Search results for "Complex Mixture"
showing 10 items of 826 documents
Phase separation of binary mixtures in thin films: Effects of an initial concentration gradient across the film.
2012
We study the kinetics of phase separation of a binary (A,B) mixture confined in a thin film of thickness $D$ by numerical simulations of the corresponding Cahn-Hilliard-Cook (CHC) model. The initial state consisted of 50$%$ A:50$%$ B with a concentration gradient across the film, i.e., the average order parameter profile is ${\ensuremath{\Psi}}_{\mathrm{av}}(z,t=0)=(2z/D\ensuremath{-}1){\ensuremath{\Psi}}_{g},\phantom{\rule{0.28em}{0ex}}0\ensuremath{\leqslant}z\ensuremath{\leqslant}D$, for various choices of ${\ensuremath{\Psi}}_{g}$ and $D$. The equilibrium state (for time $t\ensuremath{\rightarrow}\ensuremath{\infty}$) consists of coexisting A-rich and B-rich domains separated by interfac…
VAPORIZATION CHARACTERISTICS OF ETHANOL AND 1-PROPANOL DROPLETS AT HIGH TEMPERATURES
2012
International audience; A detailed description of the vaporization of an isolated droplet has been carried out in this experimental study aimed at investigating ethanol and another aliphatic alcohol, 1-propanol. The characterization of the vaporization phenomenon is necessary for this liquid fuel to develop efficient design of injection systems for propulsion and power generation. Particularly, the vaporization rates and their dependency on temperature, important features for modeling and design, are explored for both ethanol and 1-propanol at intermediate to high temperatures. The experimental setup consists of a pressure chamber in which the furnace, the droplet formation, the droplet sup…
Preparation and characterization of continuous fly ash derived glass fibers with improved tensile strength
2018
Abstract The coal-based energy production in China generates more than 600 million tons of coal fly ash (CFA) each year, which drives us searching for new methods for recycling CFA. In this work, continuous glass fibers with a range of CFA (25–45%) were successfully prepared without showing any sign of fiber crystallization. The measured fiber tensile strength was found to increase with CFA proportionally. The fiber derived from 45% CFA exhibited the best tensile strength (higher than the E glass fiber prepared/tested under the same conditions) and good chemical stability (98% mass retention in the acid corrosion test). Our study shows a feasibility of making continuous CFA derived glass fi…
Mass absorption indices of various types of natural aerosol particles in the infrared
2010
The mass absorption index of aerosol particles has been measured in the 2-17-microm wavelength region. The measurements were performed on films of aerosol particles that were collected by an automatic jet impactor at polluted and various uncontaminated remote sites. All but marine aerosols possess strong absorption bands in the transparent part of the atmospheric long-wave spectrum, indicating marked influence of aerosol particles on the radiation budget of the atmosphere.
Morphology and Properties of Polyethylene/Clay Nanocomposite Drawn Fibers
2008
The influence of an elongational flow on the morphology of PE/clay nanocomposite drawn fibers was studied. An increase of the elastic modulus and the tensile strength as well as a decrease of the elongation at break are observed with increasing draw ratio. The applied elongational gradient orients the polymer chains and the clay particles along the spinning direction. When the applied flow results in the formation and the orientation of exfoliated nanoparticles, a pronounced increase of the mechanical properties is observed. The dispersed clay particles can be broken and oriented by the extensional flow, which might indicate a flow induced intercalated/exfoliated morphology transition.
Optimization of Cell Growth on Bacterial Cellulose by Adsorption of Collagen and Poly-L-Lysine
2015
Poly-L-lysine and collagen were separately added to bacterial cellulose (BC) nanofibers. The ionic surface charge had been previously modified in order to promote the adsorption of poly-L-lysine and collagen. Cell adhesion of Chinese hamster ovary (CHO) cells on BC surfaces was confirmed by removing unattached cells from the BC substrates. Cell viability was calculated and it was determined that both poly-L-lysine-BC and collagen-BC substrates are viable for cell growth. The results showed that the cell viability in poly-L-lysine modified BC substrate is similar to the one observed in polystyrene tissue culture plates.
Study of methyl methacrylate polymerization in the presence of rubbers
2001
Grafting of poly(methylmethacrylate) onto various unsaturated rubbers is described. The grafting is achieved through thermally initiated methylmethacrylate in-situ polymerization. The main features of the polymerization process, i.e. conversion vs. time, grafting to rubber and gel percentage, have been investigated. The chemical structure of the rubber influences the process: rubber with pendant unsaturations gives rise to higher level of grafting.
Hydrogel films engineered in a mesoscopically ordered structure and responsive to ethanol vapors
2014
Abstract Responsive hydrogels filling the interstitial spaces of photonic crystals can form mesoscopically structured materials, which exhibit reversible shifts in the Bragg diffracted light as a response of environmental changes. These materials can be used to generate chemical or biochemical sensors. The present work reports on the synthesis and characterization of ethanol responsive hydrogels that can be used in the design of novel breathalyzers. The dynamic mechanical behavior of the macroscopic hydrogels and their swelling features in the presence of different liquids or vapors have been investigated to orientate the choice of the best responsive material and curing process. The swelli…
Mapping Ash CaCO3, pH, and Extractable Elements Using Principal Component Analysis
2017
Abstract Ash cover in fire-affected areas is an important factor in the reduction of soil erosion and increased availability of soil nutrients. Thus it is important to understand the spatial distribution of ash and its capacity for soil protection and to provide nutrients to the underlying soil. In this work, we aimed to map ash CaCO3, pH, and select extractable elements using a principal component analysis (PCA). Four days after a medium to severe wildfire, we established a grid in a 9 ×27 m area on a west facing slope and took ash samples every 3 m for a total of 40 sampling points. The PCA carried out retained five different factors. Factor 1 had high positive loadings for ash with elect…
Humidity effects on gravitational settling and Brownian diffusion of atmospheric aerosol particles
1977
The dependency on relative humidity of the settling velocity of aerosol particles in stagnant air and of the diffusion coefficient due to Brownian motion of aerosol particles was computed for six aerosol types and different particles sizes in dry state. The computations are based (1) on mean bulk densities of dry aerosol particles obtained from measurements or from the knowledge of the chemical composition of the particles, (2) on micro-balance measurements of the water uptake per unit mass of dry aerosol substance versus water activity at thermodynamic equilibrium, and (3) on measurements of the equilibrium water activity of aqueous sea salt solutions. The results show a significant depend…