Search results for "DIR"
showing 10 items of 10242 documents
Review of the PEA Method for Space Charge Measurements on HVDC Cables and Mini-Cables
2019
This review takes into account articles and standards published in recent years concerning the application of the Pulsed Electro Acoustic (PEA) method for space charge measurement on High Voltage Direct Current (HVDC) cables and mini-cables. Since the 80s, the PEA method has been implemented for space charge measurements on flat specimens in order to investigate space charge phenomena and to evaluate the ageing of dielectrics. In recent years, this technique has been adapted to cylindrical geometry. Several studies and experiments have been carried out on the use of the PEA method for full size cables and HVDC cable models. The experiments have been conducted using different arrangements of…
Optical quantum information processing and storage
2018
Here we report our recent experimental progresses in optical quantum information processing. In particular, the following topics are included. First, we extend the heralding scheme to multi-mode states and demonstrate heralded creation of qutrit states. Next, we demonstrate storage of single-photon states and synchronized release of them. Then, we demonstrate real-time acquisition of quadrature values of heralded states by making use of an exponentially rising shape of wave-packets. Finally, we demonstrate cluster states in an arbitrarily long chain in the longitudinal direction.
Intermolecular and Intramolecular Transamidation Reactions
2006
The amide functional group is resonance stabilised and direct reaction with amines is known to be difficult. Facile amide exchange reactions would enable the synthesis of important new amide based molecules, therefore transamidation reactions represent an important step in this direction. In order to ensure a transamidation reaction takes place, special requirements and conditions are required. According to the different structural characteristics of the carbox-amide group and types of activation, the most relevant examples of this reaction will be reviewed.
Half-sandwich complexes of molybdenum-(III), -(IV) and -(V) with P–O and P–N bifunctional ligands Ph2PCH2X (X = 2-oxazolinyl, or C(O)NPh2)
2000
International audience; The reaction of the ligands Ph2PCH2X (X = 2-oxazolinyl, I; or C(O)NPh2, II) with the half-sandwich molybdenum(III) precursors [Mo(η-C5R5)(μ-Cl)2]2 (R = H or Me) has been investigated. Ligand I reacts with both complexes to form the corresponding adducts [Mo(η-C5R5)Cl2(Ph2PCH2C3H4NO)] (R = H, 1; or Me, 2). The reaction between I and [MoCp*Cl4] (Cp* = η-C5Me5) affords [MoCp*Cl4(Ph2PCH2C3H4NO-κ1P)] as a kinetic isomer, which then transforms quantitatively to [MoCp*Cl3(Ph2PCH2C3H4NO-κ2P,N)]+Cl−, 3. Ligand II reacts with [MoCp(μ-Cl)2]2 (Cp = η-C5H5) to afford the adduct [CpMoCl2{Ph2PCH2C(O)NPh2-κ2P,O}], 4, as an equilibrium mixture of two isomers. Longer reaction times in…
Insights into the Mechanism of Anodic N–N Bond Formation by Dehydrogenative Coupling
2017
The electrochemical synthesis of pyrazolidine-3,5-diones and benzoxazoles by N-N bond formation and C,O linkage, respectively, represents an easy access to medicinally relevant structures. Electrochemistry as a key technology ensures a safe and sustainable approach. We gained insights in the mechanism of these reactions by combining cyclovoltammetric and synthetic studies. The electron-transfer behavior of anilides and dianilides was studied and led to the following conclusion: The N-N bond formation involves a diradical as intermediate, whereas the benzoxazole formation is based on a cationic mechanism. Besides these studies, we developed a synthetic route to mixed dianilides as starting m…
Analysis of directional effects on atmospheric correction
2013
Abstract Atmospheric correction in the Visible and Near Infrared (VNIR) spectral range of remotely sensed data is significantly simplified if we assume a Lambertian target. However, natural surfaces are anisotropic. Therefore, this assumption will introduce an error in surface directional reflectance estimates and consequently in the estimation of vegetation indexes such as the Normalized Difference Vegetation Index (NDVI) and the surface albedo retrieval. In this paper we evaluate the influence of directional effects on the atmospheric correction and its impact in the NDVI and albedo estimation. First, we derived the NDVI and surface albedo from data corrected assuming a Lambertian surface…
Gravitational-wave Detection and Parameter Estimation for Accreting Black-hole Binaries and Their Electromagnetic Counterpart
2020
We study the impact of gas accretion on the orbital evolution of black-hole binaries initially at large separation in the band of the planned Laser Interferometer Space Antenna (LISA). We focus on two sources: (i)~stellar-origin black-hole binaries~(SOBHBs) that can migrate from the LISA band to the band of ground-based gravitational-wave observatories within weeks/months; and (ii) intermediate-mass black-hole binaries~(IMBHBs) in the LISA band only. Because of the large number of observable gravitational-wave cycles, the phase evolution of these systems needs to be modeled to great accuracy to avoid biasing the estimation of the source parameters. Accretion affects the gravitational-wave p…
Modelling the Effects of Climate Change on the Supply of Inorganic Nitrogen
2009
Human-induced changes in the nitrogen cycle due to the increased use of artificial fertilisers, the cultivation of nitrogen-fixing crops and atmospheric deposition have made nitrogen pollution to surface waters a long-standing cause for concern. In Europe, legislation has been introduced to minimise the risk of water quality degradation from excessive nitrogen inputs e.g., the European Union Nitrates Directive (EU, 1991), Drinking Water Directive (EU, 1998) and Water Framework Directive (EU, 2000). Coastal regions in particular have been an important focus, since coastal eutrophication has been attributed to increased fluxes of nitrogen from the landscape (Howarth et al., 1996; Boesch et al…
Evaluation of the MODIS Albedo product over a heterogeneous agricultural area
2013
In this article, the Moderate Resolution Imaging Spectroradiometer MODIS Bidirectional Reflectance Distribution Function BRDF/Albedo product MCD43 is evaluated over a heterogeneous agricultural area in the framework of the Earth Observation: Optical Data Calibration and Information Extraction EODIX project campaign, which was developed in Barrax Spain in June 2011. In this method, two models, the RossThick-LiSparse-Reciprocal RTLSR which corresponds to the MODIS BRDF algorithm and the RossThick-Maignan-LiSparse-Reciprocal RTLSR-HS, were tested over airborne data by processing high-resolution images acquired with the Airborne Hyperspectral Scanner AHS sensor. During the campaign, airborne im…
The influence of the wind direction and plants on the variability of topsoil magnetic susceptibility in industrial and urban areas of southern Poland
2016
Volume magnetic susceptibility (κ) was measured on the soil surface and in the vertical topsoil profile within a 300 km2 area located in an urban-industrial conurbation. The results were compared to plant species compositions in the forest storeys, elevation above sea level, and terrain geomorphology. The content and mineral composition of the magnetic fraction were determined in the soil horizons. It was found that the extent of the area with enhanced topsoil magnetic susceptibility was similar to the dominant wind direction (south–west). Enhanced κ values were observed for the soil at the forest margin on the leeward side of the emitters as well as at sites located on exposed local elevat…