Search results for "Clos"

showing 10 items of 1439 documents

Asymmetric Allylation/Ring Closing Metathesis: One-Pot Synthesis of Benzo-fused Cyclic Homoallylic Amines. Application to the Formal Synthesis of Ser…

2013

A one-pot asymmetric allylation/ring closing metathesis (RCM) sequence for the synthesis of cyclic homoallylic amines has been developed. A library of six- and seven-membered benzo-fused products has been synthesized in good yields and complete diastereoselectivity. The new methodology has been applied to the formal syntheses of the antidepressant Sertraline and the epimeric Norsertraline. The methodology is amenable for the synthesis of analogs.

Molecular StructureChemistryOrganic ChemistryOne-pot synthesisStereoisomerismStereoisomerismBiochemistryCatalysisFormal synthesisRing-closing metathesisSertralineOrganic chemistryAminesPhysical and Theoretical Chemistry
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3D printed fluidic platform with in-situ covalently immobilized polymer monolithic column for automatic solid-phase extraction

2020

Abstract In this work, 3D stereolithographic printing is proposed for the first time for the fabrication of fluidic devices aimed at in-situ covalent immobilization of polymer monolithic columns. Integration in advanced flow injection systems capitalized upon programmable flow was realized for fully automatic solid-phase extraction (SPE) and clean-up procedures as a ‘front-end’ to on-line liquid chromatography. The as-fabricated 3D-printed extraction column devices were designed to tolerate the pressure drop of forward-flow fluidic systems when handling large sample volumes as demonstrated by the determination of anti-microbial agents, plastic additives and monomers as models of emerging co…

Monolithic HPLC columnPolymersSurface Properties02 engineering and technology01 natural sciencesBiochemistryAnalytical ChemistryAutomationchemistry.chemical_compoundHumansEnvironmental ChemistryFluidicsSolid phase extractionParticle SizeMonolithSalivaChromatography High Pressure LiquidSpectroscopychemistry.chemical_classificationgeographygeography.geographical_feature_categoryMolecular StructureMethylparabenSolid Phase Extraction010401 analytical chemistryExtraction (chemistry)Polymer021001 nanoscience & nanotechnologyTriclosan0104 chemical scienceschemistryChemical engineeringColloidal goldPrinting Three-Dimensional0210 nano-technologyAnalytica Chimica Acta
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Herlies, Nord, les Hauts Champs : rapport de diagnostic

2016

Au terme de l'opération, les vestiges témoignent d'occupations couvrant une fourchette chronologique comprise entre l'âge du Bronze moyen et le Moyen Âge. Ceux-ci correspondent principalement à des structures en creux : fosses (rejet ? extraction ? mare), fossés (culture intensive, enclos, parcellaire, funéraire ?), trous de poteau (bâtiment) et bûchers funéraires. Deux fosses et un cercle matérialisent des traces d'occupations humaines comprises entre l'âge du Bronze moyen et final. Dispersés sur le site, les vestiges n'évoquent pas de structuration, ni d'organisation particulière. Néanmoins, la présence probable d'un monument funéraire favorise une expertise plus approfondie dans ce secte…

Moyen Âge[SHS.ARCHEO] Humanities and Social Sciences/Archaeology and PrehistoryenclosLa Tèneâge du Bronze[SHS.ARCHEO]Humanities and Social Sciences/Archaeology and PrehistorybûcherHaut-Empireenclos circulairehabitatfondation de bâtimentincinération
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Response determination of linear dynamical systems with singular matrices: A polynomial matrix theory approach

2017

Abstract An approach is developed based on polynomial matrix theory for formulating the equations of motion and for determining the response of multi-degree-of-freedom (MDOF) linear dynamical systems with singular matrices and subject to linear constraints. This system modeling may appear for reasons such as utilizing redundant DOFs, and can be advantageous from a computational cost perspective, especially for complex (multi-body) systems. The herein developed approach can be construed as an alternative to the recently proposed methodology by Udwadia and coworkers, and has the significant advantage that it circumvents the use of pseudoinverses in determining the system response. In fact, ba…

Multibody system0209 industrial biotechnologyMathematical optimizationPolynomialApplied Mathematics02 engineering and technologyLinear constrained structural/mechanical systemPolynomial matrix theoryMatrix multiplicationPolynomial matrixMatrix polynomialLinear dynamical systemMatrix (mathematics)020303 mechanical engineering & transports020901 industrial engineering & automation0203 mechanical engineeringMatrix splittingModeling and SimulationApplied mathematicsMatrix analysisClosed form solutionSingular matrixMathematics
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Human brain evolution : how the increase of brain plasticity made us a cultural species

2016

Why are humans so different from other primate species? What makes us so capable of creating language, art and music? The specializations in human brain anatomy that are responsible for our unique behavioral and cognitive traits evolved over a very short period of evolutionary time (between six and eight million years). Recent evidence suggests that, alongside a reorganization of the brain and an increase in its size, neural plasticity may also play a major role in explaining the evolutionary history of our species. Plasticity is the propensity of the brain to be molded by external influences, including the ecological, social and cultural context. The impact of these environmental influence…

MultidisciplinaryEcology05 social sciencesCultural contextEight millionClose relativesCognitionHuman brainBiology050105 experimental psychology03 medical and health sciences0302 clinical medicinemedicine.anatomical_structureHistory and Philosophy of ScienceEvolutionary biologyNeuroplasticitymedicine0501 psychology and cognitive sciences030217 neurology & neurosurgery
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Closed injective ideals of multilinear operators, related measures and interpolation

2020

[EN] We introduce and discuss several ways of extending the inner measure arisen from the closed injective hull of an ideal of linear operators to the multilinear case. In particular, we consider new measures that allow to characterize the operators that belong to a closed injective ideal of multilinear operators as those having measure equal to zero. Some interpolation formulas for these measures, and consequently interpolation results involving ideals of multilinear operators, are established. Examples and applications related to summing multilinear operators are also shown.

Multilinear mapPure mathematicsIdeal (set theory)Ideal of multilinear operatorsGeneral MathematicsZero (complex analysis)Measure associated to an idealMeasure (mathematics)Injective functionInterpolationClosed idealInjective idealInner measureInjective hullMATEMATICA APLICADAInterpolationMathematics
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Graphic Analysis Between Teaching and Research. Mario Ridolfi Unbuilt

2017

The graphic analysis in absentia, moving between thought and work, tries to track down, through digital surveys, a consistent path of design process. For many years now, the digital has changed the communication architecture processes that have always been areas of critics and representation. Architecture, indeed, can be told with texts, and new and unreleased representations wandering the sites of fruitful interaction between theoretical production and digital processing. The purpose of this study is to tell two projects, through unpublished images, about a little-known Ridolfi, through the close relationship between history, drawing and project.

MultimediaClose relationshipComputer scienceRepresentation (arts)Architecturecomputer.software_genreCommunication architecturecomputerGraphic analysisVisual arts
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Single-neutron orbits near Ni-78: Spectroscopy of the N=49 isotope Zn-79

2015

5 pags., 6 figs.

NUCLEIRICH ISOTOPESAstrophysics::High Energy Astrophysical PhenomenaNuclear Theoryeducationgamma-Ray transitionsN = 50 shell closureY-Ray transitions114 Physical sciencesELASTIC-SCATTERINGTransfer reactionsNuclear structureNuclear ExperimentN=50 shell closure
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Chthonic science: Georges Niangoran-Bouah and the anthropology of belonging in Côte d'Ivoire

2009

Georges Niangoran-Bouah worked assiduously toward Africanizing national education, academia, and public culture in Cote d'Ivoire. As part of this venture, his research projects, including his study of "drummology," can be regarded as a quest for "chthonic" science, that is, an anthropology that uncovers and implements the deep tenets of African-Ivorian culture. Properly situated in its academic, ideological, and political umwelt, we demonstrate, Niangoran-Bouah's anthropology of belonging is not merely an instance of "closure" but must be seen as a multiform attempt to recover a "local" position as a way to participate in universal-global science.

National educationPoliticsAnthropologyAnthropologymedia_common.quotation_subjectSituatedPublic cultureCote d ivoireSociologyIdeologyClosure (psychology)Umweltmedia_commonAmerican Ethnologist
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A Comparison of Direct Numerical Simulation and Turbulence Models for Liquid Metal Free Convection in Volumetrically Heated Enclosures

1999

Natural ConvectionDirect Numerical SimulationRectangular EnclosureCFDTurbulence ModelLiquid MetalSettore ING-IND/19 - Impianti NucleariInternal Heating
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