Search results for "DF"
showing 10 items of 1699 documents
Effect of solid waste landfill organic pollutants on groundwater in three areas of Sicily (Italy) characterized by different vulnerability
2017
The aim of this study was to obtain information on the presence and levels of hazardous organic pollutants in groundwater located close to solid waste landfills. Eighty-two environmental contaminants, including 16 polycyclic aromatic hydrocarbons (PAHs), 20 volatile organic compounds (VOCs), 29 polychlorinated biphenyls (PCBs), 7 dioxins (polychlorinated dibenzo-p-dioxins, PCDDs) and 10 furans (polychlorinated dibenzofurans, PCDFs) were monitored in areas characterised by different geological environments surrounding three municipal solid waste landfills (Palermo, Siculiana and Ragusa) in Sicily (Italy) in three sampling campaigns. The total concentrations of the 16 PAHs were always below t…
Utilization of Poly(vinylchloride) and Poly(vinylidenefluoride) as Macroinitiators for ATRP Polymerization of Hydroxyethylmethacrylate. Electroanalyt…
2015
The utilization of poly(vinylchloride) (PVC) and poly(vinylidenefluoride) (PVDF) as macroinitiators for atom transfer radical polymerization (ATRP) of hydroxyethylmethacrylate (HEMA) was studied performing electroanalytical investigations and “grafting from” experiments in order to achieve information on the possibility of modifying such commercial polymers by this controlled free radical polymerization technique. This study was performed changing various operating parameters such as the nature of the copper salt, the ligand, the solvent, the temperature and the reaction time. Electroanalytical data suggest that PVC can be easily activated by both CuCl/ Tris(2-pyridylmethyl)amine (TPMA) and…
Novel meso-substituted porphyrins: Synthesis, characterization and photocatalytic activity of their TiO2-based composites
2009
Abstract Two series of novel meso-substituted porphyrins, namely 5,10,15,20-tetra[4-(3-phenoxy)-propoxy]phenyl porphyrin, the structural analogue 5,10,15,20-tetra[2-(3-phenoxy)-propoxy]phenyl porphyrin and their Co(II) Cu(II) and Zn(II) complexes were synthesized. The compounds were characterized using various spectroscopic techniques and their molecular structure was proposed based on density functional theory calculations. The diverse properties of the porphyrin derivatives result from the different stereochemistry of the particular substituents at the meso site on the macrocycle and are controlled also by the coordinated metal. The 1H NMR spectrum of the free-base porphyrin showed a comp…
Monadic second-order logic over pictures and recognizability by tiling systems
1994
We show that a set of pictures (rectangular arrays of symbols) is recognized by a finite tiling system if and only if it is definable in existential monadic second-order logic. As a consequence, finite tiling systems constitute a notion of recognizability over two-dimensional inputs which at the same time generalizes finite-state recognizability over strings and matches a natural logic. The proof is based on the Ehrenfeucht-FraIsse technique for first-order logic and an implementation of “threshold counting” within tiling systems.
Monadic Second-Order Logic over Rectangular Pictures and Recognizability by Tiling Systems
1996
Abstract It is shown that a set of pictures (rectangular arrays of symbols) is recognized by a finite tiling system iff it is definable in existential monadic second-order logic. As a consequence, finite tiling systems constitute a notion of recognizability over two-dimensional inputs which at the same time generalizes finite-state recognizability over strings and also matches a natural logic. The proof is based on the Ehrenfeucht–Fraisse technique for first-order logic and an implementation of “threshold counting” within tiling systems.
Recent results on syntactic groups of prefix codes
2012
International audience; We give a simplified presentation of groups in transformation monoids. We use this presentation to describe two recent results on syntactic groups of prefix codes. The first one uses Sturmian words to build finite bifix codes with a given permutation group as syntactic group. The second one describes a class of prefix codes such that all their syntactic groups are cyclic.
Some Decision Results on Nonrepetitive Words
1985
The paper addresses some generalizations of the Thue Problem such as: given a word u, does there exist an infinite nonrepetitive overlap free (or square free) word having u as a prefix? A solution to this as well as to related problems is given for the case of overlap free words on a binary alphabet.
Promoting Wellbeing in Pregnancy: A Multi-component Positive Psychology and Mindfulness-Based Mobile App
2019
Pregnancy involves important changes for women of all ages: it is a time of physical and psychological change. Women may experience anxiety and negative emotions, which can negatively influence their wellbeing and make difficult their adaptation to the new role of mothers. Furthermore, poor mental well-being and difficulties in emotion regulation can negatively affect obstetric outcomes, development of the child and neonatal adaptation. The aim of this work is to present a new self-applied multi-component positive psychology- and mindfulness-based intervention (MPPMI) supported by a mobile App addressed to pregnant women. The core of this MPPMI is to combine traditional positive psychology …
Computational investigation of isoeugenol transformations on a platinum cluster – I: Direct deoxygenation to propylcyclohexane
2022
The growing demand for renewable and sustainable fuels, protagonists of an increasingly important research area due to the exhaustion of fossil resources, has oriented our investigation towards the computational mechanistic analysis of the catalytic hydrodeoxygenation (HDO) reaction of isoeugenol. Having the most com mon functional groups, the isoeugenol molecule is actually considered as an experimental and computational model for typical species of biomass origin. The reported computational investigation outlines the energy bar riers and the intermediates along the path for the conversion of isoeugenol to propylcyclohexane through a direct deoxygenation mechanims, catalyzed by a subnano…
Density functional theory (DFT) prediction of structural and spectroscopic parameters of cytosine using harmonic and anharmonic approximations
2015
The applicability of popular and efficient B3LYP hybrid density functional and medium-size Pople-type basis set in combination with computationally expensive anharmonic model to obtain more accurate theoretical structure, vibrational frequencies and GIAO NMR parameters of cytosine was tested. We report on prediction of cytosine equilibrium (R e ) and rovibrationally averaged (R v ) structures and vibrational frequencies in the gas phase and DMSO solution using density functional theory combined with 6-311++G** basis set. The harmonic and anharmonic vibrational frequencies (using second-order vibrational perturbation theory, VPT2) were critically discussed. In comparison with initial harmoni…