Search results for "Condensation"
showing 10 items of 468 documents
Fibre post behaviour prediction factors. A review of the literature
2013
Introduction: The advantages of fibre posts over stainless steel posts have been demonstrated in numerous studies. For clinical success, various factors need to be taken into account in post-retained restorations. Material and Methods: A review was made of literature on fibre posts published from 2000 to February 2011, identified through searches of the PubMed/Medline databases. Results: The position of the tooth in the arch, ferrule size, proximal contact, periodontal support and restoration type are survival prediction factors that should be considered when performing post-endodontic restoration. Since fibre posts present good biomechanical behaviour as a result of their elastic modulus, …
Condensation of classical optical waves beyond the cubic nonlinear Schrodinger equation
2012
International audience; A completely classical nonlinear wave is known to exhibit a process of condensation whose thermodynamic properties are analogous to those of the genuine Bose-Einstein condensation. So far this phenomenon of wave condensation has been studied essentially in the framework of the nonlinear Schrodinger (NLS) equation with a pure cubic Kerr nonlinearity. We study wave condensation by considering two representative generalizations of the NLS equation that are relevant to the context of nonlinear optics, the nonlocal nonlinearity and the saturable nonlinearity. For both cases we derive analytical expressions of the condensate fraction in the weakly and the strongly nonlinea…
Innovations in endodontic filling materials
2012
One of the goals of endodontic treatment is to achieve a complete, tridimensional, hermetic sealing of the root canal system to prevent the entry of microorganisms or their products through both the coronal and apical pathways. Gutta-percha is the most widely used material for root canal filling and despite its numerous properties, such as biocompatibility and thermoplasticity, it has however an important limit: the lack of adhesion to the canal walls. Attempts to address this problem have been made over the years by using endodontic cements capable of bonding to canal dentine but their tendency to resorption in time can compromise the quality of treatment. The first step towards a real adh…
Organic solvents vapor pressure and relative humidity effects on the phase transition rate of α and β forms of tegafur.
2011
The objective of this work was to investigate the relative humidity (RH) and solvent vapor pressure effects on the phase transition dynamics between tegafur polymorphic forms that do not form hydrates and solvates. The commercially available α and β modifications of 5-fluoro-1-(tetrahydro-2-furyl)-uracil, known as the antitumor agent tegafur, were used as model materials for this study. While investigating the phase transitions of α and β tegafur under various partial pressures of methanol, n-propanol, n-butanol, and water vapor, it was determined that the phase transition rate increased in the presence of solvent vapors, even though no solvates were formed. By increasing the relative air h…
From capillary condensation to interface localization transitions in colloid-polymer mixtures confined in thin-film geometry.
2008
Monte Carlo simulations of the Asakura-Oosawa (AO) model for colloid-polymer mixtures confined between two parallel repulsive structureless walls are presented and analyzed in the light of current theories on capillary condensation and interface localization transitions. Choosing a polymer to colloid size ratio of q=0.8 and studying ultrathin films in the range of D=3 to D=10 colloid diameters thickness, grand canonical Monte Carlo methods are used; phase transitions are analyzed via finite size scaling, as in previous work on bulk systems and under confinement between identical types of walls. Unlike the latter work, inequivalent walls are used here: while the left wall has a hard-core rep…
Confinement effects on phase behavior of soft matter systems.
2008
When systems that can undergo phase separation between two coexisting phases in the bulk are confined in thin film geometry between parallel walls, the phase behavior can be profoundly modified. These phenomena shall be described and exemplified by computer simulations of the Asakura-Oosawa model for colloid-polymer mixtures, but applications to other soft matter systems (e.g. confined polymer blends) will also be mentioned. Typically a wall will prefer one of the phases, and hence the composition of the system in the direction perpendicular to the walls will not be homogeneous. If both walls are of the same kind, this effect leads to a distortion of the phase diagram of the system in thin …
Capillary condensation in cylindrical pores: Monte Carlo study of the interplay of surface and finite size effects.
2010
When a fluid that undergoes a vapor to liquid transition in the bulk is confined to a long cylindrical pore, the phase transition is shifted (mostly due to surface effects at the walls of the pore) and rounded (due to finite size effects). The nature of the phase coexistence at the transition depends on the length of the pore: For very long pores the system is axially homogeneous at low temperatures. At the chemical potential where the transition takes place fluctuations occur between vapor-like and liquid-like states of the cylinder as a whole. At somewhat higher temperatures (but still far below bulk criticality) the system at phase coexistence is in an axially inhomogeneous multi-domain …
Double-well thermodynamic potentials and spinodal curves: how real are they?
2007
The concept of double-well thermodynamic potentials, ubiquitous since the van der Waals description of the vapour-to-liquid transition and the Landau theory of phase transitions, is critically re-examined. Particular emphasis is put on the extent to which spinodal curves (separating ‘metastable’ from ‘unstable’ states) are meaningful. It is argued that in full thermodynamic equilibrium spinodals are well-defined when one either considers finite subsystems of an infinitely large system, or systems with all linear dimensions finite. Evidence is given that in a finite (cubic) d-dimensional box the spinodals correspond (in a fluid) to the rounded ‘droplet evaporation’ or ‘bubble condensation’ t…
Polymer mixtures in confined geometries: Model systems to explore phase transitions
2005
While binary (A,B) symmetric polymer mixtures ind = 3 dimensions have an unmixing critical point that belongs to the 3d Ising universality class and crosses over to mean field behavior for very long chains, the critical behavior of mixtures confined into thin film geometry falls in the 2d Ising class irrespective of chain length. The critical temperature always scales linearly with chain length, except for strictly two-dimensional chains confined to a plane, for whichT; c ∝N; 5/8 (this unusual exponent describes the fractal contact line between segregated chains in dense melts in two spatial dimensions, d = 2). When the walls of the thin film are not neutral, but preferentially attract one …
Implications of tau data for CP violation in K decays
2019
The \bm{D=6}𝐃=6 contribution of the Operator Product Expansion (OPE) of the \bm{\mathrm{VV-AA}}VV−AA correlator of quark currents can be related to hadronic matrix elements associated to CP violation in non-leptonic kaon decays. We use those relations to find an updated value for \bm{\langle(\pi\pi)_{I=2}|\mathcal{Q}_{8}|K\rangle}⟨(𝛑𝛑)𝐈=2|𝒬8|𝐊⟩ in the chiral limit using the updated ALEPH spectral function. Taking instead values of the matrix elements from the lattice to obtain the \bm{D=6}𝐃=6 vacuum elements provides a new short-distance constraint that allows for an inclusive determination of \bm{f_{\pi}}𝐟𝛑 and an updated value for the \bm{D=8}𝐃=8 condensate.