Search results for "D2"
showing 10 items of 2418 documents
Fractal Weyl law for open quantum chaotic maps
2014
We study the semiclassical quantization of Poincar\'e maps arising in scattering problems with fractal hyperbolic trapped sets. The main application is the proof of a fractal Weyl upper bound for the number of resonances/scattering poles in small domains near the real axis. This result encompasses the case of several convex (hard) obstacles satisfying a no-eclipse condition.
Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties
2020
The control of ligand-field splitting in iron (II) complexes is critical to slow down the metal-to-ligand charge transfer (MLCT)-excited states deactivation pathways. The gap between the metal-centered states is maximal when the coordination sphere of the complex approaches an ideal octahedral geometry. Two new iron(II) complexes (C1 and C2), prepared from pyridylNHC and pyridylquinoline type ligands, respectively, have a near-perfect octahedral coordination of the metal. The photophysics of the complexes have been further investigated by means of ultrafast spectroscopy and TD-DFT modeling. For C1, it is shown that&mdash
Système semis direct non permanent (SD2) testé sur CA-SYS
2019
National audience
Structure-function analysis of peroxisomal ATP-binding cassette transporters using chimeric dimers
2014
Background: Peroxisomal ABC transporters are predicted to function as homodimers in mammals. [br/] Results: ABCD1 interacts with ABCD2. Chimeric proteins mimicking full-length dimers represent novel tools for functional study. Artificial homodimers and heterodimers are functional. [br/] Conclusion: Interchangeability between ABCD1 and ABCD2 is confirmed, but PUFA transport depends on ABCD2. [br/] Significance: For the first time, heterodimers in mammals are proven to be functional.[br/] ABCD1 and ABCD2 are two closely related ATP-binding cassette half-transporters predicted to homodimerize and form peroxisomal importers for fatty acyl-CoAs. Available evidence has shown that ABCD1 and ABCD2 …
Influence of Temperature, Solvent and pH on the Selective Extraction of Phenolic Compounds from Tiger Nuts by-Products: Triple-TOF-LC-MS-MS Character…
2019
The aim of this study was to assess the effect of temperature, solvent (hydroethanolic mixtures) and pH on the recovery of individual phenolic compounds from &ldquo
Effect of the pea (Pisum sativum L.) gene PsSym36 on Glomus intraradices gene expression
2007
International audience; The Pisum sativum L. mutant RisNod24 (Pssym36) is defective for arbuscular mycorrhiza formation in late stages of AM. Recent studies identified some plant genes up- and down- regulated at stage of arbuscular development using pea mutant RisNod24, but nothing is still known about fungal gene inactivation. To investigate effect of PsSym36 pea gene on fungal gene expression, Glomus intraradices genes which have been previously identified as markers of successful symbiosis development (Seddas et al., unpublished results) were chosen. List of AM genes used in this study: signalling, transcription, protein turn-over (RHO/GDP dissociation inhibitor, Peptidylprolyl isomerase…
La maximisation microéconomique du taux de profit
1992
National audience; Dans la théorie microéconomique traditionnelle, les firmes sont supposées maximiser le profit pur. Nous étudions ici l'impact de la prise en compte des actionnaires et d'un profit social rémunérant le capital. On montre les conséquences de l'abandon de la maximisation du profit pour considérer la maximisation du taux de profit social. Les cas de concurrence avec coefficient fixe de capital, monopole avec coefficient fixe de capital, monopole avec coefficient variable de capital sont étudiés. Les solutions fournies par les comportements de maximisation du profit et de maximisation du taux de profit sont comparées. On conclut à une réduction du volume d'investissement dans …
Acetone Vapor-Sensing Properties of Chitosan-Polyethylene Glycol Using Surface Plasmon Resonance Technique
2020
To non-invasively monitor and screen for diabetes in patients, there is need to detect low concentration of acetone vapor in the range from 1.8 ppm to 5 ppm, which is the concentration range of acetone vapor in diabetic patients. This work presents an investigation for the utilization of chitosan-polyethylene glycol (PEG)-based surface plasmon resonance (SPR) sensor in the detection of trace concentration acetone vapor in the range of breath acetone in diabetic subjects. The structure, morphology, and elemental composition of the chitosan-PEG sensing layer were characterized using FTIR, UV-VIS, FESEM, EDX, AFM, and XPS methods. Response testing was conducted using low concentration of aceto…
Tackling Performance Challenges in Organic Photovoltaics: An Overview about Compatibilizers
2020
Organic Photovoltaics (OPVs) based on Bulk Heterojunction (BHJ) blends are a mature technology. Having started their intensive development two decades ago, their low cost, processability and flexibility rapidly funneled the interest of the scientific community, searching for new solutions to expand solar photovoltaics market and promote sustainable development. However, their robust implementation is hampered by some issues, concerning the choice of the donor/acceptor materials, the device thermal/photo-stability, and, last but not least, their morphology. Indeed, the morphological profile of BHJs has a strong impact over charge generation, collection, and recombination processes; control o…
Hydrothermal Ageing Effect on Reinforcement Efficiency of Nanofibrillated Cellulose/Biobased Poly(butylene succinate) Composites
2022
Nanofibrillated cellulose (NFC) is a sustainable functional nanomaterial known for its high strength, stiffness, and biocompatibility. It has become a key building block for the next-generation of lightweight, advanced materials for applications such as consumer products, biomedical, energy storage, coatings, construction, and automotive. Tunable and predictable durability under environmental impact is required for high performance applications. Bio-based poly (butylene succinate) (PBS) composites containing up to 50% NFC content were designed and aged in distilled water or at high relative humidity (RH98%). PBS/NFC composites are characterized by up to 10-fold increased water absorption ca…