Search results for "CORROSION"
showing 10 items of 456 documents
Corrosion protection of Nd–Fe–B type permanent magnets by zinc phosphate surface conversion coatings
2001
Abstract The use of protective zinc phosphate top coatings to protect Nd–Fe–B type permanent magnets against corrosion is discussed. The progress of the phosphatisation process has been tested by simultaneous measurement of pH near surface, corrosion potential, substrate mass loss and phosphate coating mass gain. The corrosion behaviour of the magnet in phosphate solution was analyzed by the anodic polarization technique and the general resistance of the magnet to corrosion was evaluated by the Akimov drop test. It is shown that immersion of the magnet in the acidified (pH=2) phosphating solution containing Zn(II), nitrate and fluoride ions resulted in the formation of well adhered, thin an…
Electrochemical behavior of nanocrystalline iron aluminide obtained by mechanically activated field activated pressure assisted synthesis
2004
Abstract The corrosion behavior of nanocrystalline iron aluminide obtained by mechanically activated field—activated pressure—assisted synthesis was investigated in sulphuric acid media using potentiodynamic curves. The effect of microstructure on the electrochemical corrosion resistance was investigated by examining samples which were heat treated to effect a change in crystallite size and microdistorsion.
Elaboration of Nickel Aluminide Diffusion Coatings: Application to Oxidation Resistance
2008
Aluminide diffusion coatings are widely used in aeronautic domain. Nickel based superalloys present good mechanical properties and creep resistance at high temperature but their corrosion resistance is somewhat poor. In order to enhance their lifetime at high temperature, aluminide coatings can be applied on alloy surface. Aluminium present on material surface can form, at high temperature, alumina scale which is a protective oxide scale. In the present study, nickel aluminide coatings were carried out by aluminisation in a single step pack cementation process on nickel based superalloys 600 and AM1. Ni-Al intermetallic was obtained in each case. Oxidation tests were carried out at 900°C in…
Sintered (Nd, Tb)–(Fe, Ti)–B+C permanent magnets
2001
Abstract This paper undertakes a study of the effect of carbon addition on the magnetic properties, the microstructure and corrosion resistance of Nd14.60Tb0.20Fe77.56Ti1.24B6.40+C sintered permanent magnets. It is shown that a 0.12 wt.% C addition increase the remanence and the maximum energy product and reduces (slightly) the intrinsic coercivity. The corrosion resistance in atmospheric environment is also significantly improved by this element.
A Grain-Scale Model of Inter-Granular Stress Corrosion Cracking in Polycrystals
2017
In this contribution, we propose a cohesive grain-boundary model for hydrogen-assisted inter-granular stress corrosion cracking at the grain-scale in 3D polycrystalline aggregates. The inter-granular strength is degraded by the presence of hydrogen and this is accounted for by employing traction-separation laws directly depending on hydrogen concentration, whose diffusion is represented at this stage through simplified phenomenological relationships. The main feature of the model is that all the relevant mechanical fields are represented in terms of grain-boundary variables only, which couples particularly well with the employment of traction-separation laws.
Texture Effects on Zircaloy Oxidation : Experiment and Simulation
2002
Mechanical properties and corrosion behaviour of low carbon martensitic stainless steel after machining
2014
The influence of different combinations of cutting conditions on the mechanical behaviour (microhardness), the microstructure and the corrosion behaviour in NaCl solution (using the electrochemical microcell technique and pulse potentiodynamic testing) of a low carbon martensitic stainless steel (grade X4CrNiMo16.5.1 stainless steel) after tempering treatment was studied. Microhardness was increased on the machined surface. In addition, the electrochemical experiments have shown that the machined materials have a heterogeneous electrochemical behaviour. Significant effect of machining on pitting corrosion was noticed. The pitting potential was found to decrease as the microhardness increase…
A microstructural model for homogenisation and cracking of piezoelectric polycrystals
2019
Abstract An original three-dimensional generalised micro-electro-mechanical model for computational homogenisation and analysis of degradation and micro-cracking of piezoelectric polycrystalline materials is proposed in this study. The model is developed starting from a generalised electro-mechanical boundary integral representation of the micro-structural problem for the individual bulk grains and a generalised cohesive formulation is employed for studying intergranular micro-damage initiation and evolution into intergranular micro-cracks. To capture the electro-mechanical coupling at the evolving damaging intergranular interfaces, standard mechanical cohesive laws are enriched with suitab…
Early-stage detection of surface stress corrosion cracking at the subgranular level
2014
The strain field at the interface between an alloy and its oxide layer has been mapped using nanopatterned gauges resistant to the environment of the primary nuclear medium. It was found that oxidation has decreased the alloy ductility, thereby enabling some grain boundary opening to be detectable from 1.8 % strain. It is shown that statistics of extreme rare events of hotspots quantify the occurrence of the local opening of intergranular cracks, and thereby the ageing process.