Search results for "Chlorobenzene"

showing 10 items of 104 documents

Novel deoxycholic acid alkylamide-phenylurea-derived organogelators

2010

Abstract Three monomeric and three dimeric deoxycholic acid (DCA) alkylamido-phenylurea derivatives are designed based on known gelators and are synthesized and characterized by 1 H and 13 C NMR spectroscopy, ESI-TOF mass spectrometry, and elemental analyses. Among them, a monomeric derivative forms supramolecular gels in CHCl 3 and chlorobenzene, whereas a dimeric derivative gels THF and higher 1-alkanols containing 7–10 carbons. The morphologies of their xerogels are studied by scanning electron microscopy (SEM). No signature of macroscopic chirality of the gels is visible.

Organic ChemistryDeoxycholic acidSupramolecular chemistryCarbon-13 NMRMass spectrometryBiochemistrychemistry.chemical_compoundMonomerchemistryChlorobenzeneDrug DiscoveryOrganic chemistryChirality (chemistry)SpectroscopyTetrahedron Letters
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Signals involved in the early TH1/TH2 polarization of an immune response depending on the type of antigen.

1999

Abstract Background: The early production of distinct cytokines by epidermal cells (ECs) in response to antigen exposure may govern the development of T H1 -like immune responses, such as contact sensitivity, or T H2 -like immune responses, such as IgE-dependent allergies of the immediate type, depending on the type of antigen. Objective: The aim of this study was to compare the signals induced by protein allergens with those induced by haptens in ECs and subsequently in local draining lymph node cells (LNCs) or splenocytes. Methods: BALB/c mice were primed in vivo with the protein allergens ovalbumin or birch pollen or the haptens 2,4-dinitrofluorobenzene or trinitrochlorbenzene, respectiv…

Ovalbuminmedicine.medical_treatmentImmunologyImmunoglobulinsEnzyme-Linked Immunosorbent AssayPicryl ChlorideBiologyMiceImmune systemTh2 CellsAntigenmedicineDinitrochlorobenzeneImmunology and AllergyAnimalsRNA MessengerCells CulturedMice Inbred BALB CReverse Transcriptase Polymerase Chain ReactionCell PolarityEpithelial CellsT lymphocyteAllergensTh1 CellsInterleukin-10Interleukin 10OvalbuminBlotting SouthernKineticsCytokineImmunologybiology.proteinCytokinesPollenFemaleLymph NodesAntibodyHaptenHaptensSpleenSignal TransductionThe Journal of allergy and clinical immunology
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Mixed Function Oxidase Activity and Organochlorine Levels in Farmed Sharpsnout Seabream (Diplodus puntazzo) from Two Intensive Aquaculture Facilities

2004

Mixed function oxidase (MFO) activities and organochlorine levels were investigated in liver of farmed sharpsnout seabream bred in two intensive facilities, a sea farm and a land-based farm. The aim of this study is to investigate how different facility locations and breeding conditions might affect fish metabolic capabilities and accumulation of toxic chemicals in farmed sharpsnout seabream. The differences between breeding two or more fish species in the same cage or tank known as polyculture, and monoculture (1 species) were also investigated. The results showed that both facility location (sea and land) as well as breeding systems (polyculture and monoculture) might be responsible for t…

Settore BIO/07 - EcologiaDiplodus puntazzoMetabolizing enzymesbusiness.industryFish farmingHexachlorobenzeneAquatic ScienceBiologyLand-based MFO Organochlorines Sea farming Sharpsnout seabreamEnzyme assayFisherychemistry.chemical_compoundAnimal scienceAquaculturechemistrybiology.proteinPolycultureMonoculturebusinessAgronomy and Crop ScienceAquaculture International
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Comparison of stable isotope composition and inorganic and organic contaminant levels in wild and farmed bluefin tuna, Thunnus thynnus, in the Medite…

2009

Abstract Stable isotope composition (δ13C and δ15N) and persistent pollutants, including heavy metals (Hg, Cd, Pb, As, Cu, Zn) and organochlorine compounds (PCBs, HCB and p,p′-DDE), were measured in muscle and liver tissues of wild and farmed bluefin tunas to investigate the changes occurring during the farming period and to assess the quality, in terms of contaminants, of the final product. At the end of farming, the food supplied was clearly integrated into the tuna tissues as derived from stable isotope signatures, and, contrarily to the literature findings obtained for other species, farmed tunas showed slight variations in persistent elements and chemical compounds in comparison with w…

Settore BIO/07 - EcologiaEnvironmental EngineeringDichlorodiphenyl DichloroethyleneHealth Toxicology and MutagenesisFish farmingAquaculturechemistry.chemical_compoundAquacultureMetals HeavyPCBs HCB pp’-DDE heavy metals stable isotopes tuna farmingHexachlorobenzeneHydrocarbons ChlorinatedMediterranean SeaAnimalsEnvironmental ChemistryPollutantCarbon IsotopesNitrogen IsotopesbiologyTunabusiness.industryChemistryStable isotope ratioPublic Health Environmental and Occupational Healthfood and beveragesGeneral MedicineGeneral ChemistryHexachlorobenzeneContaminationbiology.organism_classificationPolychlorinated BiphenylsPollutionLiverEnvironmental chemistryMultivariate AnalysisbusinessTunahuman activitiesWater Pollutants ChemicalThunnusEnvironmental MonitoringChemosphere
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The trophic transfer of persistent pollutants (HCB, DDTs, PCBs) within polar marine food webs.

2017

Biomagnification (increase in contaminant concentrations at successively higher levels of trophic web), is a process that can transversally impair biodiversity and human health. Most research shows that biomagnification should be higher at poles with northern sites having a major tendency to biomagnify Persistent Organic Pollutants (POPs) through their marine food webs. We investigated the biomagnification degree into two marine trophic webs combining carbon and nitrogen stable isotopes and POP analyses. We showed that the Antarctic trophic web was more depleted than the sub-Arctic one and the differences highlighted for the basal part could explain the difference in length between them. Co…

Settore BIO/07 - EcologiaEnvironmental EngineeringFood Chain010504 meteorology & atmospheric sciencesHealth Toxicology and MutagenesisBiomagnificationDichlorodiphenyl DichloroethyleneBiodiversityAntarctic Regions010501 environmental sciences01 natural sciencesBiomagnification; Marine organisms; POPs; Ross Sea; Stable isotopes; Sub-Arctic; Chemistry (all); Environmental ChemistryHuman healthchemistry.chemical_compoundSub arcticRoss SeaMarine organismHexachlorobenzeneEnvironmental ChemistryAnimalsSeawaterPOPsMarine organismsStable isotopesBiomagnification0105 earth and related environmental sciencesTrophic levelPollutantCarbon IsotopesNitrogen IsotopesEcologyStable isotope ratioArctic RegionsChemistry (all)Public Health Environmental and Occupational HealthFishesGeneral MedicineGeneral ChemistryHexachlorobenzenePOPStable isotopePollutionPolychlorinated BiphenylsSub-ArcticchemistryEnvironmental chemistryVertebratesEnvironmental scienceWater Pollutants ChemicalChemosphere
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HCB, p,p'-DDE and PCB ontogenetic transfer and magnification in bluefin tuna (Thunnus thynnus) from the Mediterranean Sea.

2007

The bluefin tuna, Thunnus thynnus (Linnaeus 1758), is biologically and economically important in the Atlantic--Mediterranean ecosystems. Bluefin tuna feed on diverse food items depending on their age, thus they occupy different trophic levels during their lifespan. Hexachlorobenzene (HCB), p,p'-DDE and polychlorinated biphenyls (PCBs) are well-known persistent organic pollutants (POPs) in the Mediterranean basin. The relationship between stable isotopes of nitrogen (N) and the POP residue levels in tissues has recently increased knowledge on the link between the trophic levels and the contaminant accumulation. Trophic levels were estimated by using 15N/14N ratio (delta15N) and HCB, p,p'-DDE…

Settore BIO/07 - EcologiaFood ChainScombridaeBiomagnificationDichlorodiphenyl DichloroethyleneZoologychemistry.chemical_compoundMediterranean seaHexachlorobenzeneMediterranean SeaEnvironmental ChemistryAnimalsBody SizeSeawaterTrophic levelPersistent organic pollutantbiologyNitrogen IsotopesEcologyTunaGeneral ChemistryHexachlorobenzeneContaminantbiology.organism_classificationPolychlorinated BiphenylschemistryThusnnus MEDTunaThunnusWater Pollutants ChemicalEnvironmental MonitoringEnvironmental sciencetechnology
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CCDC 820755: Experimental Crystal Structure Determination

2011

Related Article: F.Riobe, F.Piron, C.Rethore, A.M.Madalan, C.J.Gomez-Garcia, J.Lacour, J.D.Wallis, N.Avarvari|2011|New J.Chem.|35|2279|doi:10.1039/c1nj20310j

Space GroupCrystallography((RRRR)-Tetramethylbis(ethylenedithio)tetrathiafulvalene) rac-tris(tetrachlorobenzene-12-diolato)phosphate(v) acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 976101: Experimental Crystal Structure Determination

2016

Related Article: Zouhour Denden, Wafa Harhouri, Leila Ben Haj Hassen, Yoann Rousselin, Eric Saint-Aman, Habib Nasri|2017|J.Mol.Struct.|1133|472|doi:10.1016/j.molstruc.2016.11.080

Space GroupCrystallography(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium(i) (5101520-tetrakis(4-methylphenyl)porphyrinato)-isothiocyanato-zinc(ii) chlorobenzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 820753: Experimental Crystal Structure Determination

2011

Related Article: F.Riobe, F.Piron, C.Rethore, A.M.Madalan, C.J.Gomez-Garcia, J.Lacour, J.D.Wallis, N.Avarvari|2011|New J.Chem.|35|2279|doi:10.1039/c1nj20310j

Space GroupCrystallography(rac-4'5'-Ethylenedithio-4-(4-methyl-2-oxazolin-2-yl)tetrathiafulvalene) rac-tris(tetrachlorobenzene-12-diolato)phosphate(v) acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 637751: Experimental Crystal Structure Determination

2007

Related Article: M.Bujak, K.Dziubek, A.Katrusiak|2007|Acta Crystallogr.,Sect.B:Struct.Sci.|63|124|doi:10.1107/S0108768106046684

Space GroupCrystallography12-dichlorobenzeneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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