Search results for "Capacity"
showing 10 items of 999 documents
Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metal–organic frameworks
2016
Two series of fluorine-containing UiO-66 have been synthesized, replacing the 1,4-benzodicarboxylic acid linker with increasing amounts of 2-fluoro-1,4-benzodicarboxylic acid or 2-trifluoromethyl-1,4-benzodicarboxylic acid. The capacity to store oxygen and nitrogen within these MOFs has been tested, which revealed a positive correlation between the fluorine content and the oxygen storage performances.
Increasing the shear capacity of reinforced concrete beams using pretensioned stainless steel ribbons
2017
In this work, the second part of an experimental campaign investigating the efficiency of an alternative retrofitting method for increasing the flexural and/or shear capacity in reinforced concrete beams, based on the use of prestressed stainless steel ribbons and steel angles, is presented and analytically reproduced. This group of tests focuses on the ability of the adopted retrofitting method to improve the shear strength and ultimate deformation of reinforced concrete structural elements. As described in a companion paper, the adopted retrofitting method is alternative to traditional techniques of reinforced concrete retrofitting, being easy to install and usually reversible, and charac…
Bearing strength and failure behavior of pinned hybrid glass-flax composite laminates
2018
Abstract The aim of the present work is to evaluate the influence of external layers of glass woven fabric on the pin-hole strength of flax/epoxy laminates. Single lap bearing tests were carried out to evaluate the fastened joint performances depending on laminate stacking sequence. In order to better identify the mechanical behavior of the hybrid laminate, full glass and flax laminates were also compared. In particular, bearing stress and failure mechanisms were investigated at varying joint geometry. Furthermore, an experimental failure map, clustering main failure modes of pinned hybrid composite laminate, was used to better clarify the relationship between mechanical failure and geometr…
Masonry columns confined with fabric reinforced cementitious matrix (FRCM) systems: A round robin test
2021
Abstract The conservation and the preservation of existing masonry buildings, most of them recognized as cultural heritage, require retrofitting techniques that should reduce the invasiveness and assure reversibility and compatibility with the substrate. In this perspective, the strengthening system should be able to improve the bearing capacity of the structural member and, at the same time, to assure mechanical and material compatibility. The use of Fabric Reinforced Cementitious Matrix (FRCM) composites is now recognized to be suitable for these purposes. Indeed, the inorganic matrix has comparable properties with respect to the existing historical mortars while the fabric has relevant t…
Heat-capacity anomaly due to spin reorientation and thermodynamic functions of ErFeO3 and TmFeO3
2001
Abstract Heat capacities of orthoferrites, ErFeO 3 and TmFeO 3 , have been measured below room temperature by adiabatic calorimetry. A broad but definite anomaly due to the spin reorientation phenomenon was successfully detected in the expected temperature range (ca. 90 K). The results are compared with a vast anomaly reported for YbFeO 3 . The temperature dependence of the electric quadrupole splitting of the Fe nuclear levels was determined by Mossbauer spectroscopy through the spin reorientation. A heat capacity anomaly centered at 3.60 K due to the magnetic ordering of Er 3+ ions was clearly detected. Some Schottky anomalies were resolved and energy splittings involved were roughly esti…
High-performance of PbO2 nanowire electrodes for lead-acid battery
2014
Abstract PbO2 nanowires were obtained by template electrodeposition in polycarbonate membranes and tested as positive electrode for lead-acid battery. Nanowires were grown on the same material acting as current collector that was electrodeposited too. The nanostructured electrodes were assembled in a zero-gap configuration using commercial negative plate and separator. Cell performance was tested by galvanostatic charge/discharge cycles in a 5 M H2SO4 aqueous electrolyte. PbO2 nanostructured electrodes were able to deliver at 1C rate an almost constant capacity of about 190 mAh g−1 (85% of active material utilization), close to the theoretical value (224 mAh g−1). The nanowire array provide…
First-principles comparative study of perfect and defective CsPbX3 (X = Br, I) crystals
2020
We thank R. Merkle for numerous fruitful discussions and G. Siegle for experimental assistance. This study was partly supported by the M-ERA-NET project SunToChem (EK). Calculations were performed using computational facilities of St. Petersburg State University and Max Planck Institute for Solid State Research. Open Access funding provided by the Max Planck Society.
Exploring High-Energy Li-I(r)on Batteries and Capacitors with Conversion-Type Fe3O4-rGO as the Negative Electrode
2017
We report a microwave-assisted solvothermal process for the preparation of magnetite (Fe3O4, ca. 5 nm)-anchored reduced graphene oxide (rGO). It has been examined as a prospective conversion-type negative electrode for multiple energy storage applications, such as Li-ion batteries (LIBs) and Li-ion capacitors (LICs). A LiFePO4/Fe3O4-rGO cell is constructed and capable of delivering an energy density of approximately 139 Wh kg−1 with a notable cyclability (ca. 76 %) after 500 cycles. Prior to the fabrication of a LIB, the Fe3O4-rGO is electrochemically pretreated to eliminate the irreversible capacity loss. In addition to the LIB, a high-energy LIC is also fabricated by using the pre-lithiat…
Shear Capacity Model with Variable Orientation of Concrete Stress Field for RC Beams Strengthened by FRP with Different Inclinations
2021
A design-oriented analytical model able to evaluate the shear capacity of reinforced concrete (RC) beams strengthened with fiber-reinforced polymer (FRP) sheets or strips oriented in any direction is proposed. The formulation of the model is based on the variable-inclination stress-field approach, aiming to extend the provisions of current European standards to beams strengthened in shear using FRP. The main novelty of the model lies in taking into account the possible different inclination of steel stirrup and FRP reinforcement in determining the orientation of a compressed concrete stress field, and in shear strength evaluation, overcoming the approximation of the known models with variab…
Thermal and elastic properties of poly(vinyl chloride) (PVC) + chlorinated polyethylene (CPE) blends
2003
Eight types of PVC + CPE blends with different weight ratios (PVC/CPE = 100/0, 90/10, 80/20, 60/40, 40/60, 20/80, 10/90, and 0/100) are tested. Data on the heat conductivity, thermal diffusivity, and heat capacity of the blends investigated are reported. Primary attention is paid to the structural approach for effective elastic constants: bulk, shear, and Young's modulae. The blends are considered as random mixtures of two isotropic constituents. It is found that the elastic moduli may be well represented by the Kerner and Budiansky equations.