Search results for "CURVE"

Application of ultra-high pressure liquid chromatography linear ion-trap orbitrap to qualitative and quantitative assessment of pesticide residues

2014

Abstract The analysis of pesticides residues using a last generation high resolution and high mass accuracy hybrid linear ion trap-Orbitrap mass spectrometer (LTQ-Orbitrap-MS) was explored. Pesticides were extracted from fruits, fish, bees and sediments by QuEChERS and from water by solid-phase with Oasis HLB cartridges. Ultra-high pressure liquid chromatography (UHPLC)–LTQ-Orbitrap mass spectrometer acquired full scan MS data for quantification, and data dependent (dd) MS 2 and MS 3 product ion spectra for identification and/or confirmation. The regression coefficients ( r 2 ) for the calibration curves (two order of magnitude up to the lowest calibration level) in the study were ≥0.99. Th…

Science based calibration for the extraction of 'analyte-specific' HPLC-DAD chromatograms in environmental analysis

2010

Multivariate science based calibration (SBC) has been applied to the resolution of overlapped peaks in liquid chromatography with diode array detection (LC-DAD). Complex river water samples spiked with 11 pharmaceutical substances resulted in poorly resolved chromatograms containing additional peaks from interfering matrix compounds and a change in the background absorbance due to the mobile phase gradient. Applying the present multivariate approach it was possible to resolve all 11 analytes from overlapping peaks, obtaining linear calibration lines (R2 > 0.96). Recovery percentages on spiked samples ranged between 74.6 and 113.5%, which are quite satisfactory taking into account the low co…

Immuno-SLM—a combined sample handling and analytical technique

2004

Immuno-supported liquid membrane (immuno-SLM) extraction is a new technique that makes use of antibody (Ab)-antigen interactions as the "extraction force" to drive the mass transfer in a selective way. In immuno-SLM, anti-analyte (Ag) Abs are introduced into the acceptor phase of the SLM unit to trap the Ag that passes from the flowing donor through the SLM into the stagnant acceptor. The amount of immuno-extracted analyte (AbAg) is quantified by connecting the immuno-SLM unit on-line with a non-competitive heterogeneous fluorescence flow immunoassay (FFIA) that makes use of a fluorescein-labeled analyte tracer that titrates the residual excess of Ab present in the acceptor. A restricted ac…

On Weakly Singular Integral Equations of the Second Kind

1988

The factorization method for real elliptic problems

2006

The Factorization Method localizes inclusions inside a body from mea- surements on its surface. Without a priori knowing the physical parameters inside the inclusions, the points belonging to them can be characterized using the range of an auxiliary operator. The method relies on a range characterization that relates the range of the auxiliary operator to the measurements and is only known for very particular applications. In this work we develop a general framework for the method by considering sym- metric and coercive operators between abstract Hilbert spaces. We show that the important range characterization holds if the difference between the inclusions and the background medium satisfi…

On a global superconvergence of the gradient of linear triangular elements

1987

Abstract We study a simple superconvergent scheme which recovers the gradient when solving a second-order elliptic problem in the plane by the usual linear elements. The recovered gradient globally approximates the true gradient even by one order of accuracy higher in the L 2 -norm than the piecewise constant gradient of the Ritz—Galerkin solution. A superconvergent approximation to the boundary flux is presented as well.

Computation of a few smallest eigenvalues of elliptic operators using fast elliptic solvers

2001

The computation of a few smallest eigenvalues of generalized algebraic eigenvalue problems is studied. The considered problems are obtained by discretizing self-adjoint second-order elliptic partial differential eigenvalue problems in two- or three-dimensional domains. The standard Lanczos algorithm with the complete orthogonalization is used to compute some eigenvalues of the inverted eigenvalue problem. Under suitable assumptions, the number of Lanczos iterations is shown to be independent of the problem size. The arising linear problems are solved using some standard fast elliptic solver. Numerical experiments demonstrate that the inverted problem is much easier to solve with the Lanczos…

Our Friend and Mathematician Karl Strambach

2020

This paper is dedicated to Karl Strambach on the occasion of his 80th birthday. Here we want to describe our work with Prof. Karl Strambach.

Real-time clothoid approximation by Rational Bezier curves

2008

This paper presents a novel technique for implementing Clothoidal real-time paths for mobile robots. As first step, rational Bezier curves are obtained as approximation of the Fresnel integrals. By rescaling, rotating and translating the previously computed RBC, an on-line Clothoidal path is obtained. In this process, coefficients, weights and control points are kept invariant. This on-line approach guarantees that an RBC has the same behavior as the original Clothoid using a low curve order. The resulting Clothoidal path allows any two arbitrary poses to be joined in a plane. RBCs working as Clothoids are also used to search for the shortest bounded-curvature path with a significant comput…

Mark-Houwink Parameters of Biosynthetic Poly(γ-glutamic acid) in Aqueous Solution

2001

A combined viscosity–light scattering–gel permeation chromatography (GPC) study was carried out on bacterially produced poly(γ-glutamic acid) (PGGA). PGGA samples with weight-average molecular weights ranging from 8×104 up to 8×105 g·mol–1 dissolved in phosphate buffer at 0.13 M ionic strength were used. It was found that the Mark–Houwink relation is acceptably obeyed, giving K and a values of 1.84×10–6 dL·g–1 and 1.16, respectively. As expected, GPC analysis showed that PGGA does not follow the universal calibration plot and that deviations can not be avoided by modifying the ionic strength.