Search results for "Crystal"
showing 10 items of 22886 documents
CCDC 1400855: Experimental Crystal Structure Determination
2015
Related Article: Maciej Bujak, Walter Frank|2014|Z.Kristallogr.-New Cryst.Struct.|229|147|doi:10.1515/ncrs-2014-0083
Amorphous silicon nanotubes
2017
In the following, the attention will be focused on the silicon nanotube (SiNTs) that is a highly desired form of silicon for its fundamental role in the miniaturization trend of the electronic devices. After a description of the properties and applications of SiNTs and their fabrication methods, the attention will be focused on chemical vapour deposition (CVD) template synthesis that is the most usual synthetic method for this material. Then, galvanic template synthesis will be described as a general method for the fabrication of different metals and oxides nanostructures, therefore the use of this technique for synthesizing SiNTs will be detailed. Characterization methods will be also desc…
Optical hybrid nanocomposite sensors for selective explosive detection
2022
Durant l'última dècada, la detecció d'artefactes explosius improvisats (IEDs) tant en l'àmbit militar com civil s'ha convertit en una prioritat estratègica en la seguretat nacional a causa de la creixent amenaça terrorista. Encara que les tècniques convencionals, com la cromatografia de gasos acoblada a espectrometria de masses o la difracció de raigs X mostren notables avantatges degut a la seua elevada sensibilitat i selectivitat, una gran part d’aquestes presenten inconvenients, com per exemple processos de mesura lents, instrumentació cara, complexa i voluminosa, que limiten el mostreig en continu i en temps real. Per aquesta raó, existeix una recerca constant per trobar una plataforma …
Diammine{N-[2-(hydroxyimino)propionyl]-N'-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ4 N,N',N'',N'''}iron(III)
2012
In the title compound, [Fe(C9H13N4O4)(NH3)2], the FeIII atom, lying on a mirror plane, is coordinated by four N atoms of a triply deprotonated tetradentate N-[2-(hydroxyimino)- propionyl]-N0 -[2-(oxidoimino)propionyl]propane-1,3-diaminide ligand in the equatorial plane and two N atoms of two ammonia molecules at the axial positions in a distorted octahedral geometry. A short intramolecular O—HO hydrogen bond between the cis-disposed oxime O atoms stabilizes the pseudo-macrocyclic configuration of the ligand. In the crystal, molecules are linked by N—HO hydrogen bonds into a three-dimensional network. The ligand has a mirror-plane symmetry. One of the methylene groups of the propane bridge i…
Synthesis and characterization of Zwitterionic Zn(II) and Cu(II) coordination compounds with ring-substituted 2,2′-biimidazole derivatives
2016
Zwitterionic coordination compounds with strongly asymmetrical charge distribution were synthesized and characterized. Ring-substituted biimidazoles were used as the primary ligands for Zn and Cu compounds. Formation of Zwitterionic coordination compound was found to be strongly dependent on the pH of the reaction medium as well as on the ring and nitrogen substituents of the ligand. Reaction of the Df-R2biim (Df-R2biim = 2,2′-bi-1R-imidazole-5,5′-dicarboxaldehyde, R = Me, Et or Pr) with ZnCl2 in neutral conditions led to binuclear compounds [Zn2Cl4(Df-R2biim)2] with two bridging ligands (1a–c). Reaction with CuCl2·2H2O gave neutral mononuclear compound [CuCl2(Df-Me2biim)] (1d) with chelati…
Synthesis, characterization, and reactivity of heavier group 13 and 14 metallylenes and metalloid clusters : small molecule activation and more
2015
CCDC 1943794: Experimental Crystal Structure Determination
2020
Related Article: F. Sabbaghi, A. As'habi, A. Saneei, M. Pourayoubi, A.A. Abdul Salam, M. Nečas, M. Dušek, M. Kučeráková, S. Acharya|2021|Acta Crystallogr.,Sect.C:Cryst.Struct.Chem.|77|68|doi:10.1107/S2053229620016502
Local mechanical properties by Atomic Force Microscopy nanoindentations
2008
The analysis of mechanical properties on a nanometer scale is a useful tool for combining information concerning texture organization obtained by microscopy with the properties of individual components- Moreover, this technique promotes the understanding of the hierarchical arrangement in complex natural materials as well in the case of simpler morphologies arising from industrial processes. Atomic Force Microscopy, AFM, can bridge morphological information, obtained with outstanding resolution, to local mechanical properties. When performing an AFM nanoindentation, the rough force curve, i.e., the plot of the voltage output from the photodiode vs. the voltage applied to the piezo-scanner, …
Ti Alloyed α-Ga2O3: Route towards Wide Band Gap Engineering
2020
The suitability of Ti as a band gap modifier for &alpha
Bi-2212 and Y123 highly curved single-crystal-like objects: whiskers, bows and ring-like structures
2012
High-temperature superconducting objects of Bi2Sr2CaCu2O8 and Y Ba2Cu3O7 highly curved in the ab-plane, such as curved/kinked whiskers, bows and ring-like structures, were obtained within a solid?liquid?solid (SLS) grass-like growth mechanism. As-grown objects are crystals with three-dimensional epitaxy similar to conventional single crystals: they can be viewed as crystal parts ?cut? from a conventional rectangular crystal. Between our curved objects and conventional crystals, whiskers or thin films there are some differences in the superconducting properties induced only by the shape factors and no new physics is observed. Some details of the growth mechanism are discussed, emphasizing cu…