Search results for "DNET"
showing 10 items of 33 documents
Sensitive Assays by Nucleophile-Induced Rearrangement of Photoactivated Diarylethenes.
2018
Upon light-induced isomerization, diarylethenes (DAEs) equipped with reactive aldehyde moieties rearrange selectively in the presence of amines, accompanied by decoloration. In a comprehensive study, the probe structure was optimized with regard to its inherent reactivity in the nucleophile-triggered rearrangement reaction. Detailed structure−reactivity relationships could be derived, in particular with regard to the type of integrated (het)aryl moieties as well as the location of the formyl residue, and the probes’ intrinsic reactivity with primary and secondary amines was optimized. Utilizing an ancillary base, the initially formed rearrangement product can engage in a subsequent catalyti…
Sense Equivalence in plWordNet to Princeton WordNet Mapping
2019
Abstract Though the interest in use of wordnets for lexicography is (gradually) growing, no research has been conducted so far on equivalence between lexical units (or senses) in inter-linked wordnets. In this paper, we present and validate a procedure of sense-linking between plWordNet and Princeton WordNet. The proposed procedure employs a continuum of three equivalence types: strong, regular and weak, distinguished by a custom-designed set of formal, semantic and translational features. To validate the procedure, three independent samples of 120 sense pairs were manually analysed with respect to the features. The results show that synsets from the two wordnets linked by interlingual syno…
Broadband Multi-wavelength Properties of M87 during the 2017 Event Horizon Telescope Campaign
2021
Full list of authors: EHT MWL Science Working Group; Algaba, J. C.; Anczarski, J.; Asada, K.; Baloković, M.; Chandra, S.; Cui, Y. -Z.; Falcone, A. D.; Giroletti, M.; Goddi, C.; Hada, K.; Haggard, D.; Jorstad, S.; Kaur, A.; Kawashima, T.; Keating, G.; Kim, J. -Y.; Kino, M.; Komossa, S.; Kravchenko, E. V.; Krichbaum, T. P.; Lee, S. -S.; Lu, R. -S.; Lucchini, M.; Markoff, S.; Neilsen, J.; Nowak, M. A.; Park, J.; Principe, G.; Ramakrishnan, V.; Reynolds, M. T.; Sasada, M.; Savchenko, S. S.; Williamson, K. E.; Event Horizon Telescope Collaboration; Akiyama, Kazunori; Alberdi, Antxon; Alef, Walter; Anantua, Richard; Azulay, Rebecca; Baczko, Anne-Kathrin; Ball, David; Barrett, John; Bintley, Dan; …
Search for Multimessenger Sources of Gravitational Waves and High-energy Neutrinos with Advanced LIGO during Its First Observing Run, ANTARES, and Ic…
2019
[EN] Astrophysical sources of gravitational waves, such as binary neutron star and black hole mergers or core-collapse supernovae, can drive relativistic outflows, giving rise to non-thermal high-energy emission. High-energy neutrinos are signatures of such outflows. The detection of gravitational waves and high-energy neutrinos from common sources could help establish the connection between the dynamics of the progenitor and the properties of the out¿ow. We searched for associated emission of gravitational waves and high-energy neutrinos from astrophysical transients with minimal assumptions using data from Advanced LIGO from its first observing run O1, and data from the ANTARES and IceCub…
PyDSC: a simple tool to treat differential scanning calorimetry data
2020
AbstractHerein, we describe an open-source, Python-based, script to treat the output of differential scanning calorimetry (DSC) experiments, called pyDSC, available free of charge for download at https://github.com/leonardo-chiappisi/pyDSC under a GNU General Public License v3.0. The main aim of this program is to provide the community with a simple program to analyze raw DSC data. Key features include the correction from spurious signals, and, most importantly, the baseline is computed with a robust, physically consistent approach. We also show that the baseline correction routine implemented in the script is significantly more reproducible than different standard ones proposed by propriet…
Word sense disamibiguation combining conceptual distance, frequency and gloss
2004
Word sense disambiguation (WSD) is the process of assigning a meaning to a word based on the context in which it occurs. The absence of sense tagged training data is a real problem for the word sense disambiguation task. We present a method for the resolution of lexical ambiguity which relies on the use of the wide-coverage noun taxonomy of WordNet and the notion of conceptual distance among concepts, captured by a conceptual density formula developed for this purpose. The formula we propose, is a generalised form of the Agirre-Rigau conceptual density measure in which many (parameterised) refinements were introduced and an exhaustive evaluation of all meaningful combinations was performed.…
Sub-symbolic Encoding of Words
2003
A new methodology for sub-symbolic semantic encoding of words is presented. The methodology uses the WordNet lexical database and an ad hoc modified Sammon algorithm to associate a vector to each word in a semantic n-space. All words have been grouped according to the WordNet lexicographers’ files classification criteria: these groups have been called lexical sets. The word vector is composed by two parts: the first one, takes into account the belonging of the word to one of these lexical sets; the second one is related to the meaning of the word and it is responsible for distinguishing the word among the other ones of the same lexical set. The application of the proposed technique over all…
Light-controlled reversible modulation of frontier molecular orbital energy levels in trifluoromethylated diarylethenes
2017
Among bistable photochromic molecules, diarylethenes (DAEs) possess the distinct feature that upon photoisomerization they undergo a large modulation of their π-electronic system, accompanied by a marked shift of the HOMO/LUMO energies and hence oxidation/reduction potentials. The electronic modulation can be utilized to remote-control charge- as well as energy-transfer processes and it can be transduced to functional entities adjacent to the DAE core, thereby regulating their properties. In order to exploit such photoswitchable systems it is important to precisely adjust the absolute position of their HOMO and LUMO levels and to maximize the extent of the photoinduced shifts of these energ…
Instrumental calculation, cognitive role-playing, or both?: self-perceptions of Seconded National Experts in the European Commission
2011
This is the authors’ final, accepted and refereed manuscript to the article Most work studying micro-processes of integration – i.e. how agents develop identities and decision-making behaviours within a particular institution – offers explanations based on either instrumental rationality or socialisation. This article proposes a two-dimensional framework that allows analysing under which conditions both logics of social action co-exist. Our empirical analysis employs a unique dataset from a 2011 survey of all 1098 currently active Seconded National Experts (SNEs) in the European Commission. We find that a) instrumental cost-benefit calculation and cognitive role-playing (as semi-reflexive s…
Knowledge gaps and future directions in cognitive functions in children and adolescents with primary arterial hypertension: A systematic review
2022
Arterial hypertension (AH) among adults is known to be associated with worse cognitive outcomes. Similarly, children and adolescents with AH could be expected to underperform during neuropsychological evaluations when compared with healthy peers. Our aims were to review the existing literature on cognitive functioning among children and adolescents with primary AH and to identify what additional evidence may be needed to substantiate the impact of hypertension on poor cognitive outcomes in this population. We conducted a systematic review of articles in PubMed and Web of Science published before 17 January 2022, reporting on cognitive testing among children and adolescents with primary AH. …