Search results for "Confined"

showing 10 items of 65 documents

Confined crystallization of a HKUST-1 metal–organic framework within mesostructured silica with enhanced structural resistance towards water

2017

A HKUST-1 metal–organic framework was crystallized in the NH2-modified mesostructured silica FDU-12 in order to improve its structural stability upon water exposure. In-depth structural characterization studies of the designed composite confirmed successful formation of the MOF phase within the ordered spherical mesopores of the silica matrix. In spite of the confinement within the cavities, MOF exhibits full accessibility for the adsorbed gas molecules. In contrast to the bulk HKUST-1, which undergoes slow phase transition in a humid environment, the structural integrity of the HKUST-1 in the humid-protective matrix remains unchanged even after immersion and stirring in water at elevated t…

Phase transitionMaterials scienceRenewable Energy Sustainability and the EnvironmentComposite numberEngineering controlled terms: Crystalline materialsOrganometallicsStability Compendex keywords Confined crystallizationElevated temperatureMesostructured silicaMetal organic frameworkSpherical mesoporesStructural characterizationStructural resistanceStructural stabilities Engineering main heading: SilicaNanotechnology02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical scienceslaw.inventionAdsorptionChemical engineeringlawPhase (matter)MoleculeGeneral Materials ScienceMetal-organic frameworkCrystallization0210 nano-technologyMesoporous material
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Charge control in laterally coupled double quantum dots

2011

4 figuras, 4 páginas.-- PACS number(s): 78.67.Hc, 73.21.La, 78.55.Cr

PhysicsCondensed Matter - Mesoscale and Nanoscale PhysicsOptical propertiesQuantum dotsElectrons--EmissióQuantum point contactQuantum-confined Stark effectFOS: Physical sciencesElectronsElectronic structureCondensed Matter PhysicsCondensed Matter::Mesoscopic Systems and Quantum Hall EffectElectronic Optical and Magnetic MaterialsCondensed Matter::Materials ScienceQuantum dot laserQuantum dotElectronic propertiesMesoscale and Nanoscale Physics (cond-mat.mes-hall)Electrons--EmissionEmission spectrumTrionAtomic physicsPunts quànticsQuantum tunnelling
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Lateral induced dipole moment and polarizability of excitons in a ZnO single quantum disk

2013

The lateral Stark shift of an exciton confined in a single ZnO quantum thin disk of radius R was calculated using a variational approach within the two bands effective mass approximation. It is shown that the exciton has a non negligible induced dipole moment when an external electric field is applied mainly for electron-hole separation below to the 3D excitonic Bohr radius. The behavior of the exciton lateral Stark shift proves the existence of an important correlation between the polarizability and the induced dipole moment.

PhysicsCondensed matter physicsCondensed Matter::OtherExcitonQuantum-confined Stark effectGeneral Physics and AstronomyCondensed Matter::Mesoscopic Systems and Quantum Hall EffectCondensed Matter::Materials Sciencesymbols.namesakeDipoleStark effectPolarizabilityQuantum dotsymbolsPhysics::Atomic PhysicsBohr radiusBiexcitonJournal of Applied Physics
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Competition between carrier recombination and tunneling in quantum dots and rings under the action of electric fields

2008

6 páginas, 3 figuras.-- Proceedings of the 7th International Conference on Physics of Light-Matter Coupling in Nanostructures.

PhysicsCondensed matter physicsExcitonQuantum-confined Stark effectSingle quantum dotElectronCondensed Matter::Mesoscopic Systems and Quantum Hall EffectCondensed Matter PhysicsQuantum dotElectric fieldElectro-absorption modulatorCharged excitonsGeneral Materials ScienceElectrical and Electronic EngineeringWave functionQuantum tunnellingSuperlattices and Microstructures
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Properties of the Ising magnet confined in a corner geometry

2007

Abstract The properties of Ising square lattices with nearest neighbor ferromagnetic exchange confined in a corner geometry, are studied by means of Monte Carlo simulations. Free boundary conditions at which boundary magnetic fields ± h are applied, i.e., at the two boundary rows ending at the lower left corner a field + h acts, while at the two boundary rows ending at the upper right corner a field − h acts. For temperatures T less than the critical temperature T c of the bulk, this boundary condition leads to the formation of two domains with opposite orientation of the magnetization direction, separated by an interface which for T larger than the filling transition temperature T f ( h ) …

PhysicsCondensed matter physicsTransition temperatureGeneral Physics and AstronomyBoundary (topology)GeometrySurfaces and InterfacesGeneral ChemistryCondensed Matter Physics01 natural sciences010305 fluids & plasmasSurfaces Coatings and FilmsMagnetic fieldMagnetizationFerromagnetism0103 physical sciencesIsing modelBoundary value problem010306 general physicsConfined spaceApplied Surface Science
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Spatial correlation of laser-generated electrons and holes in quantum wells

1995

The spatial correlation of hot electrons and holes generated by light in a semiconductor quantum well (QW) is studied. For hot electron-hole pairs in a polar material, this correlation is determined by the interaction with LO-phonons. We analyze the distribution F N (r, K) of electrons and holes which are created in a given light absorption process, with respect to their relative separation r and total quasimomentum ħK, after the emission of a number N of LO-phonons. The relationship between the spatial distribution of electrons and holes in these intermediate states and the cross-section of multi-phonon resonant Raman scattering (MPRRS) is established. Spatial correlation effects are stron…

PhysicsSpatial correlationbusiness.industryQuantum-confined Stark effectElectronCondensed Matter PhysicsLaserSpatial distributionElectronic Optical and Magnetic Materialslaw.inventionsymbols.namesakeSemiconductorlawsymbolsAtomic physicsbusinessRaman scatteringQuantum wellphysica status solidi (b)
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Energy levels of a quantum ring in a lateral electric field

2002

Abstract The electronic states of a semiconductor quantum ring (QR) under an applied lateral electric field are theoretically investigated and compared with those of a quantum disk of the same size. The eigenstates and eigenvalues of the Hamiltonian are obtained from a direct matrix diagonalization scheme. Numerical calculations are performed for a hard-wall confinement potential and the electronic states are obtained as a function of the electric field and the ratio r2/r1, where r2 (r1) is the outer (inner) radius of the ring. The effects of decreasing symmetry and mixing on the energy levels and wave functions due to the applied electric field are also studied. The direct optical absorpti…

Physicsbusiness.industryElectric susceptibilityQuantum-confined Stark effectGeneral EngineeringOptical fieldElectric fluxOpticsParametric processElectric fieldElectric potentialAtomic physicsWave functionbusinessMicroelectronics Journal
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Coherent Light Harvesting through Strong Coupling to Confined Light

2018

When photoactive molecules interact strongly with confined light modes, new hybrid light–matter states may form: the polaritons. These polaritons are coherent superpositions of excitations of the molecules and of the cavity photon. Recently, polaritons were shown to mediate energy transfer between chromophores at distances beyond the Forster limit. Here we explore the potential of strong coupling for light-harvesting applications by means of atomistic molecular dynamics simulations of mixtures of photoreactive and non-photo-reactive molecules strongly coupled to a single confined light mode. These molecules are spatially separated and present at different concentrations. Our simulations sug…

Physicsconfined lightPhotonLetterta114010405 organic chemistryChromophore010402 general chemistry7. Clean energy01 natural sciences0104 chemical sciencesDelocalized electronMolecular dynamicscoherent light harvestingChemical physicsstrong couplingPolaritonStrong couplingMoleculeGeneral Materials SciencevalokemiaPhysical and Theoretical ChemistryPhysics::Chemical Physicsta116ExcitationJournal of Physical Chemistry Letters
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Reply to “Comment to ‘Dynamics of supercooled confined water measured by deep inelastic neutron scattering’ by Y. Finkelstein and R. Moreh”

2019

We reply to the comment [Front. Phys. 14(5), 53605 (2019)] by Y. Finkelstein and R. Moreh on our article Front. Phys. 13(1), 138205 (2018). We agree with some of their criticisms about our calculation of the temperature effect on the kinetic energy of hydrogen atoms of supercooled confined water; we also agree with their statement that, in view of the current sensitivity of the technique, possible effects of the liquid-liquid water transition are hardly detected with deep inelastic neutron scattering (DINS). However, we disagree with their use of the translational mass ratio of a single water molecule and, in general, with their underestimation of collective effects.

Physicsliquid-liquid transitionPhysics and Astronomy (miscellaneous)HydrogenSettore FIS/07Front (oceanography)chemistry.chemical_elementvibrational density of statesMass ratioproton kinetic energyKinetic energy01 natural sciencesInelastic neutron scatteringSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)chemistry0103 physical sciencesLibrationlibrationAtomic physics010306 general physicsSupercoolingConfined waterdeep inelastic neutron scatteringsupercooled water
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M3_Microfluidics_for_CNT

2018

Droplet production in T-junction microfluidic device. The droplets are cut off from the water phase flow by pressure of oil. The droplets confined in the channel proceed at the same speed as the continuous phase.

Physics::Fluid Dynamicsendocrine systemdroplet formationT-junctionconfined regimetechnology industry and agriculturePhysics::Atomic and Molecular Clustersmicrofluidicscomplex mixtureseye diseases
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