Search results for "Confine"

Experimental investigation on the compressive behavior of short-term preloaded carbon fiber reinforced polymer-confined concrete columns

2017

Strengthening of concrete columns with fiber reinforced polymer sheets provides a good improvement to the existing structural members in terms of load and strain capacity due to the properties of the composite jacket. A proper knowledge of the load–strain response of the composite members is necessary to design retrofitting intervention of existing structures; however, so far the available design methods do not allow to take into account the effect of the possible presence of service loads on the compressive behavior of the reinforced columns. An experimental investigation on the compressive behavior of preloaded circular concrete columns reinforced with carbon fiber reinforced polymer was …

Experimental results of RC columns strengthnened with Fiber Reinforced Cementitious Mortars

2012

The structural behaviour of reinforced concrete columns strengthened with a system made up of fibre nets embedded in an inorganic stabilized cementitious matrix was investigated. Specimens with circular and square cross-section were cast and subjected to monotonic uniaxial compression to investigate the efficiency of a Polypara-phenylene-benzo-bisthiazole (PBO) Fibre Reinforced Cementitious Mortars (FRCM) system in increasing both carrying capacity and ductility. The experimental results show that confinement with PBO fibre produced a noticeable increment in strength and ductility, though the low mechanical ratios of fibre considered were not always able to ensure hardening behaviour up to …

Overview of the JET results

2015

Since the installation of an ITER-like wall, the JET programme has focused on the consolidation of ITER design choices and the preparation for ITER operation, with a specific emphasis given to the bulk tungsten melt experiment, which has been crucial for the final decision on the material choice for the day-one tungsten divertor in ITER. Integrated scenarios have been progressed with the re-establishment of long-pulse, high-confinement H-modes by optimizing the magnetic configuration and the use of ICRH to avoid tungsten impurity accumulation. Stationary discharges with detached divertor conditions and small edge localized modes have been demonstrated by nitrogen seeding. The differences in…

Charged supramolecular assemblies of surfactant molecules in gas phase

2015

The aim of this review is to critically analyze recent literature on charged supramolecular assemblies formed by surfactant molecules in gas phase. Apart our specific interest on this research area, the stimuli to undertake the task arise from the widespread theoretical and applicative benefits emerging from a comprehensive view of this topic. In fact, the study of the formation, stability, and physicochemical peculiarities of non-covalent assemblies of surfactant molecules in gas phase allows to unveil interesting aspects such as the role of attractive, repulsive, and steric intermolecular interactions as driving force of supramolecular organization in absence of interactions with surround…

Organic synthesis of high added value molecules with MOF catalysts

2020

Recent examples of organic synthesis of fine chemicals and pharmaceuticals in confined spaces of MOFs are highlighted and compared with silica-based ordered porous solids, such as zeolites or mesoporous (organo)silica. These heterogeneous catalysts offer the possibility of stabilizing the desired transition states and/or intermediates during organic transformations of functional groups and (C-C/C-N) bond forming steps towards the desired functional high added value molecular scaffolds. A short introduction on zeolites, mesoporous silica and metal-organic frameworks is followed by relevant applications in which confined active sites in the pores promote single or multi-step organic synthesis…

Diffusion Control in Single-Site Zinc Reticular Amination Catalysts.

2020

Zn-containing metal-organic frameworks have been used for the first time as heterogeneous catalysts in the amination of C-Cl bonds. The use of extended bis(pyrazolate) linkers can generate highly porous architectures, which favor the diffusion of amines to the confined spaces with respect to other imidazolate frameworks with narrower pore windows. The N4Zn nodes of the Zn-reticular framework show comparable activity to state-of-the-art homogeneous Zn amination catalysts, avoiding the use of basic conditions, precious metals, or other additives. This is combined with long-term activity and stability upon several reaction cycles, without contamination of the reaction product. ispartof: INORGA…

Computational Study on Cesium Azide Trapped in a Cyclopeptidic Tubular Structure

2008

The structures and the electronic properties of host-guest complexes formed by a cyclopeptidic tubular aggregate and the species CsN3, CS2(N-3)(2), and CS2N6 have been investigated by means of density functional theory. Taking advantage of the azide property to act as a bridge ligand between two or more metal cations, it may be possible to trap N-3(-) ions inside a confined space. This could be important for the preparation of polynitrogen molecules N-n. Results show that there are significant attractive interactions between the azide ion and the cavity walls, which make the ion stay inside the inner empty space of the cyclopeptidic aggregate. The confinement of the species CS2(N-3)(2) forc…

Induced Chirality in Confined Space on Halogen Gold Complexes

2015

The solubilization of HAuCl4 in toluene within optically active reverse micelles and lamellar structures formed by (1R,2S)-Dodecyl(2-hydroxy-1-methyl-2-phenylethyl)- dimethylammonium bromide (DMEB) has allowed us to evidence the complex phenomenology accompanying the confinement of Au salt within these nanostructures. Together with a chloride/bromide exchange process occurring in the first coordination sphere of an Au ion, UV−vis and electronic circular dichroism (ECD) spectra reveal the appearance of an induced dichroic signal attributable to Au complexes entrapped in the hydrophilic domain of the DMEB chiral nanostructures. Interestingly, change of the effective oxidation state and coordi…

Pratiques numériques au collège durant le confinement et transformation pédagogique du rôle de l’enseignant

2021

International audience

Experimental investigation on the effectiveness of basalt-fibre strengthening systems for confining masonry elements

L’impiego di materiali compositi per il rinforzo di colonne in muratura è diventato una pratica ampiamente diffusa nel corso degli ultimi decenni. Questa tecnica, che consiste generalmente nell’applicazione di materiali polimerici fibrorinforzati (Fibre Reinforced Polymer-FRP), ha mostrato buone potenzialità, essendo in grado di garantire notevoli incrementi di resistenza e duttilità dell’elemento rinforzato, grazie ad un’azione di confinamento passivo. Tuttavia, l’impiego di compositi a matrice polimerica presenta alcuni limiti legati soprattutto alle prestazioni delle resine epossidiche, che a causa della loro natura sintetica danno luogo a problemi di compatibilità con il supporto murari…