Search results for "Caesium"
showing 10 items of 63 documents
Imaging connected porosity of crystalline rock by contrast agent-aided X-ray microtomography and scanning electron microscopy
2017
We set out to study connected porosity of crystalline rock using X-ray microtomography and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) with caesium chloride as a contrast agent. Caesium is an important radionuclide regarding the final deposition of nuclear waste and also forms dense phases that can be readily distinguished by X-ray microtomography and SEM-EDS. Six samples from two sites, Olkiluoto (Finland) and Grimsel (Switzerland), where transport properties of crystalline rock are being studied in situ, were investigated using X-ray microtomography and SEM-EDS. The samples were imaged with X-ray microtomography, immersed in a saturated caesium chlorid…
Pyrogallarenes as alkali metal receptors: the role of cation-pi interactions in complexation.
2006
Crystallization studies of C-methyl pyrogallarene with potassium, rubidium and caesium bromides or chlorides resulted in a hydrogen bonded molecular cage in which the alkali metal cations are eta6 coordinated to aromatic rings via strong cation-pi interactions.
Validating the use of caesium-137 measurements to estimate soil erosion rates in a small drainage basin in Calabria, Southern Italy
2001
Recent concern for problems of soil degradation and the offsite impacts of accelerated erosion has highlighted the need for improved methods of estimating rates and patterns of soil erosion by water. The use of environmental radionuclides, particularly caesium-137 (137Cs), as a means of estimating rates of soil erosion and deposition is attracting increasing attention and the approach has now been recognised as possessing several important advantages. However, one important uncertainty associated with the use of 137Cs measurements to estimate soil erosion rates is the need to employ a calibration relationship to convert the measured 137Cs inventory to an estimate of the erosion rate. Existi…
Validating erosion rate estimates provided by caesium-137 measurements for two small forested catchments in Calabria, southern Italy
2003
Increasing concern for problems of soil degradation and the off-site impacts of accelerated erosion has generated a need for improved methods of estimating rates and patterns of soil erosion by water. The use of environmental radionuclides, particularly 137 Cs, to estimate erosion rates has attracted increased attention and the approach has been shown to possess several important advantages. However, the use of 137 Cs measurements to estimate erosion rates introduces one important uncertainty, namely, the need to employ a conversion model or relationship to convert the measured reduction in the 137 Cs inventory to an estimate of the erosion rate. There have been few attempts to validate the…
Assessing soil erosion in a small Sicilian basin by caesium-137 measurements and a simplified mass balance model
2000
Abstract The caesium-137 technique affords both an alternative to conventional measurement methods and an effective quantitative estimate of soil redistribution at the basin scale. Among the available calibration relationships which link the degree of increase or depletion of the 137Cs activity relative to the baseline 137Cs input and sediment yield, the mass balance approach has received increased application for its physical basis. First, the applicability of the refined simplified point-based mass balance (RSPMB) model of Zhang et al. (1999) at the scale of the morphological unit is proposed herein. The 137Cs spatial distribution measured in a small Sicilian basin and the spatial distrib…
Efficient Vacuum-Deposited Perovskite Solar Cells with Stable Cubic FA 1– x MA x PbI 3
2020
Preparation of black formamidinium lead iodide (FAPbI3) requires high temperature annealing and the incorporation of smaller A-site cations, such as methylammonium (MA+), cesium or rubidium. A major advantage of vacuum processing is the possibility to deposit perovskite films at room temperature (RT), without any annealing step. Here we demonstrate stabilization of the cubic perovskite phase at RT, in a three-sources co-sublimation method. We found that the MA+ incorporation is a self-limiting process, where the amount of MA+ which is incorporated in the perovskite is essentially unvaried with increasing MAI deposition rate. In this way a phase-pure, cubic perovskite with a bandgap of 1.53 …
Collinear Laser Spectroscopy on Fast Atomic Beams
1978
In collinear geometry we have observed laser-excited, narrow resonances in fast beams of Na and Cs atoms obtained from ion beams by charge transfer collisions. Being very sensitive, the method is suited for measuring isotope shifts and hyperfine structure of isotopes far from stability provided by on-line mass separators. It may be used furthermore to study inelastic charge transfer from the energy-loss spectrum of the Doppler-shifted lines.
Ultrathin lead bromide perovskite platelets spotted with europium(ii) bromide dots
2019
We describe here the preparation of a novel nanohybrid comprising a two-layer cesium lead bromide nanoplatelet, [CsPbBr3]PbBr4 NPL, containing europium(II) bromide (EuBr2) nanodots, by ultrasound/heating treatment of toluene dispersions of the CsPbBr3 nanomaterial in the presence of EuBr2 nanodots. The hybrid nanoplatelets exhibit strong excitonic and narrow emission peaks characteristic of ultrathin NPLs at 430 and 436 nm, respectively.
Solvent-Free Synthesis and Thin-Film Deposition of Cesium Copper Halides with Bright Blue Photoluminescence
2019
Non-toxic alternatives to lead halide perovskites are highly sought after for applications in optoelectronics. Blue-luminescent materials are especially demanded as they could be used to prepare white light-emitting diodes, with important potential applications in lighting systems. However, wide bandgap blue emitters with high photoluminescence quantum yields (PLQY) are typically more difficult to obtain as compared to green- or red-emitting ones. Here, we prepared two series of inorganic cesium copper halides, with the general formulas Cs3Cu2X5 and CsCu2X3 (X = Cl, Br, I, and mixtures thereof) by dry mechanochemical synthesis at room temperature. X-ray diffraction demonstrates quantitative…
Room temperature vacuum-deposition of CsPbI2Br perovskite films from multiple-sources and mixed halide precursors
2020
Fully inorganic cesium lead halide perovskites, such as CsPbI2Br, show enhanced thermal stability compared to hybrid ones and are being widely investigated as wide bandgap absorbers for tandem applications. Despite their simple stoichiometry, the preparation of highly crystalline and stable cesium lead halide thin films is not trivial. In general, high-efficiency solar cells based on solution-processed CsPbI2Br thin films are prepared by hightemperature annealing or the use of chemical additives. In this work, we use solvent-free synthesis to investigate the formation of CsPbI2Br in bulk or in thin films via mechanochemical synthesis and multiple-source vacuum deposition, respectively. We d…