Search results for "Charge"
showing 10 items of 4686 documents
Self-assembly mechanism based on charge density topological interaction energies
2017
The packing interactions have been evaluated in the context of the self-assembly mechanism of crystal growth and also for its impacts on the aromaticity of the trimesate anion. The structure of ethylammonium trimesate hydrate (1) measured at 100 K and a charge density model, derived in part from theoretical structures, is reported. Theoretical structure factors were obtained from the geometry-optimized periodic wave function. The trimesic acid portion of 1 is fully deprotonated and participates in a variety hydrogen bonding motifs. Topological analysis of the charge density model reveals the most significant packing interactions and is then compared to a complementary analysis performed by …
Electronic spectroscopy of I2-Xe complexes in solid Krypton
2012
In the present work, we have studied ion-pair states of matrix-isolated I2 with vacuum-UV absorption and UV-vis-NIR emission, where the matrix environment is systematically changed by mixing Kr with Xe, from pure Kr to a more polarizable Xe host. Particular emphasis is put on low doping levels of Xe that yield a binary complex I2–Xe, as verified by coherent anti-Stokes Raman scattering (CARS) measurements. Associated with interaction of I2 with Xe we can observe strong new absorption in vacuum-UV, redshifted 2400 cm−1 from the X → D transition of I2. Observed redshift can be explained by symmetry breaking of ion-pair states within the I2–Xe complex. Systematic Xe doping of Kr matrices shows…
Charge radii of exotic potassium isotopes challenge nuclear theory and the magic character of N = 32
2020
Nuclear charge radii are sensitive probes of different aspects of the nucleon-nucleon interaction and the bulk properties of nuclear matter; thus, they provide a stringent test and challenge for nuclear theory. The calcium region has been of particular interest, as experimental evidence has suggested a new magic number at $N = 32$ [1-3], while the unexpectedly large increases in the charge radii [4,5] open new questions about the evolution of nuclear size in neutron-rich systems. By combining the collinear resonance ionization spectroscopy method with $\beta$-decay detection, we were able to extend the charge radii measurement of potassium ($Z =19$) isotopes up to the exotic $^{52}$K ($t_{1…
Halloysite Nanotubes Coated by Chitosan for the Controlled Release of Khellin
2020
In this work, we have developed a novel strategy to prepare hybrid nanostructures with controlled release properties towards khellin by exploiting the electrostatic interactions between chitosan and halloysite nanotubes (HNT). Firstly, khellin was loaded into the HNT lumen by the vacuum-assisted procedure. The drug confinement within the halloysite cavity has been proved by water contact angle experiments on the HNT/khellin tablets. Therefore, the loaded nanotubes were coated with chitosan as a consequence of the attractions between the cationic biopolymer and the halloysite outer surface, which is negatively charged in a wide pH range. The effect of the ionic strength of the aqueous medium…
L'audience et l'influence d'une revue mesurée à travers Internet : une application à Finance Contrôle Stratégie
2009
This article aims to show the interest of statistics available on the Internet concerning consultations of abstracts, downloads and citations of articles to assess the attractiveness and influence of a scientific review. This interest is illustrated by the case of the review Finance Contrôle Stratégie on the basis of the statistics provided by Repec and Publish or Perish. Beyond the findings that confirm the good performance of FCS and the usefulness of these statistics for the management of a scientific review, the article also provides insights into the life cycle of an article and the choice of the language of publication.
Adolescent and Young Adult Cancer Survivors: Design and Characteristics of the First Nationwide Population-Based Cohort in Italy
2020
Purpose: Adolescent and young adult (AYA, 15-39 years) cancer survivors (alive at least 5 years after cancer diagnosis) are less studied than younger and older cancer survivors and research on their late effects is limited. To facilitate research on long-term outcomes of AYA cancer survivors, we established, in Italy, a population-based AYA cancer survivors' cohort. This article describes the study design and main characteristics of this cohort. Methods: The cohort derives from population-based cancer registries (CRs). Each CR identified AYA cancer patients retrospectively. Treatment for first primary cancer and all health events from diagnosis to death can be traced through linkage with av…
Nanostructured Pb electrode for innovative lead-acid battery
2017
Lead-acid batteries are widely used for energy storage, due to a well-established and reliable technology. Over the years, various studies for improving the performance of this battery have been performed. The main goal is to replace conventional plates with innovative electrodes having good stability, high capacity and high surface area. In particular, it is necessary to improve the kinetics of electrochemical conversion reactions at the electrode-solution interface, and to guarantee good electrical continuity during repeated charge/discharge cycles. To achieve these goals, the attention was focused on nanostructured electrodes. Up-to-date, two principal approaches have been followed. In t…
Discharge estimation combining flow routing and occasional measurements of velocity
2011
A new procedure is proposed for estimating river discharge hydrographs during flood events, using only water level data at a single gauged site, as well as 1-D shallow water modelling and occasional maximum surface flow velocity measurements. One-dimensional diffusive hydraulic model is used for routing the recorded stage hydrograph in the channel reach considering zero-diffusion downstream boundary condition. Based on synthetic tests concerning a broad prismatic channel, the “suitable” reach length is chosen in order to minimize the effect of the approximated downstream boundary condition on the estimation of the upstream discharge hydrograph. The Manning’s roughness coefficient is calibra…
Computation of vertically averaged velocities in irregular sections of straight channels
2015
Abstract. Two new methods for vertically averaged velocity computation are presented, validated and compared with other available formulas. The first method derives from the well-known Huthoff algorithm, which is first shown to be dependent on the way the river cross section is discretized into several subsections. The second method assumes the vertically averaged longitudinal velocity to be a function only of the friction factor and of the so-called "local hydraulic radius", computed as the ratio between the integral of the elementary areas around a given vertical and the integral of the elementary solid boundaries around the same vertical. Both integrals are weighted with a linear shape f…
”En ny hverdag”. Mødres opplevelse av hverdagen med et prematurt barn, og støtten ved en ressurshelsestasjon
2015
The study explores mothers’ of premature infants experience of how health centers especially adapted for families with premature infants can help them to cope with everyday life after discharge from a neonatal intensive care unit. Background: Premature children are at higher risk for physical and mental health problems, which makes parenting demanding. The transition between hospital and home is a challenging period where parents may need extra support to cope with everyday life. Method: Nine mothers of premature infants receiving follow-up care at a health center especially adapted for families with premature infants were interviewed. Data were analyzed by Kvale and Brinkmann’s guidelines …