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Properties and interactions – melting point of tri­bromo­benzene isomers

2021

The melting points of tri­bromo­benzene isomers are correlated with the number, nature and distribution of intermolecular interactions in their structures.

chemistry.chemical_classificationHalogen bondtribromobenzene isomersChemistryIntermolecular forcemelting pointMetals and AlloysClose-packing of equal spheresResearch PapersAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsCrystalmolecular symmetryCrystallographynoncovalent interactionsMaterials ChemistryMelting pointMolecular symmetrystructure-property relationshipNon-covalent interactionsMoleculehalogen bondActa Crystallographica Section B-Structural Science Crystal Engineering and Materials
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Closed-loop recycling. A case study of films for greenhouses

2010

Abstract The degradation undergone by plastic films used for greenhouse coverage is the main cause of the worsening of the processability, of the mechanical properties and of the durability of secondary materials obtained by their recycling. This means that this secondary material cannot be processed to produce films for the same applications (closed-loop recycling). In this work different strategies are proposed to improve the processability, some mechanical properties and the resistance to photo-oxidation of these secondary materials. In particular, homopolymer blends or multilayer films where the secondary material is used in combination with virgin polymer give the best results.

chemistry.chemical_classificationMaterials sciencePolymers and PlasticsPlastic filmGreenhousePolymerCondensed Matter PhysicsDurabilitychemistryMechanics of MaterialsMaterials ChemistryDegradation (geology)ExtrusionPolymer blendComposite materialClosed loopPolymer Degradation and Stability
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Advanced descriptors for long-range noncovalent interactions between SARS-CoV-2 spikes and polymer surfaces.

2021

The recent pandemic triggered numerous societal efforts aimed to control and limit the spread of SARS-CoV-2. One of these aspects is related on how the virion interacts with inanimate surfaces, which might be the source of secondary infection. Although recent works address the adsorption of the spike protein on surfaces, there is no information concerning the long-range interactions between spike and surfaces, experimented by the virion when is dispersed in the droplet before its possible adsorption. Some descriptors, namely the interaction potentials per single protein and global potentials, were calculated in this work. These descriptors, evaluated for the closed and open states of the sp…

chemistry.chemical_classificationclosed and open structuresDensity Functional calculationsSecondary infectionIonic bondingFiltration and SeparationPolymerArticleAnalytical Chemistrychemistry.chemical_compoundAdsorptionPolylactic acidchemistryChemical physicsCovalent bondlong-range interaction potential energiesPolyethylene terephthalateNon-covalent interactionssurface affinity descriptorsSARS-CoV-2 spike proteinsMolecular Mechanics and Dynamics simulationsSeparation and purification technology
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A real-space approach to the analysis of stacking faults in close-packed metals: Modelling and Q-space feedback Longo Alessandro

2020

An R-space approach to the simulation and fitting of a structural model to the experimental pair distribution function is described, to investigate the structural disorder (distance distribution and stacking faults) in close-packed metals. This is carried out by transferring the Debye function analysis into R space and simulating the low-angle and high-angle truncation for the evaluation of the relevant Fourier transform. The strengths and weaknesses of the R-space approach with respect to the usual Q-space approach are discussed.

close-packed metalstacking faultcobalt.pair distribution functioncobaltDebye function analysi
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Modelli ed evoulzione delle politiche

2008

Questo contributo propone alcune riflessioni utili all’inquadramento ed alla valutazione delle politiche a sostegno dell’innovazione. L’attenzione viene posta, in particolare, sull’evoluzione dello scenario nel quale opera l’impresa innovativa, sul ruolo di alcune tipologie di agglomerazioni emerse in questo nuovo scenario, quali le reti per l’innovazione ed i distretti tecnologici, sui sistemi territoriali innovativi nei quali i processi istituzionali hanno un ruolo sempre più importante, come nel caso dei sistemi d’innovazione nazionale e regionale, ed infine sulla questione dell’identificazione e della misurazione dei fattori chiave dell’innovazione utili per una valutazione delle politi…

closed and open innovation politiche innovazione reti per l'innovazione distretti tecnologici tripla elica Sistemi Nazionali e Regionali d'Innovazione
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Preliminary results of a PV closed greenhouse system for high irradiation zones in south Italy

2011

closed greenhouse photovoltaic greenhouse renewable energy Sicily stand-alone PV solar system
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Exciton and multiexciton optical properties of single InAs/GaAs site-controlled quantum dots

2013

We have studied the optical properties of InAs site-controlled quantum dots (SCQDs) grown on pre-patterned GaAs substrates. Since InAs nucleates preferentially on the lithography motifs, the location of the resulting QDs is determined by the pattern, which is fabricated by local oxidation nanolithography. Optical characterization has been performed on such SCQDs to study the fundamental and excited states. At the ground state different exciton complex transitions of about 500 μeV linewidth have been identified and the fine structure splitting of the neutral exciton has been determined (≈65 μeV). The observed electronic structure covers the demands of future quantum information technologies.…

congenital hereditary and neonatal diseases and abnormalitiesPhotoluminescenceMaterials sciencegenetic structuresPhysics and Astronomy (miscellaneous)ExcitonPhysics::OpticsElectronic structureEmissionCondensed Matter::Materials ScienceFine structureBiexcitonPhotonsCondensed Matter::Otherbusiness.industrynutritional and metabolic diseasesCondensed Matter::Mesoscopic Systems and Quantum Hall Effecteye diseasesClose proximitySurfacesQuantum dotExcited stateOptoelectronicsInAs site-controlled quantum dots optical properties fine structure splittingbusinessGround stateState
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The social entrepreneur: Analysis of social awareness

2015

Resumen Los emprendedores sociales están ganando cierto reconocimiento como uno de los agentes de cambio social más importantes. Aun así, poco se conoce sobre sus motivaciones y el proceso a través del cual sus ideas se conciben y desarrollan. En este trabajo se analiza el proceso de descubrimiento de oportunidades en el caso de los emprendedores sociales, partiendo de la teoría del descubrimiento y del concepto de alerta emprendedora que, en este caso, rebautizamos como alerta social. Para ello se estudia el papel de la formación y la experiencia previa del emprendedor, la cercanía a otros emprendedores y la cercanía al problema social como variables relacionadas con la alerta social. Dada…

discovery theory social alertnessentrepreneur knowledgeComputingMilieux_THECOMPUTINGPROFESSIONTeoría del descubrimientocloseness to other entrepreneursEmprendedor socialSocial alertnessEntrepreneur knowledgeCercanía a emprendedoresDiscovery theoryConocimiento emprendedorCloseness to other entrepreneursSocial entrepreneurcloseness to social problemCloseness to social problemalerta socialAlerta sociallcsh:H1-99cercanía a emprendedoreslcsh:Social sciences (General)conocimiento emprendedorteoría del descubrimientocercanía al problema social.Cercanía al problema social
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A Top-Down Approach Based on the Circularity Potential to Increase the Use of Reclaimed Asphalt

2023

Resource depletion and climate change, amongst others, are increasingly worrying environmental challenges for which the road engineering sector is a major contributor. Globally, viable solutions that comply with the principles of circular economy (CE) are being investigated that can replace conventional asphalt mixtures in a post-fossil fuel society. The use of reclaimed asphalt (RA) is a widely used and well-established method to reduce the environmental and economic impacts of asphalt mixtures while increasing their circularity. However, RA’s market supply and demand have not yet been systematically analyzed and established. Moreover, the actual circularity potential and the opportu…

end of wasteasphaltclosed-loopCircular economyreclaimed asphaltcircular economy; reclaimed asphalt; closed-loop; end of waste; asphalt; material circularity indicatormaterial circularity indicatorGeneral Materials ScienceBuilding and ConstructionGeotechnical Engineering and Engineering GeologyComputer Science ApplicationsCivil and Structural EngineeringInfrastructures; Volume 8; Issue 5; Pages: 83
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The genetic mechanism of fallness: St. Maximos the Confessor revisited

2022

Through a close reading of the two definitions of evil in the Introduction to Responses to Thalassios , this article points out a circular, cognitive-affective-somatic, genetic mechanism that St. Maximos the Confessor considers responsible for the initiation and transmission of the fallness as a human condition and the specific manifestation of it in the form of passions. It elucidates the first definition as mainly phenomenological, by identifying the circular mechanism and its behavioural expressions, and the second definition as more aetiological, by explaining why this mechanism emerges and reemerges with the fallen humanity despite its catastrophic results. Contribution: This article h…

fallness; passions; philautia; responses to Thalassios; Maximos the Confessor.CursePhilosophyBS1-2970Religious studiesPassionsHuman conditionfallnessPractical Theologymaximos the confessorEpistemologyScholarshippassionsphilautiaresponses to thalassiosBV1-5099Close readingHumanityThe BibleMechanism (sociology)HTS Teologiese Studies/Theological Studies
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