Search results for "Ceramic"
showing 10 items of 2129 documents
OH-related Infrared Absorption Bands in Oxide Glasses
2005
We report the infrared activity, in the spectral region of the OH stretching modes, of different composite silicate glasses whose chemical composition is established by X-ray fluorescence measurements. The analysis of the absorption line profiles is made in terms of different spectral contributions, Gaussian in shape. The comparison with analogous spectra obtained in vitreous silica samples with impurity concentrations < 100 part per million moles is evidence of the effects of the different oxides on the vibrational properties of the OH groups. In particular, for oxide glasses a red shift of the composite band at about 3670 cm(-1), assigned to the OH stretching modes of free Si-OH groups an…
In-situ observation of beta-ray induced UV optical absorption in a-SiO2: radiation darkening and room temperature recovery
2006
International audience; We studied the optical absorption in the 3.0-6.2 eV range induced in bulk amorphous SiO2 by beta-ray irradiation up to similar to 1 MGy at room temperature. The induced absorption was measured in situ both during irradiation and in the post irradiation time. Our data evidence E', center as the main defect induced by irradiation and the partial decay of their absorption band at about 5.8 eV after irradiation. A quantitative analysis of the time evolution of the induced absorption shows that the transmission recovery observed after irradiation is compatible with the reaction of radiation-induced defects with H-related (H-2, H2O) species diffusing in the amorphous matrix
Non-destructive automatic determination of aspect ratio and cross-sectional properties of fibres
2015
A novel method for computerised estimation of the aspect ratio distribution and various cross-sectional geometrical properties of fibres in short-fibre reinforced composites is proposed. The method, based on X-ray micro-computed tomography, is non-destructive and does not require user intervention. Based on results on specially fabricated model material, the accuracy and precision of the method seems adequate. The method is applied in analysing a manufacturing process of wood fibre reinforced thermoplastic composite. The results indicate a significant decrease of the aspect ratio of fibres during the processing steps. Finally, the feasibility of the method is assessed by estimating paramete…
Thermal stability of transition alumina nanocrystals with different microstructures
2018
Abstract The preparation of well-crystallized boehmite nanoparticles with different morphologies, encompassing from aciculae or rods of 320, 150 and 70 nm of length to platelets of 50 nm in diameter, allowed a comparative study of their respective thermal evolutions as alumina precursors. Static thermal treatments of boehmite nanocrystals at 600, 1000 and 1200 °C and a dynamic, in situ synchrotron study between 100 and 1000 °C revealed that original boehmite microstructures, i.e. size and shape of the nanoparticles, were kept not only in γ-Al 2 O 3 but also in transitional aluminas up to 1000 °C. Specifically, at that temperature, acicular samples presented θ-Al 2 O 3 structure, while in pl…
Mechanism of crystallization of fast fired mullite-based glass–ceramic glazes for floor-tiles
2006
Abstract The mechanism of crystallization from a B 2 O 3 -containing glass, with composition based in the CaO–MgO–Al 2 O 3 –SiO 2 system, to a glass–ceramic glaze was studied by different techniques. Glass powder pellets were fast heated, simulating current industrial tile processing methods, at several temperatures from 700 to 1200 °C with a 5 min hold. Microstructural study by field emission scanning electron microscopy revealed that a phase separation phenomenon occurred in the glass, which promoted the onset of mullite crystallization at 900 °C. The amount of mullite in the glass heated between 1100 and 1200 °C was around 20 wt%, as determined by Rietveld refinement. The microstructure …
Effect of boron oxide on the microstructure of mullite-based glass-ceramic glazes for floor-tiles in the CaO–MgO–Al2O3–SiO2 system
2006
Abstract The effect of increasing replacement of Al2O3 by B2O3 in a parent glass on the sintering and further crystallization of mullite was investigated. The composition of the parent glass was chosen in the mullite primary phase field of the CaO–MgO–Al2O3–SiO2 quaternary system. Glass powder pellets were heated under standard (10 °C/min and 2 h of hold time) and fast heatings (25 °C/min and 5 min of hold time) at different temperatures from 700 to 1190 °C. Sintering of B2O3-containing glasses took place in the range between 850 and 1050 °C. X-ray diffraction results showed that mullite formed as unique crystalline phase for glasses containing amounts of B2O3 larger than 6 wt%. For lower a…
Rec. E. Pala, Acropoli di Atene. Un microcosmo della produzione e distribuzione della ceramica attica, l?Erma di Bretschneider 2012
2013
Caracterización mineralógica de materias primas cerámicas por métodos cuantitativos de difracción de rayos x
2002
[ES] El objetivo de este trabajo es la caracterización de fases minerales presentes en materias primas utilizadas en la industria cerámica. Para ello se utilizan dos métodos cuantitativos basados en la difracción de rayos X, el método de Rietveld y un método sin estándar. Los resultados obtenidos por difracción rayos X de estos materiales policristalinos se comparan con los correspondientes análisis químicos y la composición normativa calculada. La precisión y reproducibilidad de los resultados obtenidos, en concordancia con los del análisis químico, son una de las más importantes ventajas de la difractometría cuantitativa que facilitan su utilización en la industria cerámica en el control …
Green composites: A brief review
2011
The rising concern towards environmental issues and, on the other hand, the need for more versatile polymer-based materials has led to increasing interest about polymer composites filled with natural-organic fillers, i.e. fillers coming from renewable sources and biodegradable. The composites, usually referred to as "green", can find several industrial applications. On the other hand, some problems exist, such as worse processability and reduction of the ductility. The use of adhesion promoters, additives or chemical modification of the filler can help in overcoming many of these limitations. These composites can be further environment-friendly when the polymer matrix is biodegradable and c…