Search results for "Chlorophenol"
showing 10 items of 64 documents
Chlorophenol Compounds in Snow
1988
Polychlorinated phenols, guaiacols and catechols have been studied in snow from North Pole, North, Central and South Finland. Only Central and South Finland samples contained known compounds above limit of determination 0.5 ng/1. Airborne chlorophenol pollution appeared to be very much higher in South than in Central Finland.
Chlorinated and methylated dibenzothiophenes in sediment samples from a river contaminated by organochlorine wastes
2001
Eleven sediment samples from the lower Kymijoki River were analyzed for the occurrence of polychlorinated and polymethylated dibenzothiophenes (PCDT and PMeDTs). The area was heavily polluted by wastes from a pulp chlorobleachery and by leakage from a factory producing wood preservative chlorophenol formulation Ky-5. Levels in the sediments were from <5 to 400, 200 and 50 pg g-1 dw for tetra, penta and hexa-CDT, respectively. The concentrations of mono, di, tri and tetra-MeDTs were in the range of 1–5, 5–85, 5–500 and 15–2300 ng g-1 dw, respectively. PCDT contents in surface sediment (0–3 cm layers) decreased by distance downstream from the bleachery and Ky-5 factory similar to those of the…
Gas chromatographic-mass spectrometric analysis of chlorinated phenoxyphenols in the technical chlorophenol formulation ky-5′
1984
Abstract The content of polychlorinated phenoxyphenol (PCPP) impurities in the technical chlorophenol formulation Ky-5 (wood preservative) was studied. The phenolic fraction was shown to contain predioxins and isopredioxins, the structures of the components being verified by gas chromatography mass spectrometry of non-derivatized, methylated and acetylated fractions. 2,6-Dichloro-4-(2,4,6-trichlorophenoxy)phenol and 2,6-dichloro-4-(2,3,4,6-tetrachlorophenoxy)phenol were identified by the comparison of their retention times and the mass spectra of their methyl and acetyl derivatives with those of authentic specimens. The amounts of the above components in Ky-5 were ca. 0.8 and 0.2%, respecti…
Polychlorinated phenols and their metabolites in soil and earthworms of sawmill environment
1990
Abstract Topsoil and earthworm samples collected from three Finnish sawmill environments were analysed for polychlorinated phenols, 2,3,4,6-tetrachloro- and pentachlorophenol, and their metabolites. Analyses were carried out by gas chromatography/mass spectrometry using a selected ion monitoring technique and by dual-channel gas chromatography using quartz capillary columns and two electron capture detectors. The total chlorophenol concentrations ranged from ca. 260 to 480 μg/g (dry weight) in soil and from ca. 140 to 3500 μg/g fat in earthworms. The most important metabolites in soil were chlorinated dihydroxy-benzenes (also at ppm level); only traces of chlorinated anisoles were detected …
EXPERIENCES OF STRUCTURE ANALYSES OF CHLOROPHENOL DIMERS AND TRIMERS FOUND IN DIFFERENT SAMPLES
1982
ABSTRACT Chlorophenol formulations (Kymi/Kymmene Co., wood preservatives), sawmill wood waste samples and different waste treatment product samples were analyzed for oligomeric by-products of the polychlorinated phenols. Structure types for 26 phenolic dimers, 45 neutral dimers and 13 phenolic trimers were determined by GC/MS. Types of one tetrachloro and one hexachloro compound detected remained unknown. Contents of by-products in chlorophenol formulations varied greatly depending on their production method. Chemical treatment of wastes with NaClO and NaOH lowered their contents of chlorophenols and phenolic dimers, but did not change (NaOH) or increased (NaClO) the contents of neutral dim…
Effects of ultrahigh dilutions of 3,5-dichlorophenol on the luminescence of the bacterium Vibrio fischeri.
2003
Abstract There is a great need for research in the field of homeopathy for laboratory test systems to investigate the actions of ultrahighly diluted biological effectors. With this in mind, we used the luminescent bacterium Vibrio fischeri, which is used throughout the world in testing water quality. Luminescence inhibition is utilized as a test parameter for the toxicity of a sample. We used ultrahigh dilutions (UHD) of 3,5-dichlorophenol as effector and adapted the standard test procedure for water toxicity in a way that let us evaluate very minute effects. Three groups of samples were prepared and then blinded: 45 dilutions of 3,5-dichlorophenol in steps of 10, starting with 4.2×10−2 M, …
Responses of microbial activity and decomposer organisms to contamination in microcosms containing coniferous forest soil.
2002
Soil respiration from microcosms contaminated with pentachlorophenol, 2-ethanolhexanoate, creosote, CuSO4, and benomyl was measured in order to evaluate usefulness of soil microcosms and microbial respiration rate monitoring as a toxicity test in soils with high organic matter content. Coniferous forest soil and its organisms were used as test objects. In addition, how a short-term low temperature period including frost affects respiration dynamics in stressed soils was studied, i.e., whether contaminants reduce resistance of the community to other (also natural) stresses. In addition, at the end of the experiment, effects of contaminants on faunal and microbial community structures were an…
Subcellular localization of pentachlorophenol 4-monooxygenase in Sphingobium chlorophenolicum ATCC 39723.
2002
Abstract We have studied the subcellular localization of pentachlorophenol 4-monooxygenase (PCP4MO) in Sphingobium chlorophenolicum ATCC 39723 during induction by pentachlorophenol (PCP). Using a monoclonal antibody CL6 specific to the native and recombinant PCP4MO, the enzyme was primarily found soluble as determined by immunoblot and ELISA analyses of cellular fractions. However, the enzyme was observed both in the soluble and membrane-bound forms during induction for 2–4 h, suggesting its translocation out from the cytoplasm. Electron microscopy confirmed that PCP4MO was predominantly present in the cytoplasm at 1 h, whereas at 4 h significant amount was detected also in the membrane and…
Sphingomonas fennica sp. nov. and Sphingomonas haloaromaticamans sp. nov., outliers of the genus Sphingomonas.
2007
Bacterial isolates obtained from polychlorophenol-contaminated sites in Finland (strain K101T) and from a Dutch drinking water well (strain A175T) were characterized taxonomically. 16S rRNA gene sequence analysis, determination of DNA G+C content, physiological characterization, estimation of the ubiquinone and polar lipid patterns and fatty acid content revealed that strains K101T and A175T were similar to Sphingomonas wittichii RW1T but also showed pronounced differences. The DNA G+C contents of the two novel strains were 63.6 and 66.1 mol%, respectively. On the basis of these results, two novel species of the genus Sphingomonas are described, for which the names Sphingomonas haloaromatic…
Novosphingobium lentum sp. nov., a psychrotolerant bacterium from a polychlorophenol bioremediation process
2005
A polychlorophenol-degrading strain, designated MT1T, and three MT1-like strains, MT101, MT103 and MT104, were isolated from a cold (4–8 °C) fluidized-bed process treating chlorophenol-contaminated groundwater in southern Finland. The organisms were Gram-negative, rod-shaped, catalase-positive, non-spore-forming and non-motile. Phylogenetic analysis based on 16S rRNA gene sequences indicated that the strains belonged to the α-4 subclass of the Proteobacteria and were members of the genus Novosphingobium. The highest 16S rRNA gene sequence similarity observed for these strains was 96·5 % with the type strains of Novosphingobium hassiacum, Novosphingobium aromaticivorans and Novosphingobium s…