Search results for "Coupling"
showing 10 items of 1862 documents
Theoretical EHT study of oxidative coupling of methane on pure MgO and MgO doped with Li and Na
1991
Abstract On the basis of Extended Huckel Theory, empirical studies on the oxidative coupling of methane with MgO pure and MgO doped with Li and Na are presented. The results obtained from the two-dimensional energy surfaces calculated for the interaction between linear clusters of these oxides and the methane molecule show a qualitative agreement with the experimental behaviour reported for these catalysts. The calculated activation energy barriers are in accord with the relative activities of these oxides (Li/MgO > Na/ MgO > MgO) and are of the same order of magnitude as the experimentally determined activation energies.
Synthesis Crystal Structure and Magnetic Properties of the Trinuclear Nickel(II) Complex Bis[(μ-thiocyanato-N)bis(μ-pyridazine-N1,N2)bis(thiocyanato-…
2000
Unusual single N-bridging thiocyanato and double pyridazine (pdz) bridges occur in the linear trinuclear nickel(II) complex of formula [Ni3(pdz)6(NCS)6]. The compound exhibits a quasi Curie law behavior, the antiferromagnetic coupling through the double 1,2-diazine links being nearly compensated by the ferromagnetic exchange through the single N-bridging thiocyanato.
Highly Loaded Multi-Walled Carbon Nanotubes Non-Covalently Modified with a Bis-Imidazolium Salt and their Use as Catalyst Supports
2016
The surfaces of multi-walled carbon nanotubes (MWCNTs) were non-covalently modified using two bis-imidazolium dibromide derivatives having phenyl or pyrene groups. Due to the presence of the two pyrene groups the bis(pyren-1-ylmethylimidazolium) dibromide derivative was immobilised at a loading of about 15-16 wt %, whereas only <3 wt % of the phenyl derivative was immobilised. The presence of the two imidazolium cations helped the immobilisation of tetrachloropalladate ions after exchange with bromide ions. Tetrachloropalladate was used as pre-catalyst in several Suzuki-Miyaura carbon-carbon cross-coupling reactions in water or water/ethanol at 50 °C in only 0.1 mol % and compared with the …
Concurrent TMS-fMRI for causal network perturbation and proof of target engagement
2021
The experimental manipulation of neural activity by neurostimulation techniques overcomes the inherent limitations of correlative recordings, enabling the researcher to investigate causal brain-behavior relationships. But only when stimulation and recordings are combined, the direct impact of the stimulation on neural activity can be evaluated. In humans, this can be achieved non-invasively through the concurrent combination of transcranial magnetic stimulation (TMS) with functional magnetic resonance imaging (fMRI). Concurrent TMS-fMRI allows the assessment of the neurovascular responses evoked by TMS with excellent spatial resolution and full-brain coverage. This enables the functional ma…
Electrochemically Induced Reversible and Irreversible Coupling of Triarylamines
2011
The electrochemical coupling and dimerization behavior of the low molecular compounds triphenylamine (TPA) and 9-phenylcarbazole (PHC) in comparison to tri-p-tolylamine (p-TTA) with para-blocked methyl groups has been investigated in detail. In contrast to the unsubstituted radical cations of TPA and PHC, the radical cations of p-TTA are stable in the radical cation state and do not undergo any further coupling reactions. However, we found that the dicationic state of p-TTA does undergo two different competitive reaction pathways: (1) an irreversible intramolecular coupling reaction which leads to phenylcarbazole moieties and (2) a reversible intermolecular dimerization leading to charged σ…
Characterization of impervious layers using scale models and an inverse method
2009
We describe a novel procedure that uses an inverse method to determine unknown parameters for impervious layers used in multilayer structures. The proposed model of the multilayer structure is limited to an ideal double plate separated by an unbonded, fibrous, sound-absorbing material. Experimental data were obtained by nearfield acoustic holography for the calculation of the transmission loss of various multilayer structures mounted in a window in a wooden box designed specifically for this purpose. We used the Trochidis and Kalaroutis forecast model of acoustic insulation for multilayer structures, which is based on a spatial Fourier transform. The experimental pressure and velocity data …
Higher-order polarizations on the Virasoro group and anomalies
1991
In a previous paper the authors showed that the space of (first order) polarized functions on the Virasoro group is not, in general, irreducible. The full reduction was explicitly achieved by taking the orbit of the enveloping algebra through the vacuum. This additional step provided the proper quantization in the “strong-coupling” domain 0<c≦1. In this paper we introduce the concept of “higher order polarization” as a generalization of that of polarization. We prove that the imposing of the additional (higher-order) polarization conditions is equivalent to the taking of the above-mentioned orbit. This demonstrates that the generalized (higher-order) polarization conditions suffice to obtai…
Localizing quantum phase slips in one-dimensional Josephson junction chains
2013
Published version of an article in the journal: New Journal of Physics. Also available from the publisher at: http://dx.doi.org/10.1088/1367-2630/15/9/095014 Open Access We studied quantum phase-slip (QPS) phenomena in long one-dimensional Josephson junction series arrays with tunable Josephson coupling. These chains were fabricated with as many as 2888 junctions, where one sample had a separately tunable link in the middle of the chain. Measurements were made of the zero-bias resistance, R0, as well as current-voltage characteristics (IVC). The finite R0 is explained by QPS and shows an exponential dependence on with a distinct change in the exponent at R 0 = RQ = h/4e2. When R0 > R Q, the…
Induced unconventional superconductivity on the surface states of Bi2Te3 topological insulator
2017
Topological superconductivity is central to a variety of novel phenomena involving the interplay between topologically ordered phases and broken-symmetry states. The key ingredient is an unconventional order parameter, with an orbital component containing a chiral $p_x$ + i$p_y$ wave term. Here we present phase-sensitive measurements, based on the quantum interference in nanoscale Josephson junctions, realized by using Bi$_2$Te$_3$ topological insulator. We demonstrate that the induced superconductivity is unconventional and consistent with a sign-changing order parameter, such as a chiral $p_x$ + i$p_y$ component. The magnetic field pattern of the junctions shows a dip at zero externally a…
Fabrication of Nb-based superconducting single electron transistor
2003
Abstract We have fabricated Nb/(Al-)AlOx/Nb junctions with a single electron transistor (SET) geometry using conventional e-beam lithographic technique. It was possible to reach a clearly defined superconducting gap of 0.75 meV as measured in the current vs. voltage (I–V) characteristic curve, which corresponds to Tc of 4.6 K . The Josephson coupling energy was comparable to the charging energy, EJ≈Ec=30– 40 μeV .