and the ion in the laboratory reference fr…
Structural relaxation in a molten salt probed by time-dependent dc conductivity measurements
1998
Abstract Time-dependent dc conductivity was measured after cooling steps of about 2 K in the glass transformation range of 2Ca(NO 3 ) 2 -3RbNO 3 . The shape and time scale of the structural relaxation function was thus monitored for times 60 s t 6 s. The time scale could be compared with results from scanning calorimetry measurements and good agreement was found. From the heat capacity data and from the solid state conductivity the expected liquid state conductivity relaxation time was calculated using several models. The good compatibility of these calculations with the experimental results provides evidence that near the calorimetric glass transition the mobile ions perform concerted moti…
Solution Synthesis of a New Thermoelectric Zn1-xSb Nanophase and Its Structure Determination Using Automated Electron Diffraction Tomography
2010
Engineering materials with specific physical properties have recently focused on the effect of nanoscopic inhomogeneities at the 10 nm scale. Such features are expected to scatter medium- and long-wavelength phonons thereby lowering the thermal conductivity of the system. Low thermal conductivity is a prerequisite for effective thermoelectric materials, and the challenge is to limit the transport of heat by phonons, without simultaneously decreasing charge transport. A solution-phase technique was devised for synthesis of thermoelectric "Zn(4)Sb(3)" nanocrystals as a precursor for phase segregation into ZnSb and a new Zn-Sb intermetallic phase, Zn(1+delta)Sb, in a peritectoid reaction. Our …
Transfer coefficients for the liquid–vapor interface of a two-component mixture
2011
Abstract We present the excess entropy production for heat and mass transport across an interface of a non-ideal two-component mixture, using as interface variables the excess densities proposed by Gibbs. With the help of these variables we define the interface as an autonomous system in local equilibrium and study its transport properties. The entropy production determines the conjugate fluxes and forces, and equivalent forms are given. The forms contain finite differences of intensive variables into and across the surface as driving forces. These expressions for the fluxes serve as boundary conditions for integration across heterogeneous systems that are far from global equilibrium. The r…