Search results for "Characterization"

Polymorphic Derivatives of NiII and CoII Mesocates with 3D Networks and “Brick and Mortar” Structures: Preparation, Structural Characterization, and …

2020

In this work we describe the preparation, spectroscopic, thermal and structural characterization, and cryomagnetic investigation of four new polymorphic derivatives of the [M2(H2mpba)3]2– mesocate ...

A New Possibility for Powder Diffraction: The Characterization of the Domain Microstructure in a Ferroelectric Material

1996

[MoO2(SCPh2CO2)2]2− and [MoO(SCPh2CO2)2]− anion complexes. A theoretical structure characterization

1995

Abstract Geometry optimization of [MoO 2 (SCH 2 CO 2 ) 2 ] 2− and [MoO(SCH 2 CO 2 ) 2 ] − systems as models of [MoO 2 (SCPh 2 CO 2 ) 2 ] 2− and [MoO(SCPh 2 CO 2 ) 2 ] − anion complexes have been carried out at STO-3G, 3-21G, LANL1MB and LANL2DZ basis set levels. A comparison of the theoretical results and X-ray experimental data has been performed. STO-3G minimal basis set produces the best geometrical agreement, in particular the distances and orientations of the different ligands linked to molybdenum transition metal. A large structural overlap with STO-3G optimized geometry and X-ray data has been found for the [MoO 2 (SCPh 2 CO 2 ) 2 ] 2− and [MoO(SCPh 2 CO 2 ) 2 ] − anion complexes.

Structural and Magnetic Characterization of a Novel Heptanuclear Hydroxo-Bridged Copper(II) Cluster of the Corner-Sharing Dicubane Type

1994

Compatibility between traditional ground layers and 3D printing materials

2018

Starting point of this work was the restoration of a Panel Painting depicting the Adoration of the Shepherds with a Saint Bishop, by an unknown author, stored in the Galleria Regionale della Sicilia di Palazzo Abatellis, in Palermo. It was decided to integrate a missing angular decorative element of the painting’s frame in order to restore the integrity of the frame by reverse engineering and 3D printing. Reintegration was feasible as the frame has a modular decorative pattern and the remaining three corners were available. Reverse engineering and 3D printing techniques have been used in order to find a solution according to the principles of recognition, reversibility and compatibility. Mo…

Structure and Deformations of Pd−Ni Core−Shell Nanoparticles

2005

International audience; Homogeneous collections of Pd−Ni core−shell nanoparticles have been prepared by decomposition of metal−organic compounds and studied by several electron microscopy techniques: transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), high-resolution transmission electron microscopy (HRTEM), energy-filtered microscopy (EFTEM), and by X-ray photoelectron spectroscopy (XPS). The physical and chemical properties of the Pd shell are supposed to depend on its electronic properties, which are influenced by the presence of the Ni core and by the deformation in the Pd lattice. Here, the interfacial structure of Pd/Ni and the lattice deformations in t…

DACRON© 360 WOVEN: EXPERIMENTAL CHARACTERIZATION AND COMPUTATIONAL ASPECTS

2010

In this paper a first experimental study on Dacron© 360 woven constitutive behavior is presented. This woven is widely adopted in sail manufacturing, it is obtained by weaving polyethylene terephthalate (PET) yarn and it shows some peculiar features due to its own manufacturing process. The experimental tests, in terms of tensile tests and cyclic tests, clearly show the orthotropy features of the material, its high strength and deformability. The examination with optical microscope of the tested specimen allows to evidence the interaction between warp and weft yarns. The obtained results represent a first step for the definition of a correct computational approach to such materials.

Uncertainty evaluation in power measurements with commercial data acquisition boards

2011

The paper deals with the metrological characterization of a digital wattmeter developed by using a personal computer, a shunt, two commercial data acquisition boards and commercial software. The uncertainty of the active power measurements is assessed individually characterizing the voltage channel, the current channel and the phase displacement measurement between the two channels. In particular, the uncertainty on the voltage and current rms measurements is evaluated by using an already proposed approach based on the Monte Carlo method and on the usage of five parameters, while the uncertainty on the phase angle is experimentally estimated. In order to validate the proposed approach for t…

Proposal of Up-to-Date Standards on Methods of Measuring Noise Parameters of Microwave Transistors

1994

One of the most interesting topics for microrwave community is the characterization of low-noise transistors. After so many years, the Standards suggested by IEEE in 1960 are considered obsolete by the experimenters. A new methodology is here proposed as a standard. To support this proposal, an original measuring system for the complete characterization of microwave transistors in terms of noise, gain and scattering parameters from noise figure measurements only is presented.

General route to dissymmetric heteroannular-functionalized ferrocenyl 1,2-diphosphines: selective synthesis and characterization of a new class of tr…

2006

Several monosubstituted-cyclopentadienyl anions (A-Li) and [1,2-bis(diphenylphosphino)-4-tert-butylcyclopentadienyl]lithium (B-Li) react with FeCl2 to afford a novel class of multidentate ferroceny...