Search results for "Cooling"
showing 10 items of 470 documents
Structure and Dynamics of the Quasi-Liquid Layer at the Surface of Ice from Molecular Simulations
2018
We characterized the structural and dynamical properties of the quasi-liquid layer (QLL) at the surface of ice by molecular dynamics simulations with a thermodynamically consistent water model. Our simulations show that for three low-index ice surfaces only the outermost molecular layer presents short-range and mid-range disorder and is diffusive. The onset temperature for normal diffusion is much higher than the glass temperature of supercooled water, although the diffusivity of the QLL is higher than that of bulk water at the corresponding temperature. The underlying subsurface layers impose an ordered template, which produces a regular patterning of the ice/water interface at any tempera…
Thermal-hydraulic behaviour of the DEMO divertor plasma facing components cooling circuit
2017
Abstract Within the framework of the Work Package DIV 1 – “Divertor Cassette Design and Integration” of the EUROfusion action, a research campaign has been jointly carried out by ENEA and University of Palermo to investigate the thermal-hydraulic performances of the DEMO divertor cassette cooling system. A comparative evaluation study has been performed considering three different options for the cooling circuit layout of the divertor Plasma Facing Components (PFCs). The potential improvement in the thermal-hydraulic performance of the cooling system, to be achieved by modifying cooling circuit layout, has been also assessed and discussed in terms of optimization strategy. The research acti…
Parametric study of the influence of First Wall cooling water on the Water Cooled Lithium Lead Breeding Blanket nuclear response
2019
Abstract In the framework of EUROfusion Work Package International Cooperation R&D activities, a close collaboration has been started among University of Palermo, ENEA Brasimone and ENEA Frascati for the development of the Water Cooled Lithium Lead (WCLL) Breeding Blanket (BB) concept. In this context, a research campaign has been carried out at the University of Palermo in order to investigate the influence of First Wall (FW) cooling water configuration on the nuclear response of the WCLL BB under irradiation in EU-DEMO, in order to gain useful indications for the WCLL BB pre-conceptual designs. To this end, three-dimensional nuclear analyses have been performed by MCNP5 v. 1.6 Monte Carlo…
H-2 vibrational spectral signatures in binary and ternary mixtures: theoretical model, simulation and application to CARS thermometry in high pressur…
2001
International audience; A summary of the main results obtained by the two groups in the field of H-2 vibrational spectral line signatures for various mixtures. in connection with CARS diagnostics of H-2-O-2 combustion systems, is presented. H-2-X Systems may have specific large inhomogeneous spectral features, due to the dependence of the line broadening and line shifting on the (H-2) radiator speed, particularly at high temperature. Thus, careful attention has to be paid to rigorously analyze such features, both from the experimental point of view (Dijon) and from the theoretical one (Besancon). Applications of the present results to high-pressure H-2/air flame thermometry are also briefly…
Protein dynamical transition vs. liquid-liquid phase transition in protein hydration water
2013
In this work, we compare experimental data on myoglobin hydrated powders from elastic neutron scattering, broadband dielectric spectroscopy, and differential scanning calorimetry. Our aim is to obtain new insights on the connection between the protein dynamical transition, a fundamental phenomenon observed in proteins whose physical origin is highly debated, and the liquid-liquid phase transition (LLPT) possibly occurring in protein hydration water and related to the existence of a low temperature critical point in supercooled water. Our results provide a consistent thermodynamic/dynamic description which gives experimental support to the LLPT hypothesis and further reveals how fundamental …
Modelling of Compressors in an Industrial CO $$_2$$ -Based Operational Cooling System Using ANN for Energy Management Purposes
2019
Large scale cooling installations usually have high energy consumption and fluctuating power demands. There are several ways to control energy consumption and power requirements through intelligent energy and power management, such as utilizing excess heat, thermal energy storage and local renewable energy sources. Intelligent energy and power management in an operational setting is only possible if the time-varying performance of the individual components of the energy system is known. This paper presents an approach to model the compressors in an industrial, operational two-stage cooling system, with CO\(_2\) as the working fluid, located in an advanced food distribution warehouse in Norw…
On the Glass Transition in Polymer Films: Recent Monte Carlo Results
1998
AbstractThis paper reports results of a Monte Carlo simulation for a simplified lattice modelof a supercooled polymer film. The film geometry is realized by two opposite hard walls.The distance between the walls is varied. The chains exhibit a strong tendency to orientparallel to the walls and are flattened when being very close to them. This deviation of thepolymer structure with respect to the bulk is accompanied by an acceleration of local densityfluctuations. On the other hand, the diffusion coefficient of a chain remains unaffected.
Theory of nucleation and crystal growth of polymers in concentrated solutions
1974
ABSTRACT The process of crystallization in concentrated solutions depends strongly on the rate of crystallization and the rate of long range diffusion of the polymer chains. If the crystallization proceeds slowly compared to diffusion, this type of crystal nucleus will be formed for which the free energy of nucleation is smallest. By taking into account entropy effects which are characteristic for chain molecules one can show that the crystal with smallest free energy of nucleation is a crystal with almost regular chain folds on the surfaces. The influence of supercooling, concentration and molecular weight on the thickness and growth rate of such crystals is discussed. If the crystallizati…
Monte Carlo simulation of the glass transition in polymeric systems: Recent developments
1995
Abstract The bond fluctuation model on square and s.c. lattices is used as a coarse-grained model for flexible polymers in dense melts. Using an energy that favours long bonds, a conflict is created between the tendency of the bonds to stretch at low temperatures and packing constraints. This simple concept of ‘geometric frustration’ leads to glass transition. Both static and dynamic properties of this model are investigated by Monte Carlo simulations, paying attention to effects found by varying the cooling rate and the chain length N of the polymers. In two and three spatial dimensions an effective (cooling-rate dependent) glass transition temperature T g can be defined, where the system …
Molecular dynamics of supercooled polymer films
2000
We present results of molecular dynamics simulations for a supercooled polymer melt confined between two smooth and purely repulsive walls. The thickness D of the film is about 7 times the bulk radius of gyration. For all temperatures studied, a significant increase of the monomer and chain mobilities with respect to the bulk is observed. Preliminary results suggest that structural relaxation times exhibit a power-law behavior in the vicinity of a critical temperature T c (D) 0.39 (in Lennard-Jones units). This estimate of T c (D) is about 14% smaller than the corresponding bulk value. Despite this significant decrease the time dependence of various mean-square displacements seems to be una…