Search results for "Carboni"
showing 10 items of 357 documents
Thermodynamic parameters of the interaction between Co(II) bovine carbonic anhydrase and anionic inhibitors
1992
The pH dependence of the apparent affinity constants of perchlorate for cobalt(II)bovine carbonic anhydrase II has been measured by electronic absorption spectroscopy. The obtained data have been analyzed in terms of the ionization of two acidic groups of CoBCAII, and the affinity of perchlorate for the two water-containing species of the enzyme have been estimated. Furthermore, the affinity constants of nitrate, perchlorate, and azide for CoBCAII in the temperature range 5 degrees C-30 degrees C have been determined by spectrophotometric titrations at pH 7. The affinity constants for these ligands decrease with increasing temperatures. The temperature dependence of binding was used to esti…
Scheelite-Bearing Metalliferous Sequences of the Peloritani Mountains, Northeastern Sicily (with some Remarks on Tungsten Metallogenesis in the Calab…
1988
The Peloritani Mountains (Northeastern Sicily) are part of a segment of the Hercynian chain recognized in the Calabrian-Peloritan Arc, geotectonically defined by a pre-Hercynian crystalline basement (Aspromonte Nappe + Mandanici Unit) overthrust and overturned on its Paleozoic (Cambro-Ordovician up to Devonian Carboniferous) volcanosedimentary cover. Tungsten (scheelite) and associated polymetallic stratabound ores, more or less intensely affected by the pre-Hercynian and Hercynian tectonometamorphic events, are confined to the pre-Hercynian basement. In particular, the most significant scheelite-tourmaline (arsenopyrite) and scheelite-carbonate-quartz (albite) mineralizations could be cons…
Ediacaran, Early Ordovician and early Silurian arcs in the South Tianshan orogen of Kyrgyzstan
2020
Abstract The oldest magmatic rocks from the South Tianshan orogen of Kyrgyzstan (STS) are important for better understanding of the Neoproterozoic and early Palaeozoic evolution of the southwestern Central Asian Orogenic Belt. Bulk rock major and trace element and Sm-Nd isotopic composition and zircon U-Pb ages of granitoids from melange blocks reveal two previously unknown episodes of arc magmatism in the STS orogen of Kyrgyzstan, namely, the Ediacaran (ca. 624 Ma) and Early Ordovician (ca. 472 Ma) episodes. Moderately positive ɛNd(t) value of + 5.8 of the Ediacaran granodiorite indicates a mainly juvenile source for this rock. Negative ɛNd(t) value of −9.1 for the Early Ordovician granodi…
Cropland and grassland management
2014
According to the latest National Inventory, the Italian agricultural sector is a source of GHGs with 34.5 Mt of CO2 eq in 2009, corresponding to 7 % of the total emissions (excluding LULUCF). In particular, more than half (19.1 Mt of CO2 eq) are N2O emissions from soils. Although the national methodology is in accordance with Tier 1 and 2 approaches proposed by the IPCC (2006), still empirical emission factors are used to assess the emission from fertilizer (e.g. 0.0125 kg N2O–N kg−1 N from synthetic fertilizers). Disaggregated data at sub-national level, including models and inventory measurement systems required by higher order methods (i.e. Tier 3), are not available in Italy so far and …
The role of vineyards in the carbon balance throughout Italy
2015
A common belief is that agricultural fields cannot be net carbon sinks, but perennial tree crops, growing a permanent woody structure with a life cycle of decades could act as carbon sink. Vineyards are good candidates to test this hypothesis, because they are often grown with limited soil cultivation and produce plenty of woody pruning material that can be left on the ground. Three Eddy Covariance sites were established in different vineyards, along a north-south transect, in Italy, to study the role of vine cultivation in the carbon balance of the Italian penisula. The year 2009 was chosen as a reference year for the three sites, in order to compare carbon budget estimates in areas charac…
Adaptive Materials Research for Architecture
2018
The volume "Adaptive Materials Research for Architecture" is a Special Issue of the journal "Advanced Material Research". The goal of this volume is to spread knowledge on studies, analyses and results of scientific research carried out from academics, researchers, and scientists regarding the soundest issues related to smart materials, innovative technologies and ongoing researches in the field of adaptive materials in past and current architectural practice.
Expression Patterns and Subcellular Localization of Carbonic Anhydrases Are Developmentally Regulated during Tooth Formation
2014
Abstract Carbonic anhydrases (CAs) play fundamental roles in several physiological events, and emerging evidence points at their involvement in an array of disorders, including cancer. The expression of CAs in the different cells of teeth is unknown, let alone their expression patterns during odontogenesis. As a first step towards understanding the role of CAs during odontogenesis, we used immunohistochemistry, histochemistry and in situ hybridization to reveal hitherto unknown dynamic distribution patterns of eight CAs in mice. The most salient findings include expression of CAII/Car2 not only in maturation-stage ameloblasts (MA) but also in the papillary layer, dental papilla mesenchyme, …
The evolution of metazoan α-carbonic anhydrases and their roles in calcium carbonate biomineralization
2014
The carbonic anhydrase (CA; EC 4.2.1.1) superfamily is a class of ubiquitous metallo-enzymes that catalyse the reversible hydration of carbon dioxide. The ?-CA family, present in all metazoan clades, is a key enzyme involved in a wide range of physiological functions including pH regulation, respiration, photosynthesis, and biocalcification. This paper reviews the evolution of the ?-CA family, with an emphasis on metazoan ?-CA members involved in biocalcification. Phylogenetic analyses reveal a complex evolutionary history of ?-CAs, and suggest ?-CA was independently co-opted into a variety of skeleton forming roles (e.g. as a provider of HCO3? ions, a structural protein, a nucleation activ…
Minireview: pH and synaptic transmission
2013
AbstractAs a general rule a rise in pH increases neuronal activity, whereas it is dampened by a fall of pH. Neuronal activity per se also challenges pH homeostasis by the increase of metabolic acid equivalents. Moreover, the negative membrane potential of neurons promotes the intracellular accumulation of protons. Synaptic key players such as glutamate receptors or voltage-gated calcium channels show strong pH dependence and effects of pH gradients on synaptic processes are well known. However, the processes and mechanisms that allow controlling the pH in synaptic structures and how these mechanisms contribute to normal synaptic function are only beginning to be resolved.
On site consolidation of burnt and partially charred wood in dry conditions
2011
Abstract Forty years ago in a xx th-century church in Torino, a small fire partially burned some of the decorative external boards of the sound-box of the organ. The focus of this present work was to find a treatment able to consolidate partially burnt wood in dry conditions, in which the external charred layer would be lost if not well preserved because of its incoherence. The product had to be applied onsite on an architectural structure intended to be reused again (and not simply exhibited). This circumstance is rarely encountered in the conservation of wooden Cultural Heritage. The efficacy of treatments was evaluated on the basis of a suitable and original experimental methodology, whi…