Search results for "Composites"

Electrocatalysis of neurotransmitter catecholamines by 2,4,6-triphenylpyrylium ion immobilized inside zeolite Y supercages

1999

2,4,6-Triphenylpyrylium ions entrapped inside the supercages of Y zeolite exert a remarkable catalytic effect toward the electrochemical oxidation of dopamine and norepinephrine (neurotrasmitter catecholamines) in neutral aqueous media. Domenech Carbo, Antonio, Antonio.Domenech@uv.es

A plasma protein corona enhances the biocompatibility of Au@Fe3O4 Janus particles

2015

AbstractAu@Fe3O4 Janus particles (JPs) are heteroparticles with discrete domains defined by different materials. Their tunable composition and morphology confer multimodal and versatile capabilities for use as contrast agents and drug carriers in future medicine. Au@Fe3O4 JPs have colloidal properties and surface characteristics leading to interactions with proteins in biological fluids. The resulting protein adsorption layer (“protein corona”) critically affects their interaction with living matter. Although Au@Fe3O4 JPs displayed good biocompatibility in a standardized in vitro situation, an in-depth characterization of the protein corona is of prime importance to unravel underlying mecha…

Flexible Perfluoropolyethers-Functionalized CNTs-Based UHMWPE Composites: A Study on Hydrogen Evolution, Conductivity and Thermal Stability

2022

Flexible conductive composites based on ultra-high molecular weight polyethylene (UHMWPE) filled with multi-walled carbon nanotubes (CNTs) modified by perfluoropolyethers (PFPEs) were produced. The bonding of PFPE chains, added in 1:1 and 2:1 weight ratios, on CNTs influences the dispersion of nanotubes in the UHMWPE matrix due to the non-polar nature of the polymer, facilitating the formation of nanofillers-rich conductive pathways and improving composites’ electrical conductivity (two to five orders of magnitude more) in comparison to UHMWPE-based nanocomposites obtained with pristine CNTs. Electrochemical atomic force microscopy (EC-AFM) was used to evaluate the morphological changes dur…

Engineering a morphogenetically active hydrogel for bioprinting of bioartificial tissue derived from human osteoblast-like SaOS-2 cells.

2014

Abstract Sodium alginate hydrogel, stabilized with gelatin, is a suitable, biologically inert matrix that can be used for encapsulating and 3D bioprinting of bone-related SaOS-2 cells. However, the cells, embedded in this matrix, remain in a non-proliferating state. Here we show that addition of an overlay onto the bioprinted alginate/gelatine/SaOS-2 cell scaffold, consisting of agarose and the calcium salt of polyphosphate [polyP·Ca 2+ -complex], resulted in a marked increase in cell proliferation . In the presence of 100 μ m polyP·Ca2+ -complex, the cells proliferate with a generation time of approximately 47–55 h. In addition, the hardness of the alginate/gelatin hydrogel substantially i…

Free vibrations analysis of cracked variable stiffness composite plates by the eXtended Ritz method

2022

Variable stiffness composite laminates show advantageous structural features related to their enlarged design space. They are attractive candidates for advanced engineering applications where the assessment of static and dynamic behavior and strength in the presence of cracks is often required. In the present work, a single-domain extended Ritz formulation is proposed to study the free vibrations of cracked variable stiffness composite plates. The plate model is based on the first-order shear deformation theory whose primary variable, i.e. displacements and rotations, are approximated via a set of orthogonal polynomial trial functions enriched with a set of special crack functions. These fu…

Statistical analysis of the performances of PC/CNTs nanocomposites

2013

Clay nanocomposites based on functionalized polyethylene. Effect of the clay modifier and the preparation conditions

2009

INTERACTIONS BETWEEN FUNCTIONALIZED THERMOPLASTIC ELASTOMER AND LAYERED DOUBLE HYDROXIDES

2016

Results coming from rheological analysis clearly suggest that in SEBS-g-MA-based nanocomposites, containing high amount of o-LDH, the formation of strong interactions between the dispersed nanoparticles and maleic functionalities of matrix occurs. A significant modification of the rheological behaviour can be noticed due to the formation of gel-like structures.

Guías ópticas activas de polímero con puntos cuánticos coloidales

2013

En este trabajo se propone la integración de nanoparticulas semiconductoras coloidales en matrices de polímero para desarrollar nanocomposites que puedan ser utilizados en nuevos dispositivos fotónicos, y en particular como núcleos de guías de onda activas. De esta manera se dispersaron distintas familias de QDs (de CdSe, CdTe, CdS y PbS) y QRs (CdSe-CdS y PbS-CdS) en matrices de polímero (PMMA y SU-8), con el fin de demostrar que los nanocomposites elaborados a partir de estos materiales pueden funcionar como núcleos en guías de onda. En primer lugar se fabricaron y caracterizaron guías de onda planas, estudiando la dependencia de las propiedades de propagación de la luz con la concentraci…

Triggering a transient organo-gelation system in a chemically active solvent

2021

A transient organo-gelation system with spatiotemporal dynamic properties is described. Here, the solvent actively controls a complex set of equilibria that underpin the dynamic assembly event. The observed metastability is due to the in situ formation of a secondary solvent, acting as an antagonist against the primary solvent of the organogel. peerReviewed