Search results for "Curve"

Sensitivity and Specificity of Stability Criteria for Immediately Loaded Splinted Maxillary Implants

2014

Background To assess the suitability of dental implants for immediate loading, primary stability is usually evaluated intraoperatively. Purpose This retrospective study aimed to assess the suitability of three stability parameters – namely, insertion torque (IT), implant stability quotient (ISQ; measured by resonance frequency analysis), and Periotest (PT) values – as potential predictors for the risk of nonosseointegration of immediately loaded splinted implants. The stability parameters were routinely collected under immediate loading. Materials and Methods Nineteen patients with 11 edentulous and 8 partially edentulous maxillae were treated with 105 dental implants, which were immediatel…

Damage and fracture study of cold extrusion dies

2004

Abstract In the present paper die fracture in cold extrusion was investigated considering a few different die reduction zone geometries. A former finite element method (FEM) analysis of the process was developed to obtain the contact pressure distribution at the workpiece–die interface for each of the investigated geometries; subsequently a stress and strain analysis utilizing the BEM code Franc3D was carried out, with the aim to evaluate the crack propagation at each loading cycle, i.e. at each extrusion process. In this way the die life for each of the investigated extrusion die geometries was compared utilizing the Paris law and the values assumed by the stress concentration coefficient …

Solution properties of polyelectrolytes

1991

Abstract Chromatographic data for sodium polystyrene sulphonate were obtained on both silica- and polymer-based size-exclusion supports using mobile phases of various pH and ionic strength. Deviations of the elution volume were observed towards both lower and higher values relative to the reference calibration graph obtained with uncharged standards. An empirical correlation is proposed in order to account for all the secondary effects observed. The general applicability of this correlation was further tested for chromatographic data obtained for a series of peptides and proteins on a silica-based support under very different eluent conditions. Deviations from ideal elution behaviour such a…

Flow-injection spectrophotometric determination of amino acids based on an immobilised copper(II) -zincon system

1993

Abstract The flow-injection spectrophotometric determination of different amino acids was carried out by reaction with copper(II) ions entrapped in a polymeric material and filling a packed-bed reactor; the released copper(II), complexed with the amino acid, reacted with zincon in a basic medium producing a blue colour that was monitored at 600 nm. The method was applied to determine the contents of different amino acids in pharmaceutical formulations. The calibration graph for glycine was linear over the range 0.5–20 μg ml −1 with a relative standard deviation of 0.8% ( n = 6) at 10 μg ml −1 and a sample throughput of 108 h −1 .

Processability and Properties of Re-Graded, Photo-Oxidized Post-Consumer Greenhouse Films

2005

The recycling of post‐consumer plastics leads, in general, to secondary materials having properties worse than those of the reclaimed material and certainly worse than those of the same virgin polymer. This is because of the degradation undergone by the objects during their use and because of the thermo‐mechanical degradation undergone during the reprocessing operations. The change of the molecular architecture is responsible for this worsening of properties. The use of stabilizing systems can slow the degradation during the melt processing but cannot give any improvement of the final properties of the material. In order to enhance the properties of the recycled plastics, some rebuilding of…

Re-gradation of Photo-oxidized Post-consumer Greenhouse Films

2005

The degradation undergone by the polymers during their use and because of the thermo-mechanical degradation undergone during the reprocessing operations provokes, among other effects, the decrease of the molecular weight. The change of the molecular architecture is responsable for the deterioration of all the properties. In order to restore the properties of post-consumer recycled plastics, some rebuilding of the molecular structure is necessary. In this work, photo-oxidized films for greenhouses were reprocessed in presence of additives able to react with the polyethylene in order to form branching and cross-linking, improving the properties of these post-consumer plastic.

Modeling and stress-strain characteristics of the mechanical properties of carbon-nanotube-reinforced poly(vinyl acetate) nanocomposites

2011

Polymer/carbon nanotube (CNT) composites are one of the most perspective advanced materials developed in recent years. The properties of CNT-reinforced polymer composites, however, strongly depend on structural aspects of the nanostructured filler and on its dispersion quality in a polymer matrix. Consequently, this research was devoted to the investigation of multiwalled-CNT-modified poly(vinyl acetate) (PVAc) composites with respect to the mechanical property dependence on some structural characteristics of CNTs. PVAc/CNT nanocomposites were obtained with a solution casting technique. The amount of CNTs was changed from 0.01 up to 2 wt %. The stress–strain characteristics of PVAc/CNT nano…

Effect of random copolymer additives on the interfacial tension between incompatible polymers

1998

Interfacial tensions γ were measured for mixtures of poly(methylphenylsiloxane) (4 kg/mol) and poly(dimethylsiloxane) (24 kg/mol) in the absence and in the presence of small amounts of the random copolymer poly(dimethylsiloxane-ran-methylphenylsiloxane) (89 mol-% of dimethylsiloxane units, 28 kg/mol) from 25 to 110°C. Approximately 1 wt.-% of the copolymer additive suffices to reduce γ from ca. 2.2 to 1.6 mN/m. The time dependence of the apparent γ value in the course of the attainment of equilibria also indicates surface acivity. The hypothesis is formulated that the efficiency of the random copolymer for a reduction of γ is bound to the condition that it is only sparingly soluble in both …

The fractal calibration method applied to the characterization of polymers in solvent mixtures and in mixed gel packings by SEC.

2007

The size-exclusion chromatographic (SEC) behaviour of different solvent/polymer systems in three packing sets has been analysed from fractal considerations. The three-column sets studied are specifically formed by: (i) 'pure' micro-styragel, (ii) 'mixed' TSK Gel H(HR + XL + HR) and (iii) mixed TSK Gel H(XL + HR + XL). The experimental data reveals that in most of the systems assayed the classical universal calibration (UC) is not fulfilled, denoting the existence of secondary effects accompanying the main SEC mechanism. In order to obtain an accurate characterization of different polymers eluted in solvent mixtures and/or mixed packings, the use of a reliable and trusted calibration curve i…

1996

An iterative, approximative procedure is presented, to calibrate the determination of molar masses of polymers with gel-permeation chromatography, additionally using viscometry, and transformations, according to Benoit's concept of universal calibration, even if only polymers with broad molar mass distribution are available. The calculated (intermediate) values of the average molar masses from each step of iteration converge to final values. With at least two fractions of the polymers to be analyzed, and with measured intrinsic viscosities of the fractions, a calibration curve of gel-permeation chromatography and Mark-Houwink's constants can be determined. Assumptions for the use of the cal…