Search results for "Chemical energy"
showing 10 items of 23 documents
Enhancing the photocatalytic properties of PbS QD solids: the ligand exchange approach.
2019
Surface engineering of nanomaterials is a promising tool towards the design of new materials for conversion of solar energy into chemical energy. In this work, we examine the influence of ligand exchange on the photocatalytic performance of solution-processed PbS films. We test different ligands such as oleylamine (OAm), 1,2-ethanedithiol (EDT), 3-mercaptopropionic acid (MPA) and tetrabutylammonium iodide (TBAI). The study demonstrates that PbS films capped with MPA and EDT exhibit 3.5-fold enhanced photocatalytic performance for the photodecomposition of methyl orange upon sunlight exposure. Both band energy alignment and charge carrier transport have a strong impact on the generation of r…
Optimizing Energy Transduction of Fluctuating Signals with Nanofluidic Diodes and Load Capacitors
2018
[EN] The design and experimental implementation of hybrid circuits is considered allowing charge transfer and energy conversion between nanofluidic diodes in aqueous ionic solutions and conventional electronic elements such as capacitors. The fundamental concepts involved are reviewed for the case of fluctuating zero-average external potentials acting on single pore and multipore membranes. This problem is relevant to electrochemical energy conversion and storage, the stimulus-response characteristics of nanosensors and actuators, and the estimation of the accumulative effects caused by external signals on biological ion channels. Half-wave and full-wave voltage doublers and quadruplers can…
A single-chamber membraneless microbial fuel cell exposed to air using Shewanella putrefaciens
2016
Abstract Microbial Fuel Cells (MFCs) are bio-electrochemical devices which convert the chemical energy content of organic fuels into electricity, thanks to the ability of anode respiring bacteria to give electrons to the anode. This result is usually achieved under anaerobic conditions, obtained with a sealed anode chamber. Despite this, Shewanella oneidensis has been recognized by many authors to obtain the same results in presence of air. Furthermore, another member of the Pseudomonaceae family, Shewanella putrefaciens, has also shown the capability to catalyze the cathodic oxygen reduction. In this work the capability of S. putrefaciens to work under both anaerobic and micro-aerobic cond…
Optimal Design of Grid Integration of a Net Zero Energy Building trough Electrochemical Energy Storage and Fuel Cell Utilization
2018
The integration of electrochemical energy storage, renewable energy production, and fuel cell systems can play a key role in the development of more efficient eco-friendly systems, spanning all sectors of energy management, from stationary to mobile. In particular, residential sector consumed 19% of worldwide energy production in 2015, resulting the third energivorous sector after transport and industry. Distributed energy systems, which efficiently use local resources, can reduce problems in regions with lack of a stable network and more in general help the growth of a sustainable development. In this case, the impact of PV-Lithium Batteries-SOFC integration in a NZEB (Net Zero Energy Buil…
Improving efficiency and discharge power of acid-base flow battery via a bi-objective optimisation
2023
Formation of slow molecules in chemical reactions in crossed molecular beams
2008
T. V. Tscherbul, Ğ Barinovs, J. Klos, and R. V. Krems Department of Chemistry, University of British Columbia, Vancouver, British Columbia, Canada V6T 1Z1 Department of Theoretical Physics, Institute of Chemical Physics, University of Latvia, Riga, Latvia Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA Received 13 January 2008; revised manuscript received 29 May 2008; published 8 August 2008
The acid–base flow battery : Sustainable energy storage via reversible water dissociation with bipolar membranes
2020
The increasing share of renewables in electric grids nowadays causes a growing daily and seasonal mismatch between electricity generation and demand. In this regard, novel energy storage systems need to be developed, to allow large-scale storage of the excess electricity during low-demand time, and its distribution during peak demand time. Acid–base flow battery (ABFB) is a novel and environmentally friendly technology based on the reversible water dissociation by bipolar membranes, and it stores electricity in the form of chemical energy in acid and base solutions. The technology has already been demonstrated at the laboratory scale, and the experimental testing of the first 1 kW pilot pla…
ELECTRICAL ENERGY STORAGE DEVICES BASED ON pH AND SALINITY GRADIENTS: MODELLING, EXPERIMENTS AND PILOTING
2021
Nanoporous Gold‐Based Materials for Electrochemical Energy Storage and Conversion
2021
Synthesis of Circumpyrene by Alkyne Benzannulation of Brominated Dibenzo[hi,st]ovalene
2019
A transition-metal catalyzed alkyne benzannulation allowed an unprecedented synthesis of circumpyrene, starting from 3,11-dibromo-6,14-dimesityldibenzo[hi,st]ovalene (DBOV). The circumpyrene was characterized by a combination of NMR, mass spectrometry, and single-crystal X-ray diffraction analysis, revealing its multizigzag-edged structure. Two newly introduced C═C bonds in circumpyrene strongly perturbed the electronic structures of DBOV, as evidenced by increased optical and electrochemical energy gaps. This is in good agreement with an increased number of Clar's sextets as well as a decreased number of π-electrons in the conjugation pathway of circumpyrene, according to anisotropy of the…