Search results for "DF"

showing 10 items of 1699 documents

Automātiska teksta konspektēšana izmantojot jēdzientelpu

2016

Šobrīd pasaulē ir vērojams milzīgs informācijas daudzuma pieaugums un ir arvien grūtāk iepazīties ar šo informāciju. Automātiskas teksta konspektēšanas mērķis ir spēt pārveidot lielu tekstuālas informācijas daudzumu īsākā formātā, kurš spēj saglabāt oriģinālā teksta svarīgāko informāciju. Viena no metodēm kā automātiski konspektēt tekstu ir izvēlēties svarīgākos teikumus no teksta. Mērķis ir izvēlēties teikumus tā, lai tajos esošā informācija savstarpēji nepārklājas, kā arī nosedz pietiekamu daļu no konspektējamā teksta. Lai to izdarītu ir jāsalīdzina teikumu ietvertās informācijas līdzīgums. Jēdzientelpa ir moderns rīks, ar kura palīdzību var noteikt vārdu nozīmi un līdzību ar citiem vārdi…

ekstraktīva konspektēšanajēdzientelpaDatorzinātneword2vecTF-IDF
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Mindfulness y duelo: cómo la serenidad mindful y la compasión contribuyen al bienestar tras la pérdida

2017

En esta primera parte de la tesis doctoral, pretendemos construir y exponer un marco teórico que conexione duelo y mindfulness, a través de una revisión de la literatura científica. ¿Qué necesidades presentan los dolientes tras la pérdida de un ser querido según la bibliografía revisada? ¿ Qué puede aportar mindfulness en el ámbito del duelo? (teniendo en cuenta los resultados revisados en el ámbito del bienestar psicológico en general y la literatura que relaciona mindfulness y duelo). Una vez revisada la literatura existente, crearemos una adaptación del programa MBSR dirigido a dolientes, que recibirá el nombre de programa MADED (Mindfulness para la aceptación del dolor y las emociones e…

elaboraciónmindfulnesspsicología positivacompasión:PSICOLOGÍA [UNESCO]dueloregulación emocionalUNESCO::PSICOLOGÍA
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Gas phase behavior of radical cations of perfluoroalkyl-1,2,4-triazines: an experimental and theoretical study

2009

Electron ionization mass spectrometry and low-energy collision-induced decomposition reactions occurring in a tridimensional ion trap, together with density functional theory (DFT) calculations on neutrals, even- and odd-electron cations, have been used to study the gas-phase ion chemistry of a series of perfluoroalkyl-1,2,4-triazines. Loss of oxygen, due to thermal degradation occurring before ionization, likely involving the hydroxylamino group, has been observed. Compounds having a carbonyl group at position 6 of the triazine ring fragment in the source by elimination of NO followed by HF or CO. The decomposition pathways occurring due to CID experiments have shown interesting features d…

electron ionizationFree RadicalsStereochemistryIonic bondingDFT calculationAntineoplastic AgentsMass spectrometryGas Chromatography-Mass SpectrometryIonradical ionTandem Mass SpectrometryComputational chemistrySpectroscopyElectron ionizationFluorocarbonsMolecular StructureTriazinesChemistryPolyatomic ionSettore CHIM/06 - Chimica OrganicaModels ChemicalRadical ionUnpaired electronDensity functional theorytriazineGasesfluorinated compounds
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Elektronisko parakstu īstenošana PDF dokumentos

2015

Šis darbs apskata elektronisko parakstu īstenošanu PDF dokumentos. Tas pēta elektronisko parakstu struktūru un funkcionalitāti. Darba mērķis ir izpētīt elektronisko parakstu standartus PDF dokumentiem, struktūru, darbības principus un īstenošanas iespējas. Uzmanība tiek pievērsta pakarstu struktūrai, un ir apskatīti nepieciešamie dati elektronisko parakstu veidošanai. Tiek izpētīti papildus procesi un servisi, kurus ir nepieciešams nodrošināt elektronisko parakstu sniedzēju pusē. Papildus tiek apskatīti dažu elektronisko parakstu sniedzēju produkti. Darbā tiek aprakstīta tīmekļa lietotnes veidošana, kas nodarbojas ar parakstu pievienošanu un parakstu pārbaudi PDF dokumentos. Tiek parādīts, …

elektroniskie parakstiDatorzinātnePDF dokumentisertifikātielektronisko parakstu sniedzēji
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Behavioral and psychological flexibility in eating regulation among overweight adults

2016

Weight-loss programs are often based on self-control techniques and they commonly fail in long-term weight management. Identifying psychological processes that explain eating behaviors can help to develop more effective interventions for long-term weight management. This research examined how behavioral and psychological flexibility are related to eating regulation and weight management in overweight adults. The first goal was to study the effects of flexible vs. rigid restraint of eating on weight-loss maintenance and well-being. The second goal was to examine whether psychological flexibility and mindfulness, independently and together, explain intuitive eating regulation. The third goal …

elintavatmindfulnesslaihdutushyväksymis- ja omistautumisterapiaylipainoruokatavatintuitive eatingflexible vs. rigid eating restraintpsychological flexibilityweight-loss maintenancepainonhallintaacceptance and commitment therapyruokatottumuksetjoustavuussyöminenoverweightaikuisettietoinen läsnäolo
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Biochar from Waste Derived Fuels as Low-Cost Adsorbent for Waste Hydrocarbons

2020

Abstract The aim of this study is to prove technical feasibility of combined refuse derived fuel (RDF) torrefaction and oily wastewater treatment approach by using RDF derived biochar as a sorption media. Biochars prepared from refuse derived fuels in torrefaction, carbonization and pyrolysis modes were analysed as fuels and as hydrocarbon sorbents. Changes of elemental composition and properties of material during thermal treatment and subsequent washing process have been analysed. Experimental evaluation of sorption behaviour of toluene and diesel fuel on obtained biochar performed. Our results show that torrefaction/carbonization of RDF coupled with the subsequent washing of biochar is a…

emulsified wastesMaterials scienceRenewable Energy Sustainability and the EnvironmentCarbonization020209 energycarbonizationTJ807-83002 engineering and technology010501 environmental sciencesTorrefactionrdf (refuse derived fuel)01 natural sciencesRenewable energy sourcestorrefactionAdsorptionChemical engineeringBiochar0202 electrical engineering electronic engineering information engineeringAbsorption (electromagnetic radiation)absorption0105 earth and related environmental sciencesGeneral Environmental ScienceEnvironmental and Climate Technologies
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Recent developments and applications of the chiral Brønsted acid catalyzed allylboration of carbonyl compounds

2018

The 50-year-old allylboration reaction has seen dramatic developments since the dawn of the new century after the first catalytic asymmetric versions came into play. In the past decade alone, several methodologies capable of achieving the desired homoallylic alcohols in over 90% ee have been developed. This review focuses on the chiral Brønsted acid catalyzed allylboration reaction, covering everything from the very first examples and precedents to modern day variations and applications.1 Introduction2 Early Developments3 Synthetic Applications4 Variants5 Computational Contribution6 Conclusions

enantioselective catalysis010405 organic chemistryChemistryOrganic Chemistryasymmetric synthesisEnantioselective synthesis010402 general chemistryDFT calculations01 natural sciencesCombinatorial chemistryCatalysis0104 chemical sciencesCatalysishomoallylic alcoholsallylborationchiral Brønsted acidsBrønsted–Lowry acid–base theoryenantioselective catalysis­chiral BrOnsted acids
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Katalizatory i proces koordynacyjnej polimeryzacji etylenu - eksperyment i teoria

2004

Badania eksperymentalne i teoretyczne koordynacyjnej polimeryzacji etylenu przeprowadzono wobec katalizatorów otrzymanych z prekursorów - kompleksów halogenków Ti, Zr, Hf, V z organicznymi zasadami Lewisa, nośnika magnezowego [MgCl2(THF)2] i związków glinoorganicznych. Określono zależnosć pomiędzy rodzajem halogenków w prekursorze a aktywnością katalizatora wanadowego. Ustalono profile energetyczne reakcji insercji i terminacji (beta-eliminacji) oraz przeniesienia atomu wodoru beta. Obliczone wartości barier insercji, a także energii wiązania etylenu do centrum aktywnego dobrze korelują z wynikami polimeryzacji. Stwierdzono występowanie w centrach aktywnych oddziaływań agostycznych, które o…

energetic profilesHfkompleksy halogenków TiZrHf i Vreakcja terminacjikoordynacyjna polimeryzacja etylenuprofil energetycznycatalytic activitynośnik magnezowyreakcja insercjimagnesium supportV halidesdensity functionals method (DFT)aktywność katalitycznaoxygen-donor ligandsinsertion and termination reactionspolimeryzacja etylenucoordination polymerization of ethylenecomplexes of Tiligandy tlen-donorowePolimery
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Water dissociation and water-gas shift energetics on MgO, MgO/Ag and Au/MgO/Ag surfaces

2011

Water dissociation and the energetics of the WGS reaction on a bulk MgO, an Ag supported MgO thin film and Au/MgO/Ag surfaces is studied based on the density functional theory. The literature results for water splitting on MgO and MgO/Ag surfaces with a step type defect are repeated and further analysis on the origin of the energetically favored dissociative water adsorption are made. The reactivity towards water dissociation on the stepped MgO and MgO/Ag surfaces is attributed to four contributing factors: 1. The change in the interlayer distance of the surface in dissociative adsorption is diminished on the stepped surfaces compared to the flat surfaces. On the flat surfaces the dissociat…

energetiikkaMgO thin filmMgO surfacewater-gas shiftfysiikkaDFTwater dissociationAu cluster
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UNEDF-parametrisaatioiden ennustamien sidosenergioiden tilastolliset virheet

2015

Tämän pro gradu -tutkielman tavoitteena oli tutkia UNEDF0, UNEDF1 ja UNEDF2-parametrisaatioiden ennustamia sidosenergioita ja näiden tilastollisia virheitä eri ytimille HFBTHO-tietokone-ohjelmaa käyttäen. Tilastollisena virheenä käytin keskihajontaa. Tarkasteltavana olivat parillis-parilliset Gd-ytimet (A=130−180), parillis-parilliset Dy-ytimet (A=140−182) sekä UNEDF1- ja UNEDF2-parametrisaatioissa parametrien sovitukseen käytetyt ytimien U-226, U-238, Pu-240 ja Cm-242 fissioisomeerit. Vertasin laskennallisia sidosenergioita ja näiden virheitä niin toisiinsa kuin kokeellisesti määritettyihin arvoihin. Lisäksi tutkin, mitkä käytettyjen mallien parametreista ovat eniten vastuussa tilastollise…

energiaSkyrmeUNEDFtilastollinen virheydinfysiikkasidosenergiaHFB
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