Search results for "Citation"
showing 10 items of 1710 documents
Analytic UHF-CCSD(T) second derivatives: implementation and application to the calculation of the vibration-rotation interaction constants of NCO and…
1998
An implementation of analytic open-shell UHF-CCSD(T) second derivatives is presented. To demonstrate applicability and test the accuracy of the UHF-CCSD(T) approach for the determination of spectroscopical parameters, vibration-rotation interaction constants were calculated for the ground (12Π) and first electronically excited (12Σ) states of the NCO and NCS radicals. In addition, harmonic vibrational frequencies for both states, the Renner-Teller parameter for the ground state, as well as the 12Π→12Σ excitation energy are reported. While the computed values are in good agreement with reliable experimental information for NCO, most of the data presented for NCS are predictions of quantities…
Analytical model of transit time broadening for two-photon excitation in a three-level ladder and its experimental validation
2012
We revisit transit time broadening for one of the typical experiment designs in molecular spectroscopy, that of a collimated supersonic beam of particles crossing a focused Gaussian laser beam. In particular, we consider a Doppler-free arrangement of a collimated supersonic beam of Na${}_{2}$ molecules crossing two counterpropagating laser beams that excite a two-photon transition in a three-level ladder scheme. We propose an analytical two-level model with a virtual intermediate level to show that the excitation line shape is described by a Voigt profile and provide the validity range of this model with respect to significant experimental parameters. The model also shows that line broadeni…
Emerging topics in scientific research on global water-use efficiency
2019
AbstractA bibliometric analysis of research articles published on water-use efficiency was performed using the Web of Science database and evaluated. Journal titles, publication years, subject categories, keywords and countries publishing were obtained. A number of 2077 papers were retrieved, two-thirds of them published in the last decade. The articles were published in 439 journals, with Agricultural Water Management, Agronomy Journal, Crop Science, Field Crops Research and Indian Journal of Agricultural Sciences the most productive. Most of the leading productive journals have Impact Factors in the top quartiles of the Journal Citation Reports. Agronomy, Plant Sciences, Water Resources a…
Controlling ground-state rotational dynamics of molecules by shaped femtosecond laser pulses
2004
We report controlled excitation of ground-state rotational wave packet by pulse-shaping technique. The experiment is conducted in nitrogen $({\mathrm{N}}_{2})$ at room temperature and atmospheric pressure. A femtosecond laser pulse produces rotational coherences in the vibronic ground state of ${\mathrm{N}}_{2}$ through an impulsive Raman process. The laser pulse is tailored using a spatial light modulator producing spectral phase modulation. Periodic phase steps are applied in order to control the excitation of specific rotational Raman transitions. The outcome is the modification of the relative excitation between odd and even rotational states which allows the control of the symmetry and…
Performance of electro-optical plasmonic ring resonators at telecom wavelengths
2012
International audience; In this work we report on the characteristics of an electro-optical dielectric-loaded surface plasmon polariton waveguide ring resonator. By doping the dielectric host matrix with an electro-optical material and designing an appropriate set of planar electrodes, we measured a 16% relative change of transmission upon application of a controlled electric field. We have analyzed the temporal response of the device and conclude that electrostriction of the host matrix is playing a dominating role in the transmission response.
Efficient excitation of dielectric-loaded surface plasmon-polariton waveguide modes at telecommunication wavelengths
2008
International audience; The excitation of surface plasmon-polariton (SPP) waveguide modes in subwavelength dielectric ridges deposited on a thin gold film has been characterized and optimized at telecommunication wavelengths. The experimental data on the electromagnetic mode structure obtained using scanning near-field optical microscopy have been directly compared to full vectorial three-dimensional finite element method simulations. Two excitation geometries have been investigated where SPPs are excited outside or inside the dielectric tapered region adjoint to the waveguide. The dependence of the efficiency of the SPP guided mode excitation on the taper opening angle has been measured an…
Cylindrical metal-coated optical fibre devices for filters and sensors
1996
Novel fibre-optic components suitable for sensor applications and wavelength filters are reported. The devices consist of a tapered fibre whose uniform waist has been coated with a thin layer of gold. The operation principle is the resonant excitation of a surface plasma mode of the metal film.
Novel synthesis of up-conversion phosphor based on rare-earth doped NaLaF4
2011
In this work Er3+ doped NaLaF4 material has been synthesized Along with the description of the synthesis route, luminescence spectra and decay kinetics of both traditional and up-conversion luminescence of Er3+ will be presented for different Er3+ doping levels. It will be shown that the main mechanisms involved in the creation of the up-conversion luminescence in NaLaF4:Er3+ under excitation at about 975 nm are excited state absorption and energy transfer. Relative impact of either of the mechanisms in NaLaF4:Er3+ depends on both the concentration of Er3+ and on the excitation wavelength: the increase of either the concentration or the excitation wavelength leads to the prevalence of energ…
Efficient Hot Electron Transfer in Quantum Dot-Sensitized Mesoporous Oxides at Room Temperature
2018
Hot carrier cooling processes represent one of the major efficiency losses in solar energy conversion. Losses associated with cooling can in principle be circumvented if hot carrier extraction toward selective contacts is faster than hot carrier cooling in the absorber (in so-called hot carrier solar cells). Previous work has demonstrated the possibility of hot electron extraction in quantum dot (QD)-sensitized systems, in particular, at low temperatures. Here we demonstrate a room-temperature hot electron transfer (HET) with up to unity quantum efficiency in strongly coupled PbS quantum dot-sensitized mesoporous SnO2. We show that the HET efficiency is determined by a kinetic competition b…
EBIT diagnostics using X-ray spectra of highly ionized Ne
2003
We have carried out a detailed analysis of highly ionized neon spectra collected at the NIST EBIT using an NTD germanium X-ray microcalorimeter developed at the Harvard-Smithsonian Center for Astrophysics [Nucl. Instr. and Meth. A 444 (2000) 156]. Our attention was focused especially on the Ne IX He-like triplet to check electron density diagnostics through the intercombination/forbidden line ratio. We have investigated possible effects of the ion dynamics on the plasma emission line intensities, looking at the dependence of the count-rate and the charge state distribution on the electron beam energy and current. The temperature and spatial distribution of the neon ions, and hence the overl…