Search results for "Coherence"

showing 10 items of 905 documents

Triterpenoid saponins from Piptadeniastrum africanum (Hook. f.) Brenan

2013

One new triterpenoid saponin, named piptadeniaoside (1), along with two known saponins (2–3) have been isolated from the stem bark of Piptadeniastrum africanum. After previous isolation of flavone derivatives from this plant, new phytochemical investigations were performed for its saponin content. Their structures were established by direct interpretation of their spectral data, mainly HRESIMS, 1D NMR (1H, 13C NMR, DEPT) and 2D NMR (COSY, NOESY, HSQC and HMBC), and by comparison with the literature data.

chemistry.chemical_classificationTraditional medicineChemistryStereochemistrySaponinPlant ScienceDEPTCarbon-13 NMRBiochemistrychemistry.chemical_compoundPhytochemicalAgronomy and Crop ScienceTwo-dimensional nuclear magnetic resonance spectroscopyOleanolic acidHeteronuclear single quantum coherence spectroscopyBiotechnologyTriterpenoid saponinPhytochemistry Letters
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Foetidissimosides C–F, Novel Glycosides from the Roots ofCucurbita foetidissima

2004

Two novel echinocystic acid (=(3β,16α)-3,16-dihydroxyolean-12-en-28-oic acid) glycosides, foetidissimosides C (1), and D (2), along with new cucurbitane glycosides, i.e., foetidissimosides E/F (3/4) as an 1 : 1 mixture of the (24R)/(24S) epimers, were obtained from the roots of Cucurbita foetidissima. Their structures were elucidated by means of a combination of homo- and heteronuclear 2D-NMR techniques (COSY, TOCSY, NOESY, ROESY, HSQC, and HMBC), and by FAB-MS. The new compounds were characterized as (3β,16α)-28-{[O-β-D-glucopyranosyl-(13)-O-β-D-xylopyranosyl-(14)-O-6-deoxy-α-L-mannopyranosyl-(12)-α-L-arabinopyranosyl]oxy}-16-hydroxy-28-oxoolean -12-en-3-yl β-D-glucopyranosiduronic acid (1…

chemistry.chemical_classificationbiologyChemistryStereochemistryOrganic ChemistryGlycosideCucurbitanebiology.organism_classificationBiochemistryCatalysisInorganic Chemistrychemistry.chemical_compoundHeteronuclear moleculeDrug DiscoveryEpimerCucurbita foetidissimaPhysical and Theoretical ChemistryEchinocystic acidTwo-dimensional nuclear magnetic resonance spectroscopyHeteronuclear single quantum coherence spectroscopyHelvetica Chimica Acta
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Foetidissimosides C—F, Novel Glycosides from the Roots of Cucurbita foetidissima.

2004

Two novel echinocystic acid (=(3β,16α)-3,16-dihydroxyolean-12-en-28-oic acid) glycosides, foetidissimosides C (1), and D (2), along with new cucurbitane glycosides, i.e., foetidissimosides E/F (3/4) as an 1 : 1 mixture of the (24R)/(24S) epimers, were obtained from the roots of Cucurbita foetidissima. Their structures were elucidated by means of a combination of homo- and heteronuclear 2D-NMR techniques (COSY, TOCSY, NOESY, ROESY, HSQC, and HMBC), and by FAB-MS. The new compounds were characterized as (3β,16α)-28-{[O-β-D-glucopyranosyl-(13)-O-β-D-xylopyranosyl-(14)-O-6-deoxy-α-L-mannopyranosyl-(12)-α-L-arabinopyranosyl]oxy}-16-hydroxy-28-oxoolean -12-en-3-yl β-D-glucopyranosiduronic acid (1…

chemistry.chemical_classificationbiologyStereochemistryGlycosideGeneral Medicinebiology.organism_classificationCucurbitanechemistry.chemical_compoundchemistryHeteronuclear moleculeCucurbita foetidissimaEpimerEchinocystic acidTwo-dimensional nuclear magnetic resonance spectroscopyHeteronuclear single quantum coherence spectroscopyChemInform
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Relationship of choroidal thickness with pulsatile hemodynamics in essential hypertensive patients

2021

Controversy exists about the association of choroidal thickness (CTh) with blood pressure (BP) values. There is some evidence suggesting that central hemodynamics changes are associated with microvascular disease. Our study was aimed to assess the relationships between CTh and clinic and 24-h BP and between CTh and estimated 24-h aortic pulse pressure (aPP), 24-h aortic systolic BP (aSBP), and 24-h aortic augmentation index (aAIx) in a group of hypertensive patients. We enrolled 158 hypertensive subjects (mean age 48 ± 13 years) all of which underwent evaluation of the choroidal district by Swept-Source optical coherence tomography (SS-OCT) and 24-h BP monitoring, in order to measure periph…

choroidal thicknessmedicine.medical_specialtySettore MED/09 - Medicina InternaEndocrinology Diabetes and MetabolismPulsatile flowmicrocirculationHemodynamics030204 cardiovascular system & hematologyhypertensive eye diseaseaortic pressure cardiovascular disease central hemodynamics choroidal thickness hypertensive eye disease optical coherence tomographyMicrocirculation03 medical and health sciences0302 clinical medicinecardiovascular diseaseInternal medicineInternal MedicineHumansMedicine030212 general & internal medicineAortic Pulse PressureAortaSettore MED/14 - NefrologiaOriginal Paperoptical coherence tomographyChoroidSettore MED/30 - Malattie Apparato Visivobusiness.industryHemodynamicsAortic Augmentation IndexBlood pressuremedicine.anatomical_structureHypertensionaortic pressureCardiologyAortic pressureChoroidEssential HypertensionCardiology and Cardiovascular Medicinebusinesscentral hemodynamicsPulsatile HaemodynamicsThe Journal of Clinical Hypertension
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Emergent ultrafast phenomena in correlated oxides and heterostructures

2017

The possibility of investigating the dynamics of solids on timescales faster than the thermalization of the internal degrees of freedom has disclosed novel non-equilibrium phenomena that have no counterpart at equilibrium. Transition metal oxides (TMOs) provide an interesting playground in which the correlations among the charges in the metal $d$-orbitals give rise to a wealth of intriguing electronic and thermodynamic properties involving the spin, charge, lattice and orbital orders. Furthermore, the physical properties of TMOs can be engineered at the atomic level, thus providing the platform to investigate the transport phenomena on timescales of the order of the intrinsic decoherence ti…

coherent transportFOS: Physical sciences02 engineering and technologySettore FIS/03 - FISICA DELLA MATERIA01 natural sciencesCondensed Matter - Strongly Correlated ElectronsPhysics and Astronomy (all)electronic coherenceTransition metalAtomic and Molecular PhysicsLattice (order)0103 physical sciencesMesoscale and Nanoscale Physics (cond-mat.mes-hall)coherent transport; electronic coherence; heterostructures; photon harvesting; pump probe; transition metal oxides; ultrafast dynamics; Atomic and Molecular Physics and Optics; Mathematical Physics; Condensed Matter Physics; Physics and Astronomy (all)transition metal oxides010306 general physicsAnisotropyQuantumMathematical PhysicsPhysicsCondensed Matter - Materials ScienceCondensed Matter - Mesoscale and Nanoscale PhysicsStrongly Correlated Electrons (cond-mat.str-el)Mott insulatorMaterials Science (cond-mat.mtrl-sci)Heterojunction021001 nanoscience & nanotechnologyCondensed Matter PhysicsAtomic and Molecular Physics and Opticsultrafast dynamicsThermalisationheterostructuresChemical physicsphoton harvestingpump probeand Optics0210 nano-technologyTransport phenomenacoherent transport; electronic coherence; heterostructures; photon harvesting; pump probe; transition metal oxides; ultrafast dynamics;
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Factors related to the difficulty of reading comprehension texts in the matriculation examination English tests

1997

cohesiontext linguisticsreadabilitytext typematriculation examinationreading comprehensioncoherence
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ALIGNEMENT UNI ET TRIDIMENSIONNEL DE MOLÉCULES PAR IMPULSION LASER FEMTOSECONDE

2007

This thesis is devoted to the study of the alignment of linear and asymmetric top molecules generated by an intense laser pulse. In the case of short pulses with respect to molecular rotation, periodic alignment appears in field-free conditions after the extinction of the field. We study theoretically and experimentally the effects of intensity, temperature and polarization of the electric field on produced alignment. If the field is linearly polarized, the interaction leads to the alignment of the most polarizable axis of the molecule. If the field is elliptically polarized, the pulse can generate a simultaneous alignment of the three principal axes of inertia of an asymmetric top molecule…

cohérence rotationnelleMolecular alignmenteffet Kerr optique.[PHYS.PHYS.PHYS-ATOM-PH]Physics [physics]/Physics [physics]/Atomic Physics [physics.atom-ph][ PHYS.PHYS.PHYS-ATOM-PH ] Physics [physics]/Physics [physics]/Atomic Physics [physics.atom-ph]Alignement moléculairebiréfringenceimpulsion ultrabrèveoptical Kerr effect.Pump-probe techniquelinear and asymmetric top moleculesmolécules linéaires et asymétriquestechniques pompe-sondeultrashort laser pulse[PHYS.PHYS.PHYS-ATOM-PH] Physics [physics]/Physics [physics]/Atomic Physics [physics.atom-ph]rotational coherenceeffet Kerr optique
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From imprecise probability assessments to conditional probabilities with quasi additive classes of conditioning events

2012

In this paper, starting from a generalized coherent (i.e. avoiding uniform loss) intervalvalued probability assessment on a finite family of conditional events, we construct conditional probabilities with quasi additive classes of conditioning events which are consistent with the given initial assessment. Quasi additivity assures coherence for the obtained conditional probabilities. In order to reach our goal we define a finite sequence of conditional probabilities by exploiting some theoretical results on g-coherence. In particular, we use solutions of a finite sequence of linear systems.

conditional eventFOS: Computer and information sciencesSettore MAT/06 - Probabilita' E Statistica MatematicaArtificial Intelligence (cs.AI)Computer Science - Artificial Intelligencequasi additivityProbability (math.PR)FOS: MathematicsG-coherenceconditional probabilityinterval-valued probability assessmentMathematics - Probability
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Imprecise probability assessments and the Square of Opposition

There is a long history of investigations on the square of opposition spanning over two millenia. A square of opposition represents logical relations among basic sentence types in a diagrammatic way. The basic sentence types, traditionally denoted by A (universal affirmative: ''Every S is P''), E (universal negative: ''No S is P''), I (particular affirmative: ''Some S are P''), and O (particular negative: ''Some S are not P''), constitute the corners of the square, and the logical relations--contradiction, contrarity, subalternation, and sub-contrarity--form the diagonals and the sides of the square. We investigate the square of opposition from a probabilistic point of view. To manage impre…

conditional eventimprecise probabilityg-coherenceSquare of oppositionSettore MAT/06 - Probabilita' E Statistica Matematicat-coherencegeneralized quantifierSettore MAT/01 - Logica Matematicaacceptance
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Probabilistic Logic under Coherence: Complexity and Algorithms

2005

In previous work [V. Biazzo, A. Gilio, T. Lukasiewicz and G. Sanfilippo, Probabilistic logic under coherence, model-theoretic probabilistic logic, and default reasoning in System P, Journal of Applied Non-Classical Logics 12(2) (2002) 189---213.], we have explored the relationship between probabilistic reasoning under coherence and model-theoretic probabilistic reasoning. In particular, we have shown that the notions of g-coherence and of g-coherent entailment in probabilistic reasoning under coherence can be expressed by combining notions in model-theoretic probabilistic reasoning with concepts from default reasoning. In this paper, we continue this line of research. Based on the above sem…

conditional probability assessmentSettore MAT/06 - Probabilita' E Statistica MatematicaDivergence-from-randomness modelalgorithmsprobabilistic logicConditional probability assessments; probabilistic logic; g-coherence; g-coherent entailment; complexity and algorithms.Artificial IntelligenceProbabilistic logic networkprobabilistic logic under coherenceConditional probability assessmentsProbabilistic analysis of algorithmsNon-monotonic logicconditional constraintMathematicsg-coherent entailmentConditional probability assessments probabilistic logic g-coherence g-coherent entailment complexity and algorithms.Reasoning systemcomputational complexitymodel-theoretic probabilistic logicApplied Mathematicscomplexity and algorithmsProbabilistic logiclogical constraintProbabilistic argumentationg-coherenceconditional probability assessment logical constraint conditional constraint probabilistic logic under coherence model-theoretic probabilistic logic g-coherence g-coherent entailment computational complexity algorithmsProbabilistic CTLalgorithms; computational complexity; conditional constraint; conditional probability assessment; g-coherence; g-coherent entailment; logical constraint; model-theoretic probabilistic logic; probabilistic logic under coherenceAlgorithmAnnals of Mathematics and Artificial Intelligence
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