Search results for "COPP"

Multiple-scan voltammetry and OCP: Archaeometric tools for dating archaeological bronzes

2021

[EN] The application of a multiple-scan strategy to nanosamples taken from 18 cross-sections of Bronze Age arms and armour, as well as two Roman coins using two solid-state electrochemical techniques, the voltammetry of immobilized microparticles (VIMP) and open circuit potential measurements (OCP) is described. The voltammetric responses in contact with aqueous acetate buffer can be attributed to the reduction of cuprite with variable degree of compaction and crystallinity revealing significant differences in the gradient of such properties with depth. Such differences are also revealed by "dry" OCP measurements connecting points in the cross section near and separated from the corrosion l…

"Résumé de thèse, Le Forez du VIe au Ier millénaire av. J.-C. Territoires, identités et stratégies des sociétés humaines du Massif central dans le ba…

2009

Summary of thesis: Forez from the sixth to the first front millennium BC, Territories, identities and strategies of human societies in the upstream basin of the Loire (France) by Vincent GEORGES defended on 20th December 2007 at the University of Bourgogne; Joëlle Burnouf (reporter), Hervé Cubizolle (co-dir.), José Gomez de Soto (chair), Vincent Guichard (exam.), Claude Mordant (dir.), Pierre Pétrequin (reporter). This thesis is available online on www.tel.archives-ouvertes.fr.

New perspectives on the human occupation of the Gulf of Palermo during the Metal Ages: the funerary cave of Zubbio di Cozzo San Pietro (Bagheria) and…

2020

Abstract The Archaeological Superintendency of Palermo (Sicily), with the chair of Anthropology at the University of Palermo, carried out a preliminary investigation in the Zubbio of Cozzo San Pietro (Bagheria) – a cave known so far only from a speleological point of view - which proved to be a funerary cave dating to the Copper/Bronze Age. In the course of archaeological work during the installation of the electricity grid in the Mondello area (Palermo), part of a necropolis consisting of three oven-shaped tombs was exposed. The tombs multiple depositions, whose remains were found in a very bad state of preservation. Based on the type of funerary structures and the equipment found in them,…

Pressure-induced chemical decomposition of copper orthovanadate (α-Cu3V2O8)

2021

The high pressure stability of α-Cu3V2O8 has been investigated via complementary high pressure synchrotron X-ray diffraction experiments and theoretical density functional theory calculations. The results of both experiment and theory are in close agreement. The main result of this work is that α-Cu3V2O8 undergoes a pressure-induced chemical decomposition into CuO and V2O5 at a modest pressure of ∼1.35 GPa according to the experimental observations, and at ∼2.45 GPa according to the calculations. The decomposition is investigated with enthalpy calculations and one of the main driving factors is the stability of the octhedral oxygen-coordination of the metal atoms in the decompositon product…

Copper quality and provenance in Middle Bronze Age I Byblos and Tell Arqa (Lebanon)

2013

Shrinkage Bubbles: The C–O–H–S Magmatic Fluid System at San Cristóbal Volcano

2018

New analytical results for the composition of shrinkage bubbles (09-70 vol. %) in olivine-hosted (Fo <80%) primary melt inclusions (MIs) have been incorporated into a novel geochemical model for San Cristó bal volcano, Nicaragua. The vapour, liquid, and mineral components found inside shrinkage bubbles may represent relics of early C-O-H-S fluids exsolved from a magmatichydrothermal system. This conclusion is supported by high-resolution Raman microspectroscopy revealing: (1) gaseous CO2 (d=0·17-0·31 g/cm3 in 31 samples) coexisting with liquid H2O (in seven samples) at ambient temperature (<22°C) inside the shrinkage bubbles of naturally quenched inclusions; (2) several mineral phases (i.e.…

La coppia cogenitoriale

2019

Il rapporto fra cogenitori come coppia ha un impatto notevole, certamente, sulla crescita dei figli. Occorre, innanzitutto, ricordare che ogni figlio costituisce un essere unico che, pur condividendo con i fratelli una parte del patrimonio genetico, ha proprie caratteristiche distintive: dall’ordine di genitura al genere, dal fatto di nascere in un determinato periodo della vita della famiglia, alle particolari aspettative che tutti i membri della famiglia creano intorno alla sua esistenza (Aparo, 2018). Nel processo educativo, l’ascolto e la comprensione della propria reciproca storia e la condivisione di problemi e desideri con l’altro genitore può portare non solo ad una migliore comunic…

Influence of metal ions on thermal aggregation of bovine serum albumin: aggregation kinetics and structural changes

2009

Metal ions are implicated in protein aggregation processes of several neurodegenerative pathologies. In this work the effects of Cu(II) and Zn(II) ions on heat-induced structural modifications of bovine serum albumin (BSA) were studied, with the aim of delineating the role of these ions in the early stages of proteins aggregation kinetics. A joint application of different techniques was used. The aggregate growth was followed by dynamic light scattering measurements, whereas the conformational changes occurring in the protein structure were monitored by Raman and IR spectroscopy. Both in absence and in presence of metal ions, heating treatment gave rise to b-structures to the detriment of a…

Spectroscopic, crystal structural, theoretical and biological studies of phenylacetohydrazide Schiff base derivatives and their copper complexes

2020

Two phenylacetohydrazide Schiff base derivatives: N’-(1-(2-hydroxyphenyl)ethylidene)-2-phenylacetohydrazide, HL1, and N’-((1-hydroxynaphthalen-2-yl)methylene)-2-phenylacetohydrazide, HL2, were synthesized. HL1 dimerizes in presence of HCl, probably via radical mechanism to give (2,2’-((1E)-hydrazine-1,2-diylidenebis(ethan-1-yl-1-ylidene))diphenol (DIM). Thermal reactions of Cu(II) ions with the two Schiff base ligands resulted in formation of the binuclear complexes [(CuL1)2] and [(CuL2)2]. The stoichiometry and structures of the reported compounds were investigated by several spectroscopic and analytical techniques. The structure of the HL1 ligand and its complex [(CuL1)2] as well as the D…

Synthesis and studies of new optimised chelating agents for targeting chemokine receptor CXCR4

2012

The objective of this thesis work was to develop CXCR4-targeted tools to localize and treat cancer at an early stage. In this line, we investigated the synthesis of new target-specific radiopharmaceuticals. The work focused on two main axes, i.e. the chelating agent and the carrier, by using the know-how and the expertise of our group in polyazacycloalkanes synthesis and functionalization. In the first part, we were interested in developing new macrocyclic scaffolds of high potential for copper and gallium chelation. We first focused on the development of a new powerful route towards selectively functionalized constrained homocyclens. The second part was based on C-functionalized 1,4,7-tria…