Search results for "Cycloundecanone"

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1-Cycloundecen-3-in

1988

Es wird ein Syntheseweg fur (E)-1-Cycloundecen-3-in (E-5) beschrieben (Schema 2). Die extrem gespannte Verbindung isomerisiert sich bei Raumtemperatur mit einer Halbwertszeit von 2.2 h (ΔG≠ = 76 kJ/mol). Durch Rotation um die CC-Doppelbindung entsteht dabei (Z)-1-Cycloundecen-3-in (Z-5), das keine geometrische Ringspannung Eg mehr besitzt.

chemistry.chemical_classificationCycloundecanoneKetoneHydrocarbonchemistryStereochemistryOrganic Chemistrychemistry.chemical_elementPhysical and Theoretical ChemistryMedicinal chemistryIsomerizationSeleniumLiebigs Annalen der Chemie

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