Search results for "Diffraction"
showing 10 items of 1584 documents
Etude des propriétés de coordination de nouveaux ligands macrocycliques vis-à-vis de cations métalliques en vue de l'utilisation de leurs complexes p…
2011
Noninvasive medical imaging techniques such as single-photon emission computed tomography (SPECT) or positron emission tomography (PET), are valuable tools for the development and validation of new therapeutic molecules. That approach requires the conjugation of a radioactive source emitting either y-rays or positrons with a biological tracer (e.g. DOTATOC). Among the potentially useful radionuclides available, 111In3+ (SPECT), 64Cu2+, and 68Ga3+ (PET) have attracted increasing attention over the last years for medical applications. To minimize the in vivo release of the radioactive cation by transmetalation or transchelation with biological ligands, it is essential to trap selectively the …
Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties
2020
The control of ligand-field splitting in iron (II) complexes is critical to slow down the metal-to-ligand charge transfer (MLCT)-excited states deactivation pathways. The gap between the metal-centered states is maximal when the coordination sphere of the complex approaches an ideal octahedral geometry. Two new iron(II) complexes (C1 and C2), prepared from pyridylNHC and pyridylquinoline type ligands, respectively, have a near-perfect octahedral coordination of the metal. The photophysics of the complexes have been further investigated by means of ultrafast spectroscopy and TD-DFT modeling. For C1, it is shown that&mdash
Flash microwave synthesis and sintering of nanosized La0.75Sr0.25Cr0.93Ru0.07o3–δ for fuel cell application.
2009
International audience; Perovskite-oxide nanocrystals of La0.75Sr0.25Cr0.93Ru0.07O3–δ with a mean size around 10 nm were prepared by microwave flash synthesis. This reaction was performed in alcoholic solution using metallic salts, sodium ethoxide and microwave autoclave. The obtained powder was characterised after purification by energy dispersive X-ray analysis (EDX), X-ray powder diffraction (XRD), BET adsorption technique, photon correlation spectroscopy (PCS) and transmission electron microscopy (TEM). The results show that integrated perovskite-type phase and uniform particle size were obtained in the microwave treated samples. At last the synthesised powder was directly used in a sin…
Suppression of plasma contribution in femtosecond degenerate four-wave mixing (fs-DFWM) at high intensity
2007
Femtosecond degenerate four-wave mixing (fs-DFWM) experiments in CO2 exhibit a strong background due to plasma produced at high intensity (≥20 TW/cm2), when significant molecular alignment is likely to arise. This perturbing phenomenon renders the measurements of alignment very difficult. It is shown that the plasma contribution can be avoided by employing perpendicular polarizations for the two pump pulses. The effect is explained on the basis of the different diffraction angles between signals produced by molecular alignment and plasma. Copyright © 2007 John Wiley & Sons, Ltd.
Interface engineering for improved light transmittance through photonic crystal flat lenses
2010
In this paper, we present photonic crystal flat lenses with interfaces engineered to improve the light transmittance thanks to a broad angles impedance matching. The interface engineering consists in the realization of antireflection gratings on the edges of the lenses which are designed to reduce the propagative waves reflectivity over a wide range of incident angles. The fabricated structures were measured in optical near-field and a four times enhancement of the light transmission efficiency is reported.
Quasi-phase-matched third harmonic generation in optical fibers using refractive-index gratings
2011
International audience; The purpose of this work is to demonstrate the quasi-phase-matching of third harmonic generation process in optical fibers using refractive-index gratings. We compare conversion efficiency calculated with analytical coupled modes theory and numerical approach employing system of coupled generalized nonlinear Schrödinger equation. Moreover, we show that introducing the phase matching condition that takes into account the nonlinear contribution to propagation constants significantly increases the conversion efficiency by several orders of magnitude. Finally we optimize the grating constant to maximize conversion efficiency.
Temporal analogue of the Fresnel diffraction by a phase plate in linear and nonlinear optical fibers
2021
The analogy existing between spatial and temporal optics has motivated many studies to interpret spatial phenomena in the domain of ultrafast optics [1] . Indeed, dispersion and one-dimensional diffraction may share the same mathematical formalism. Temporal analogues of common optical systems have been proposed such as lenses, imaging systems, diffraction gratings, which opens up a whole range of new possibilities for ultrafast photonics.
Integrated low drive voltage electro-optic Bragg modulator using a, periodically poled lithium niobate
2017
Periodically poled lithium niobate (PPLN) is currently used for frequency conversions using quasi-phase-matching, thanks to its high nonlinear coefficients and mature poling process. PPLN can also be attractive for electro-optic (EO) applications. Several studies have been conducted on PPLN-based EO deflectors, and recent realizations have lower the required applied voltage under hundred volts [1]. Indeed, for practical EO applications drive voltages as low as 5 V are usually required. For this purpose, we use a recent technique to realize high-quality isolated crystalline film out of LN [2] to implement an EO Bragg deflector with a drive voltage below 10 V. In this work we present an effic…
Analysis of the Bloch mode spectra of surface polaritonic crystals in the weak and strong coupling regimes: grating-enhanced transmission at oblique …
2004
The Bloch mode spectrum of surface plasmon polaritons (SPPs) on a finite thickness metal film has been analyzed in the regimes of weak and strong coupling between SPP modes on the opposite film interfaces. The SPP mode dispersion and associated field distributions have been studied. The results have been applied to the description of the light transmission through thick and thin periodically structured metal films at oblique incidence. In contrast to normal incidence, all SPP Bloch modes on a grating structure participate in the resonant photon tunnelling leading to the transmission enhancement. However, at the angle of incidence corresponding to the crossing of different symmetry film SPP …
Low drive voltage electro-optic Bragg deflector using a periodically poled lithium niobate planar waveguide
2016
International audience; An electro-optic Bragg light deflector is demonstrated in a thinned, periodically poled lithium niobate planar waveguide confined between two silica layers on a silicon substrate. More than 97% of diffraction efficiency is obtained with an operating wavelength of 633 nm for the two orthogonal light polarizations with a drive voltage of about 5 V. The temporal electric drift and the response time of the component are also studied.