Search results for "Composite"
showing 10 items of 4584 documents
The S … Hal and Se … Hal chalcogen bonding in a series of thiourea, selenourea and their derivatives
2021
The chalcogen bonding (ChB) in a series of thiourea, selenourea and their derivatives has been investigated in the present paper. Thus, selenourea and dimethylselenourea undergo dimerization and trimerization processes in the presence of various halogen species (1–5). Selenourea and dimethylselenourea form trimers 3–4 in the presence of lighter halogens (chlorine and bromine) through Se⋯Se chalcogen bonding. When moving to heavier halogen (iodine), the dimers 1–2 are formed. Thiourea and its derivatives also tend to make very strong S⋯S bonds and form dimers in the case of lighter halogens chlorine and bromine (compounds 6–7). However, the monomers separated by the iodine species are formed…
Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation
2022
Reductive debromination of the tribromoamidosilane 2 gave the tetracyclic silaheterocycle 3 through a unique reaction cascade involving unprecedented two-fold intramolecular cycloaddition by transient silylenes. Experimental and computational analyses of the reaction mechanism allowed the identification of the key intermediates that lead to the silaheterocycle 3 or, alternatively, to the cyclotrisilene 19. peerReviewed
Tribological properties of thin films made by atomic layer deposition sliding against silicon
2018
Interfacial phenomena, such as adhesion, friction, and wear, can dominate the performance and reliability of microelectromechanical (MEMS) devices. Here, thin films made by atomic layer deposition (ALD) were tested for their tribological properties. Tribological tests were carried out with silicon counterpart sliding against ALD thin films in order to simulate the contacts occurring in the MEMS devices. The counterpart was sliding in a linear reciprocating motion against the ALD films with the total sliding distances of 5 and 20 m. Al2O3 and TiO2 coatings with different deposition temperatures were investigated in addition to Al2O3-TiO2-nanolaminate, TiN, NbN, TiAlCN, a-C:H [diamondlike car…
Effects of hydrogen-charging on the properties of S235JR steel
2017
The paper presents the test results of the S235JR steel susceptibility to damage under the influence of hydrogen. The test of mechanical properties was performed on the basis of a static stretch test of non-hydrogenated samples and after cathodic polarization. Electrochemical measurements for the assessment of corrosion resistance of non-hydrogenated and hydrogenated steels were carried out using open circuit potential measurement and registering of potentiodynamic polarization curves in a three-electrode measuring system. Hydrogenation was carried out for between 3 and 24 hours in a solution of 0.1 N sulfuric acid (VI) with the addition of 2 mg/dm 3 of arsenic oxide (III) at an electric cu…
Suction controlled drying and wetting cycle effects on the volumetric behaviour of a lime-treated high plasticity clay
2016
The paper presents some experimental results collected on samples recovered from an experimental embankment obtained by compacting a lime-treated clay. Samples were collected soon after the in situ compaction and they were cured in controlled environmental conditions for at least 18 months. Mercury intrusion porosimetry tests (MIP) were carried out on freeze-dried specimens to characterize the microstructure of the material. In order to assess the durability of the improved material, laboratory tests focused on the effects of cyclic variations of the degree of saturation on the water retention properties and the volumetric behaviour of the stabilized clay. Collected results show that the li…
Accuracy of Saturated Soil Hydraulic Conductivity Estimated from Numerically Simulated Single‐Ring Infiltrations
2019
The single-ring pressure infiltrometer (PI) method is widely used to determine saturated soil hydraulic conductivity, K s , directly in the field. The original and still most common way to analyze the data makes use of the steady-state model developed by the Canadian School in the 90s and two (two-ponding-depth, TPD, approach) or more (multiple-ponding-depth, MPD, approach) depths of ponding. The so-called Wu method based on a generalized infiltration equation allows analysis of the transient infiltration data collected by establishing a single ponding depth of water on the infiltration surface. This investigation, making use of simulated infiltration runs for initially unsaturated sand to …
STRATIFICATION TECHNIQUE OF A NANOCOMPOSITE USING THE SILICON GUIDE
2015
At present, the stratification technique of composite materials, known as offering most predictable, both functional and aesthetic results, uses a silicone reference quide. This allows the dentist to appreciate the size and thickness of the composite resin layer to be applied, as well as selection of the opacity and translucidity degree according to the reconstructed enamel or dentin structure, thus facilitating the stratification of materials. The minimum adjustment, at the level of the palatal wall, represents another great advantage of the silicone key.
Optimizing the Shape of Welded Constructions Made through the Technique “Temper Bead Welding”
2020
Welded constructions are subject to high stresses during operation. One solution for improving the behavior in exploitation of welded constructions in various cases is to use the welding technique “temper bead welding” (TBW). In the paper, the optimization of the geometry of the welded joints by the TBW technique was performed. Thus, corner welded joints made of S355 steel were analyzed. To make the welded joints, three layers of welding seams were deposited, and the intermediate layers were processed through cutting with various radii. To analyze the influence of the size of these rays on the behavior of welded constructions, a research program based on factorial experiences wa…
A Study of Mechanical Properties of Polymer Composite Membranes with Various Ionic Liquids at Elevated Temperatures
2019
This work was supported by Latvian Council of Science (Cooperation project No.666/2014.4).
Green approach to corrosion inhibition of stainless steel in phosphoric acid of Artemesia herba albamedium using plant extract
2019
Essential oil from aerial parts of Artemisia herba-alba from Morocco was hydrodistilled and its chemical composition oil was investigated by capillary GC and GC/MS. The major components were 1,8-cineole (35.6%) and camphor (24.1%). Artemisia herba-alba essential oil AHAO was tested as corrosion inhibitor of stainless steel (SS) in 1M H3PO4 using potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy measurements (EIS) and scanning electronically microscopy (SEM) studies. The results obtained showed that the essential oil of Artemisia reduces the corrosion rate. Tafel polarization method indicates that the plant extract behaves as a mixed type inhibitor. The inhibition…