Search results for "Crystallization"
showing 10 items of 774 documents
Growth and anisotropic ripening in twinned colloidal crystals
2008
The heterogeneous crystallization of colloidal suspensions of Yukawa particles on a wall was observed by Bragg microscopy. The growth velocity ν 110 of the fluid-crystal interface can be very well described by a Wilson-Frenkel growth law, while the limiting velocity is found to be lower than in previous investigations. Twinned bcc domains in lateral direction (parallel to the wall) and their ripening behavior are for the first time investigated systematically. A strong anisotropic growth behavior is found: in the direction of the shear flow, which shear melts the suspension prior to the crystallization process, the extension of the domains is much larger than perpendicular to that. The incr…
Ice deformed in compression and simple shear: control of temperature and initial fabric
2012
AbstractLayered and polycrystalline ice was experimentally deformed in general shear involving axial compression (strain magnitude 0.5-17%) and simple shear (strain magnitude γ = 0.1-1.4). As the temperature is increased from -20°C to -2°C, there is at least a twofold enhancement in octahedral shear strain rate, which coincides with the onset of extensive dynamic recrystallization and a change in grain-size distribution at -15°C. Between -150C and -10°C the c-axis preferred orientation rapidly evolves with the initiation of two-maxima fabrics in shear zones. From -10°C to -2°C there is progressive evolution of a final c-axis pattern that is asymmetric with respect to the direction of shorte…
Capillary experiments of flow induced crystallization of HDPE
1990
Flow-induced crystallization experiments are made in a capillary apparatus modified with a downstream reservoir under pressure. Capillary length, diameter, and entrance angle are changed, as well as flow rate. The results show that the crystallization temperature is influenced both by the elongational flow at the capillary entrance and by the shear flow along the capillary. The independent effect of the pressure equals that obtained under static conditions. The effect of shear is correlated in terms of shearing work.
Effects of shear flow on the structure and dynamics of ionic liquids in a metallic nanoconfinement.
2021
It has been shown that a weak shear can induce crystallisation in a disordered, glassy state. In this study, we use molecular dynamics simulations in order to investigate the out-of-equilibrium properties of [BMIM][BF4] confined between metal slabs. In particular, we want to understand the extent to which the shear flow modifies the interfacial properties. In particular, the questions we address here are (i) is the shear able to promote the crystalline phase in [BMIM][BF4]? (ii) Can, as a consequence of shear flow, a solid-like layer develop at the interface with a metallic surface? (iii) What are the tribological properties of nanoconfined [BMIM][BF4]? We find that the system behaves quite…
Physical modelling of the melt flow during large-diameter silicon single crystal growth
2003
Abstract The reported investigations concern physical modelling of Czochralski growth of silicon large-diameter single crystals. InGaSn eutectic was used as a modelling liquid, employing actual criteria of the real process (Prandtl, Reynolds, Grashof numbers, etc.) and geometric similarity. A multi-channel measuring system was used to collect and process the temperature and flow velocity data. The investigations were focused on the study of heat transfer, in particular, the instability of the “cold zone” of the melt at the crystallization front.
The structure and stoichiometry of C-S-H
2004
Abstract This review relates to the models describing the structural evolution of calcium silicate hydrate (C-S-H) at the crystal–chemical level as a function of composition in terms of calcium to silicon ratio. The different models are compared and discussed in the light of recent spectroscopic and microscopic data. Taking into account the structure and the morphological properties of C-S-H, a surface reaction thermodynamic model has been proposed and discussed to predict and correlate the chemical and structural evolution of C-S-H with solution chemistry.
Plasmonic Focusing Reduces Ensemble Linewidth of Silver-Coated Gold Nanorods
2008
Silver coating gold nanorods reduces the ensemble plasmon line width by changing the relation connecting particle shape and plasmon resonance wavelength. This change, we term "plasmonic focusing", leads to less variation of resonance wavelengths for the same particle size distribution. We also find smaller single particle linewidth comparing resonances at the same wavelength but show that this does not contribute to the ensemble linewidth narrowing.
Bioprospective of Sorbus aucuparia leaf extract in development of silver and gold nanocolloids
2010
At the present time the bioprospective field is a dynamic area of research. The rapid biosynthesis of silver and gold nanoparticles without using toxic chemicals is reported here. Sorbus aucuparia is omnipresent in Europe. The aqueous leaves extract of the plant were used as reducing agent for the synthesis of silver and gold nanoparticles from their salt solutions. The synthesized nanoparticles were spherical, triangular and hexagonal in shape with an average size of 16 and 18nm for silver and gold, respectively. Different extract quantities, metal concentrations, temperatures and contact times were investigated to find their effect on nanoparticles synthesis. The resulting silver and gold…
Volume strain, strain type and flow path in a narrow shear zone
1998
This study explores the state of finite strain and changes in the mean kinematic vorticity number, grain size, whole-rock chemistry and mineralogy across an upper amphibolite-facies shear zone in a metadiorite, northern Malawi, east-central Africa. P–T conditions during shear-zone formation and deformation were approximately 700–750 °C and 5–7 kbar and are slightly less than P–T conditions for the regional peak of metamorphism. The major rock-forming minerals, plagioclase, hornblende, biotite, and quartz, were deformed by crystal-plastic processes accompanied by, except for hornblende, dynamic recrystallization. The modal abundance of all four major rock-forming minerals shows no systematic…
Thermoanalytical studies on phases of D-mannitol
1993
Abstract D-mannitol exists in several polymorphic crystalline forms. The conditions of crystallization are not well-defined, and in some cases mixtures of the different forms are obtained. In the DSC study the different forms melted nearly at the same temperature (166±°C). The heat of fusion of the k form was lower than those of the other forms. With slow heating rate (2 ° C min ) the δ form changed to k between 140 and 165 °C. The crystallization of D-mannitol from the melt gave from one to seven peaks in the DSC between 95 and 126 °C depending on cooling rates and the amounts of sample.