Search results for "Cone"
showing 10 items of 772 documents
Grafting Silicone at Room Temperature—a Transparent, Scratch-resistant Nonstick Molecular Coating
2020
Silicones are usually considered to be inert and, thus, not reactive with surfaces. Here we show that the most common silicone, methyl-terminated polydimethylsiloxane, spontaneously and stably bonds on glass-and any other material with silicon oxide surface chemistry-even at room temperature. As a result, a 2-5 nm thick and transparent coating, which shows extraordinary nonstick properties toward polar and nonpolar liquids, ice, and even super glue, is formed. Ten microliter drops of various liquids slide off a coated glass when the sample is inclined by less than 10°. Ice adhesion strength on a coated glass is only 2.7 ± 0.6 kPa, that is, more than 98% less than ice adhesion on an uncoated…
Research Regarding Uniaxial Tensile Strength of Nylon Woven Fabrics, Coated and Uncoated with Silicone
2019
Properties of woven fabrics used to make airbag cushions are influenced by a lot of factors: the nature of raw materials, woven fabric geometry and density, technological parameters of the weaving operation and finishing. The main purpose of this research paper is to find the values of three mechanical parameters – tensile strain, tensile stress and specific modulus – according to the type of samples and test direction on the testing stand. To obtain woven fabric samples were used polyamide 6-6 polyfilament yarns (nylon), silicone coated and uncoated fabric. Testing procedure and samples preparation were done following the standard EN ISO 13934-1:1999. Test results and graphs show that, we …
Solvent features of cluster single-wall C, BC2N and BN nanotubes, cones and horns
2013
Graphical abstractDisplay Omitted Highlights? It is discussed single-wall carbon, BC2N and BN nanocones in organic solvents in cluster form. ? Theory is developed based on a cluster bundlet model describing distribution function by size. ? There is explanation in which (BC2N/BN-)SWNC free energy is combined from two components. ? Bundlet model enables describing the distribution function of (BC2N/BN-)SWNC clusters by size. ? From purely geometrical differences, bundlet and droplet models predict different behaviours. It is discussed the existence of single-wall carbon nanocones (SWNCs), especially nanohorns (SWNHs), and BC2N/boron nitride (BN) analogues in organic solvents in cluster form; …
Experimental and Theoretical Study of the Field Induced Phase Separation in Electro- and Magnetorheological Suspensions
1999
We present here the study of field induced phase separation in E.R. and M.R. fluids. Two thermodynamic models — one for the formation of chais of particles and the other for phase separation are presented and compared with experimental results obtained with two kinds of suspensions. One was made of silica particles in silicone oil and the other was made of magnetic polystyrene particles in water. In the presence of a flow the phase separation occurs with the dense phase forming a regular pattern of stripes. The dependence of the period of these stripes on the intensity of the magnetic field is well reproduced by the same kind of thermodynamic model if we add the effect of normal stresses i…
Cluster nature of the solvent features of single-wall carbon nanohorns
2009
The existence of single-wall carbon nanotubes (SWNTs) in organic solvents, in the form of clusters, is discussed. A theory is developed based on a bundlet model for clusters, describing the distribution function of clusters by size. The phenomena have a unified explanation in the bundlet model of clusters, in accordance with which the free energy of an SWNT, involved in a cluster, is combined from two components: a volume one, proportional to the number of molecules n in a cluster, and a surface one proportional to n1/2. The bundlet model for clusters enables describing the distribution function of SWNT clusters by size. The droplet model is formally analogous to the one for fullerene clust…
Submicrometer-Sized Roughness Suppresses Bacteria Adhesion.
2020
Biofilm formation is most commonly combatted with antibiotics or biocides. However, proven toxicity and increasing resistance of bacteria increase the need for alternative strategies to prevent adhesion of bacteria to surfaces. Chemical modification of the surfaces by tethering of functional polymer brushes or films provides a route toward antifouling coatings. Furthermore, nanorough or superhydrophobic surfaces can delay biofilm formation. Here we show that submicrometer-sized roughness can outweigh surface chemistry by testing the adhesion of E. coli to surfaces of different topography and wettability over long exposure times (>7 days). Gram-negative and positive bacterial strains are tes…
Oxidation mechanism of the Inconel 601 alloy at high temperatures
2010
The Inconel 601 alloy oxidation was performed in air, in the temperature range 1000-1150 °C, during 90 h. Kinetic results show that the parabolic behavior is always followed in this temperature range. The Arrhenius plot of the kp values shows two different activation energies. Between 1000 and 1050 °C the activation energy is E a1 = 160 ± 10 kJ/mol. In the 1050-1150 °C temperature range a higher value is calculated E a2 = 252 ± 20 kJ/mol. The E a2 value and the X-ray diffraction (XRD) results and scanning electron microscope (SEM) energy dispersive X-ray spectroscopy (EDS) examinations are in accordance with a scale growth mechanism limited by a growing Cr 2 O 3 scale acting as a diffusion …
Microstructuring of phospholipid bilayers on gold surfaces by micromolding in capillaries
2005
Microstructuring of lipid bilayers on gold surfaces was achieved by micromolding in capillaries employing chemically modified polydimethylsiloxane (PDMS). Microfluidic networks of PDMS were prepared by micromolding and functionalized with thiol end-groups using 3-mercaptopropyltrimethoxysilane. The PDMS stamps were firmly attached to the gold substrate via quasi-covalent linkage providing a tight seal, a prerequisite for establishing individual addressable capillaries. Bilayers composed of POPC/POPG were subsequently prepared on microstructured self assembly monolayers of 11-amino-1-undecanethiol via strong electrostatic interactions. This way it is possible to generate individually address…
The Unique Versatility of the Double Metal Cyanide (DMC) Catalyst: Introducing Siloxane Segments to Polypropylene Oxide by Ring-Opening Copolymerizat…
2020
The combination of hydrophobic polydimethylsiloxane (PDMS) blocks with hydrophilic polyether segments plays a key role for silicone surfactants. Capitalizing on the double metal cyanide (DMC) catalyst, the direct (i.e., statistical) copolymerization of cyclic siloxanes and epoxides is shown to be feasible. The solvent-free one-pot copolymerization of hexamethylcyclotrisiloxane and propylene oxide results in the formation of gradient propylene oxide (PPO)-PDMS copolymers. Copolymers with up to 46% siloxane content with low dispersities (Ð < 1.2) are obtained in the molecular weight range of 2100-2900 g mol-1 . The polymerization kinetics are investigated by pressure monitoring and in situ 1 …