Search results for "Complex."
showing 10 items of 5824 documents
Weighting non-covalent forces in the molecular recognition of C60. Relevance of concave–convex complementarity
2008
The relative contributions of several weak intermolecular forces to the overall stability of the complexes formed between structurally related receptors and [60]fullerene are compared, revealing a discernible contribution from concave–convex complementarity. Viruela Martin, Pedro Manuel, Pedro.M.Viruela@uv.es ; Viruela Martin, Rafael, Rafael.Viruela@uv.es ; Orti Guillen, Enrique, Enrique.Orti@uv.es
Detection of the Lowest-Lying Odd-Parity Atomic Levels in Actinium
2020
Two lowest-energy odd-parity atomic levels of actinium, 7s27pP21/2o, 7s27pP23/2o, were observed via two-step resonant laser-ionization spectroscopy and their respective energies were measured to be 7477.36(4) and 12 276.59(2) cm-1. The lifetimes of these states were determined as 668(11) and 255(7) ns, respectively. In addition, we observed the effect of the hyperfine structure on the line for the transition to P23/2o. These properties were calculated using a hybrid approach that combines configuration interaction and coupled-cluster methods, in good agreement with the experiment. The data are of relevance for understanding the complex atomic spectra of actinides and for developing efficien…
Electrical characterization of deoxyribonucleic acid hybridization in metal-oxide-semiconductor-like structures
2012
In this work, metal-oxide-semiconductor (MOS)-like sensors in which deoxyribonucleic acid (DNA) strands are covalently immobilized either on Si oxide or on a gold surface were electrically characterized. Si oxide fabrication process allowed us to have a surface insensitive to the solution pH. A significant shift in the flat band voltage was measured after single strand DNA immobilization (+0.47 +/- 0.04 V) and after the complementary strand binding (+0.07 +/- 0.02 V). The results show that DNA sensing can be performed using a MOS structure which can be easily integrated in a more complex design, thus avoiding the problems related to the integration of micro-electrochemical cells.
Metal-organic magnets with large coercivity and ordering temperatures up to 242°C.
2020
International audience; Magnets derived from inorganic materials (e.g., oxides, rare-earth–based, and intermetallic compounds) are key components of modern technological applications. Despite considerable success in a broad range of applications, these inorganic magnets suffer several drawbacks, including energetically expensive fabrication, limited availability of certain constituent elements, high density, and poor scope for chemical tunability. A promising design strategy for next-generation magnets relies on the versatile coordination chemistry of abundant metal ions and inexpensive organic ligands. Following this approach, we report the general, simple, and efficient synthesis of light…
Fascioliasis transmission by Lymnaea neotropica confirmed by nuclear rDNA and mtDNA sequencing in Argentina
2009
Fascioliasis is widespread in livestock in Argentina. Among activities included in a long-term initiative to ascertain which are the fascioliasis areas of most concern, studies were performed in a recreational farm, including liver fluke infection in different domestic animal species, classification of the lymnaeid vector and verification of natural transmission of fascioliasis by identification of the intramolluscan trematode larval stages found in naturally infected snails. The high prevalences in the domestic animals appeared related to only one lymnaeid species present. Lymnaeid and trematode classification was verified by means of nuclear ribosomal DNA and mitochondrial DNA marker sequ…
A short proof of the self-improving regularity of quasiregular mappings
2005
. The theoryof quasiregular mappings is a central topic in modern analysis withimportant connections to a variety of topics as elliptic partial differen-tial equations, complex dynamics, differential geometry and calculus ofvariations [13] [10].A remarkable feature of quasiregular mappings is the self-improvingregularity. In 1957 [2], Bojarski proved that for planar quasiregularmappings, there exists an exponent
Age and evolution of late Mesozoic metamorphic core complexes in southern Siberia and northern Mongolia
2008
Numerous Cretaceous metamorphic core complexes (MCCs) extend from Transbaikalia in Russia to northern Mongolia within the Central Asian Orogenic Belt. We investigated the Buteel and Zagan MCCs in detail. Shear sense indicators in mylonitized rocks show footwall-to-the-NW tectonic transport. Single zircon dating of footwall rocks in the Buteel MCC establishes the emplacement of granitoid orthogneiss precursors at 240–211 Ma, a felsic metavolcanic rock at 265.0 ± 1.2 Ma, a syenite at 265.5 ± 1.2 Ma and a metarhyolite of the pre-granitoid basement at 553.6 ± 2.9 Ma. A peralkaline granite intruding orthogneisses of the Zagan MCC has a new U–Pb zircon age of 151.6 ± 0.7 Ma. 40Ar/39Ar ages of 133…
Field and petrographic evidence for partial melting of TTG gneisses from the central region of the mainland Lewisian complex, NW Scotland
2013
The central region of the mainland Lewisian complex is dominated by granulite-facies tonalite–trondhjemite–granodiorite (TTG) gneisses that are highly depleted in some mobile trace elements (Cs, Rb, Th and U) relative to amphibolite-facies TTG gneisses elsewhere in the Lewisian complex and to the average composition of TTG gneisses worldwide. Over almost half a century of research there has been vigorous debate as to the origin of this depletion, in particular with respect to the role of partial melting and melt loss. Here we provide field and petrographic evidence that TTG gneisses across the central region partially melted during granulite-facies (Badcallian) metamorphism. Partial melting…
Quotients of Fermat curves and a Hecke character
2005
AbstractWe explicitly identify infinitely many curves which are quotients of Fermat curves. We show that some of these have simple Jacobians with complex multiplication by a non-cyclotomic field. For a particular case we determine the local zeta functions with two independent methods. The first uses Jacobi sums and the second applies the general theory of complex multiplication, we verify that both methods give the same result.
Oxidative stress induces the expression of the major histocompatibility complex in murine tumor cells.
2001
The effect of t-butyl hydroperoxide (t-BOOH) on the induction of the Major Histocompatibility Complex (MHC) class I genes has been studied in two cell clones (B9 and G2) of the methylcholanthrene-induced murine fibrosarcoma GR9. These two clones were selected based on their different biological and biochemical behavior specially related to their tumor induction capability when injected into a BALB/c mouse. t-BOOH (0.125 mM) induced the expression of H-2 molecules in both cell clones. In B9 cell clone, in which MHC basal expression is very low or absent, t-BOOH significantly induced H-2Kd, H-2Dd and H-2Ld molecules. In G2 cell clone the expression of MHC class I genes was also enhanced by th…