Search results for "Density"

A Theoretical Study of the Favorskii Rearrangement. Calculation of Gas-Phase Reaction Paths and Solvation Effects on the Molecular Mechanism for the …

1997

The molecular mechanism of the α-chlorocyclobutanone transposition to yield cyclopropanecarboxylic acid, as a model of the Favorskii rearrangement, has been theoretically characterized in vacuo by means of ab initio molecular orbital procedures at the Hartree−Fock (HF) level of theory with the 6-31G* and 6-31+G* basis sets. The electron correlation has been estimated at the MP2/6-31G* level and calculations based on density functional theory, BLYP/6-31G*. The solvent effects are included at HF/6-31G* level by means of a polarizable continuum model. The questions related to the two accepted molecular mechanisms, the semibenzilic acid and the cyclopropanone transpositions, as well as the comp…

1990

The countercurrent extraction method recently developed for the continuous polymer fractionation (CPF) was applied to linear polyethylene (Mw = 55 kg/mol; Mn = 16,7 kg/mol). At temperatures higher than 130°C, moderately concentrated solution of polyethylene were extracted to remove the low-molecular-weight components. Discontinuous fractionation experiments served to detect the best suited solvents. Diphenyl ether was chosen to demonstrate that the present extraction can be performed even with the same single solvent used to prepare the feed. For very high-molecular-weight polymers, mixed solvents are, however, normally better than single ones, since they allow an easier tailoring of thermo…

Halfway up the trophic chain: development of parasite communities in the sparid fish Boops boops

2007

SUMMARYWe examined the patterns of composition and structure of parasite communities in the Mediterranean sparid fish Boops boops along a gradient of fish sizes, using a large sample from a single population. We tested the hypothesis that species forming the core of the bogue parasite fauna (i.e. species which have a wide geographical range and are responsible for recognizable community structure) appear early in the fish ontogeny. The sequential community development observed supported the prediction that core species appear in the fish population earlier than rare and stochastic species. There was also a strong correlation between the order of ‘arrival’ of the species and their overall pr…

On the Statistical Properties of the Capacity of Spatially Correlated Nakagami-M MIMO Channels

2008

This paper studies the statistical properties of the channel capacity of spatially correlated Nakagami-m multiple- input multiple-output (MIMO) channels. We have derived closed- form expressions for the probability density function (PDF), the cumulative distribution function (CDF), the level-crossing rate (LCR), and the average duration of fades (ADF) of the lower bound on the channel capacity. In order to study the impact of the spatial correlation on the channel capacity, the analysis of the statistical properties of the channel capacity is carried out for different receiver antenna spacings. It is observed that the antenna spacing has a significant influence on the spread and maximum val…

On the statistical properties of the capacity of sparse multipath fading channels

2014

Most existing works in wireless communications assume rich scattering. However, there is growing experimental evidence that physical wireless channels can exhibit a sparse structure. By assuming an asymmetric Doppler power spectral density (PSD), we can model and simulate sparse channels by using a finite sum of weighted complex harmonic functions, also called sum of cisoids (SOC). In this paper, we focus on the analysis of the statistical properties of the instantaneous capacity of sparse SOC-based multipath fading channels under line-of-sight (LOS) conditions. The probability density function (PDF), the cumulative distribution function (CDF), the level-crossing rate (LCR), and the average…

Statistical Analysis of the Channel Capacity Outage Intervals in Massive MIMO Systems with OSTBC over Rayleigh Fading Channels

2015

This paper studies approximate solutions for the statistical properties of the outage intervals of the instantaneous capacity in massive multiple- input multiple- output (MIMO) sys- tems with orthogonal space-time block code (OSTBC) over Rayleigh fading channels. We take advantage from the fact that the probability density function (PDF) of the channel power gain can be approximated by a left-truncated Gaussian distribution if the number of transmit and receive antennas is large. Assuming a symmetrical Doppler power spectral density (PSD), a closed- form expression is presented for the Rice probability function of the outage durations. This function, in general, approximates the PDF of the …

On the statistical properties of the capacity of amplify-and-forward channels under LOS conditions

2008

Amplify-and-forward channels in cooperative networks provide a promising improvement in the network coverage and system throughput. Under line-of-sight (LOS) propagation conditions in such cooperative networks, the overall fading channel can be modeled by a double Rice process. In this article, we have studied the statistical properties of the capacity of double Rice fading channels. We have derived the analytical expressions for the probability density function (PDF), cumulative distribution function (CDF), level-crossing rate (LCR), and average duration of fades (ADF) of the channel capacity. The obtained results are studied for different values of the amplitudes of the LOS components in …

A Method to Extract the Complete Fiber Network Topology of Planar Fibrous Tissues and Scaffolds

2010

Improving fabrication protocols and design strategies, investigating on how fibrous ECM and synthetic architectures affect cell morphology, metabolism and phenotypic expression, predicting mechanical behaviors, have increasingly become crucial goals in the understanding of native tissues and in the development of engineered tissue. In the present study, an image-based analysis approach that provides an automatic tool to fully characterize engineered tissue fiber network topology was developed. The following micro architectural features were detected: fiber angle distribution, fiber connectivity, fiber overlap spatial density, and fiber diameter. In order to demonstrate the potential of this…

New insights into the neolithisation process in southwest Europe according to spatial density analysis from calibrated radiocarbon dates

2017

The agricultural way of life spreads throughout Europe via two main routes: the Danube corridor and the Mediterranean basin. Current archaeological literature describes the arrival to the Western Mediterranean as a rapid process which involves both demic and cultural models, and in this regard, the dispersal movement has been investigated using mathematical models, where the key factors are time and space. In this work, we have created a compilation of all available radiocarbon dates for the whole of Iberia, in order to draw a chronological series of maps to illustrate temporal and spatial patterns in the neolithisation process. The maps were prepared by calculating the calibrated 14C date …

Assessment of image quality of intracoronary ultrasound systems with tissue-equivalent vessel phantoms

2002

Imaging of vascular structures by intracoronary ultrasound (ICUS) is finding more and more applications in coronary diagnosis and in the assessment of interventional access. The authors describe a method for easy and quick production of tissue-equivalent vessel phantoms from a special hydrocolloid. The mechanical tolerance is less than 3/100 mm. With these phantoms the authors tested the calibration and measured the resolution properties of the SONOS intravascular ultrasonic system (Hewlett Packard). The measurements revealed a slight space related underestimation of diameters up to 280 /spl mu/m. Using cross correlation and auto correlation functions the authors analyzed digitized ultrason…