Search results for "Crystal growth"
showing 10 items of 130 documents
A Probabilistic Model for Crystal Growth Applied toProtein Deposition at the Microscale.
2018
A probabilistic discrete model for 2D protein crystal growth is presented. This model takes into account the available space and can describe growing processes of a different nature due to the versatility of its parameters, which gives the model great flexibility. The accuracy of the simulation is tested against a real recrystallization experiment, carried out with the bacterial protein SbpA from Lysinibacillus sphaericus CCM2177, showing high agreement between the proposed model and the actual images of the crystal growth. Finally, it is also discussed how the regularity of the interface (i.e., the curve that separates the crystal from the substrate) affects the evolution of the simulation.
On the mechanism of the interaction between oxygen and close-packed single-crystal aluminum surfaces
2003
Abstract Using periodic first principles simulations we investigate the interaction of oxygen molecules with both regular Al(111) and Al(001) surfaces as well as a stepped Al(111) substrate. The limitation of this approach is the use of thin metallic slabs with a limited range for their coverage by adsorbed oxygen. The advantage is the detailed modeling that is possible at an atomic level. On the regular Al(111) surface, we have been able to follow the oxidation process from the approach of O 2 molecules to the surface, through the chemisorption and absorption of O atoms, up to the formation of first Al 2 O 3 formula units. An energetically feasible mechanism for the formation of these Al 2…
Processing of amorphous Si by pulsed laser irradiation at different wavelengths
2012
Amorphous Si thin films deposited on thermally oxidized Si wafers have been processed by the 2 nd and 3 rd harmonics of Nd:YAG laser. Surface modification of amorphous silicon layers have been investigated by scanning electron microscopy before and after chemical etching of processed silicon films. The super-lateral crystal growth regime was achieved with laser fluence of 280 mJ/cm 2 for the 2 nd harmonics and 155 mJ/cm 2 for the 3 rd harmonics. The grain size in polycrystalline Si samples prepared by successive crystallization in the lateral growth regime is about 0.5 - 1 μm.
Influence of Amorphous TiO2-x on Titania Nanoparticle Growth and Anatase-to-Rutile Transformation
2012
Amorphous TiO2-x formed together with precursors and anatase nuclei, during TiCl4 hydrolysis at soft conditions, influences both crystal growth and phase stability. The highly defective nanoparticles of anatase grow by reaction of their basic hydroxyls with acidic ones of TiO2 precursor species. The growth of anatase crystals, however, is affected by their interactions with simultaneously formed amorphous TiO2-x which increasingly covers the particles hindering the anatase-precursor contact. The interactions among anatase and amorphous and precursor components have been studied by H-1-MAS (magic angle spinning) NMR spectroscopy. The interaction between acid and basic hydroxyls favors the fo…
Homogeneous Langmuir-Blodgett Film of Double-Chain Ammonium Amphiphile Complexed with Anionic Polymer
1988
Heterogeneous textures suggesting the coexistence of a fluid and a solid phase were found both in a surface monolayer and in a deposited Langmuir-Blodgett (LB) film of double-chain ammonium amphiphiles by fluorescence microscopy. Although an annealing of the surface monolayer at 40°C allowed crystal growth, the heterogeneous phase separation remained in the LB film. A drastic change of the fluorescence image shows that the recrystallization of the complexed monolayer with anionic polymers conducted the homogeneous monolayer.
Hydrothermal growth mechanism of SnO2 nanorods in aqueous HCl
2018
Abstract Rutile-type nanorods of SnO2 were obtained in a one-pot hydrothermal synthesis starting from SnCl4·5H2O and HCl in a temperature range between 200 and 240°C. Although the nanorods are polydisperse, the average length of the nanorods could be adjusted from 13 to 65 nm by varying of the reaction temperature. The resulting anisotropic nanocrystals were characterized using powder X-ray diffraction (PXRD), (high resolution-) transmission electron microscopy (HR-TEM), and selected area electron diffraction (SAED). The particle growth proceeds via a dissolution-recrystallization process with soluble [SnCl5(H2O)]− intermediates, as confirmed by PXRD, Raman spectroscopy, and magic angle spi…
Conductimetric study of struvite crystallization in water as a function of pH
2017
Abstract The main objective of this work was to investigate the best pH for phosphorus removal from synthetic aqueous solutions using chemical precipitation of struvite, at constant temperature. The experimental approach, developed in the present study, consisted to precipitate struvite in synthetic wastewater containing PO 4 3− , NH 4 + and Mg 2+ ions in an equal molar ratio, using a stirred tank with continuous monitoring by conductimetry, at 25 °C. Different laboratory experiments were used to evaluate the effects of pH in the range of 8.5 till 11.8, on size, shape, and purity of the precipitated crystals. Struvite crystals were characterized by Infrared spectroscopy (FTIR), scanning ele…
Primary Cell Culture of Fresh Water Hyriopsis cumingii Mantle/Pearl Sac Tissues and Its Effect on Calcium Carbonate Mineralization
2014
Primary cell cultures of the fresh water Hyriopsis cumingii mantle and pearl sac tissues were produced in this study, and the influence of the tissue, cells, and secreted protein on calcium carbonate crystal nucleation and growth was studied. The study contributes to a further understanding of the influence of organic matrices on CaCO3 crystal formation. This research started from the protein level to the tissue/cell level, which is crucial for understanding the inorganic deposition process. The new data also add relevant theoretical approaches to an overall understanding of biomineralization processes. In the experimental groups with mantle or pearl sac tissue, the growth patterns of arago…
A new approach to the growth of ZnO by vapour transport
2005
The crystal growth of ZnO by vapour transport is classically made in presence of additional species which enhance the growth process. Usually, additional species have been considered as chemical transport agents that promote a typical CVT (Chemical Vapour Transport) process. Recently, we have proposed a new interpretation of the chemical role of some of these species. This new interpretation considers that, in some cases, the additional species promote a partial consumption of the O2 provided by the ZnO decomposition and, consequently, a Zn excess is generated. This excess of Zn pressure activates the ZnO decomposition and the growth rate is enhanced. Among those species, carbon shows an ad…
Scanning electron microscopy characterization of ZnSe single crystals grown by solid-phase recrystallization
2000
ZnSe single crystals were grown from n-type microcrystalline boules by a Solid Phase Recrystallization (SPR) method. The recrystallizations were performed under different atmospheres, Ar or Se, and pressures to investigate the influence of growth conditions on the structural features of the resulting crystals. The samples were mechanically and mechano-chemically polished in a bromine methanol solution and, then, etched in HCl for a short time, before characterization. The homogeneity and the nature of defects in the crystals were studied by Cathodoluminescence (CL) in the scanning electron microscope (SEM). CL measurements show the existence of slip bands in the recrystallized samples, like…