Search results for "Diabatic"
showing 10 items of 303 documents
Kinetics of the formation reactions of trichloro- and tribromomethyl hypohalites and alcohols in the gas-phase: Theoretical study
2007
Abstract The CX3OY molecules (X = Cl, Br and Y = H, F, Cl, Br) can be formed in the atmosphere by the recombination CX3 + OY and CX3O + Y reactions. In the present study the results of a theoretical analysis of the kinetics and thermochemistry of this class of reactions are performed. The molecular properties of the reactants and products were derived from ab initio calculations. The high-pressure limiting rate constants for the recombination reactions were evaluated using a version of the statistical adiabatic channel model. The kinetic equations derived in this study allow a description of the kinetics of the reactions under investigation in the temperature range of 200–400 K.
Adiabatic evolution for systems with infinitely many eigenvalue crossings
1998
International audience; We formulate an adiabatic theorem adapted to models that present an instantaneous eigenvalue experiencing an infinite number of crossings with the rest of the spectrum. We give an upper bound on the leading correction terms with respect to the adiabatic limit. The result requires only differentiability of the considered projector, and some geometric hypothesis on the local behavior of the eigenvalues at the crossings.
High order accurate shock capturing schemes for two-component Richtmyer-Meshkov instabilities in compressible magnetohydrodynamics
2011
We design a conservative and entropy satisfying numerical scheme to perform numerical simulations of two component Richtmyer-Meshkov (RM) instabilities in compressible magnetohydrodynamics (MHD). We first formulate a conservative model of a two-component compressible MHD fluid ruled under two ideal gases with different adiabatic exponents. The formulation includes a level set function that allows to evolve the two components of the plasma in a conservative and consistent way. We present a set of examples including two-component Riemann problems and high Mach shock wave interactions with entropy contact waves that validate the high order accurate numerical scheme. We observe that turbulent r…
Radiative Shocks in Rotating Accretion Flows around Black Holes
2004
It is well known that the rotating inviscid accretion flows with adequate injection parameters around black holes could form shock waves close to the black holes, after the flow passes through the outer sonic point and can be virtually stopped by the centrifugal force. We examine numerically such shock waves in 1D and 2D accretion flows, taking account of cooling and heating of the gas and radiation transport. The numerical results show that the shock location shifts outward compared with that in the adiabatic solutions and that the more rarefied ambient density leads to the more outward shock location. In the 2D-flow, we find an intermediate frequency QPO behavior of the shock location as …
Post-adiabatic supernova remnants in an interstellar magnetic field: oblique shocks and non-uniform environment
2018
Monthly notices of the Royal Astronomical Society 479(3), 4253 - 4270 (2018). doi:10.1093/mnras/sty1750
Efficient polarization of high-angular-momentum systems
2016
We propose methods of optical pumping that are applicable to open, high-angular-momentum transitions in atoms and molecules, for which conventional optical pumping would lead to significant population loss. Instead of applying circularly polarized cw light, as in conventional optical pumping, we propose to use techniques for coherent population transfer (e.g., adiabatic fast passage) to arrange the atoms so as to increase the entropy removed from the system with each spontaneous decay from the upper state. This minimizes the number of spontaneous-emission events required to produce a stretched state, thus reducing the population loss due to decay to other states. To produce a stretched stat…
Quasi diabatic CASSCF state functions
2002
A new method to determine quasi diabatic (QD) CASSCF states is presented. The adiabatic states are subjected to a unitary transformation resulting from diagonalization of a state-selection operator. The latter is constructed from the overlap of the adiabatic states with a suitable set of reference states. The multi-state (MS) CASPT2 method is used to account for the dynamical correlation effects in an approach where the QD-CASSCF wave functions are used as reference states. The procedure is applied to avoided crossings in excited states of BeH, LiO and ozone. The advantages of the proposed formulation are discussed.
Detection of Geometric Phases in Superconducting Nanocircuits
2000
When a quantum mechanical system undergoes an adiabatic cyclic evolution it acquires a geometrical phase factor in addition to the dynamical one. This effect has been demonstrated in a variety of microscopic systems. Advances in nanotechnologies should enable the laws of quantum dynamics to be tested at the macroscopic level, by providing controllable artificial two-level systems (for example, in quantum dots and superconducting devices). Here we propose an experimental method to detect geometric phases in a superconducting device. The setup is a Josephson junction nanocircuit consisting of a superconducting electron box. We discuss how interferometry based on geometrical phases may be real…
EFFECT OF LOW-FREQUENCY NOISE ON ADIABATIC PASSAGE IN A SUPERCONDUCTING NANOCIRCUIT
2011
Recent experiments have demonstrated coherent phenomena in three-level systems based on superconducting nanocircuits. This opens the possibility to detect Stimulated Raman Adiabatic Passage (STIRAP) in artificial atoms. Low-fequency noise (often 1/f) is one of the main sources of decoherence in these systems, and we study its effect on the transfer efficiency. We propose a way to analyze low frequency fluctuations in terms of fictitious correlated fluctuations of external parameters. We discuss a specific implementation, namely the Quantronium setup of a Cooper-pair box, showing that optimizing the trade-off between efficient coupling and protection against noise may allow us to observe co…
Nonlocal pure spin current injection via quantum pumping and crossed Andreev reflection
2005
A pure spin current injector is proposed based on adiabatic pumping and crossed normal/Andreev reflection. The device consists of a three-terminal ferromagnet-superconductor-semiconductor system in which the injection of a pure spin current is into the semiconductor which is coupled to the superconductor within a coherence length away from the ferromagnet enabling the phenomena of crossed normal /Andreev reflection to operate. Quantum pumping is induced by adiabatically modulating two independent parameters of the ferromagnetic lead, namely the magnetization strength and the strength of coupling between the ferromagnet and the superconductor. The competition between the normal/Andreev refle…