Search results for "Conversion efficiency"

Perovskite solar cells prepared by flash evaporation

2015

A simple vacuum deposition method for the preparation of high quality hybrid organic-inorganic methylammonium lead iodide perovskite thin films is reported. When sandwiched in between organic charge transporting layers, such films lead to solar cells with a power conversion efficiency of 12.2%.

Correlation between polymer architecture, mesoscale structure and photovoltaic performance in side-chain-modified poly(p-arylene-ethynylene)-alt-poly…

2011

Abstract Recent investigations have shown that an anthracene containing poly( p -arylene-ethynylene)-alt-poly( p -arylene-vinylene) statistical copolymer consisting of a well defined conjugated backbone, along which linear and branched alkoxy side chains are attached in a random manner, yields, compared to its counterparts with regular side chain substitution, an improved performance in polymer [6,6]:-phenyl-C 61 -butyric acid methyl ester (PCBM) bulk-heterojunction solar cells. The microscopic origin for the improved power conversion efficiency ( η  ≈ 3.8%) of the statistical copolymer – which is the best in its material class – has not been resolved. We conducted grazing incidence wide-an…

Metal-Oxide-Free Methylammonium Lead Iodide Perovskite-Based Solar Cells: the Influence of Organic Charge Transport Layers

2014

Metal-oxide-free methylammonium lead iodide perovskite-based solar cells are prepared using a dual-source thermal evaporation method. This method leads to high quality reproducible films with large crystal domain sizes allowing for an in depth study of the effect of perovskite film thickness and the nature of the electron and hole blocking layers on the device performance. The power conversion efficiency increases from 4.7% for a device with only an organic electron blocking layer to almost 15% when an organic hole blocking layer is also employed. In addition to the in depth study on small area cells, larger area cells (approx. 1 cm(-2)) are prepared and exhibit efficiencies in excess of 10…

Photovoltaic Properties of a Porphyrin-Containing Polymer as Donor in Bulk Heterojunction Solar Cells With Low Energy Loss

2017

High‐Efficiency Perovskite Solar Cells Using Molecularly Engineered, Thiophene‐Rich, Hole‐Transporting Materials: Influence of Alkyl Chain Length on …

2016

The synthesis and characterization of a series of novel small-molecule hole-transporting materials (HTMs) based on an anthra[1,2-b:4,3-b′:5,6-b′′:8,7-b′′′]tetrathiophene (ATT) core are reported. The new compounds follow an easy synthetic route and have no need of expensive purification steps. The novel HTMs are tested in perovskite solar cells and power conversion efficiencies (PCE) of up to 18.1% under 1 sun irradiation are measured. This value is comparable with the 17.8% efficiency obtained using 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobifluorene as a reference compound. Similarly, a significant quenching of the photoluminescence in the first nanosecond is observed, ind…

Photovoltaic effect in bulk heterojunction system with glass forming indandione derivative DMABI-6Ph

2018

The aim of the work is to evaluate possible use of 2-[[4-(bis(2-trityloxyethyl)amino)phenyl]methylene]indane-1,3-dione (DMABI-6Ph) as light absorbing material for solar cells. DMABI-6Ph is a perspective material due to its good photoelectrical, thermal and chemical properties. The main advantage of DMABI-6Ph is its ability to form amorphous films by wet-casting methods thus allowing using the compound in organic solar cells made from solution. For now most popular materials for solution processable solar cells are polymer P3HT and fullerene derivative PCBM, but lot of investigations are in the field of new low molecular weight materials to replace the polymer. Photoelectrical measurements w…

Effect of Ion Escape Velocity and Conversion Surface Material on H- Production

2011

According to generally accepted models surface production of negative ions depends on ion escape velocity and work function of the surface. We have conducted an experimental study addressing the role of the ion escape velocity on H− production. A converter‐type ion source at Los Alamos Neutron Science Center was employed for the experiment. The ion escape velocity was affected by varying the bias voltage of the converter electrode. It was observed that due to enhanced stripping of H− no direct gain of extracted beam current can be achieved by increasing the converter voltage. The conversion efficiency of H− was observed to vary with converter voltage and follow the existing theories in qual…