Search results for "Diffusion"
showing 10 items of 1615 documents
Molecular-dynamics simulation of a glassy polymer melt: Rouse model and cage effect
1999
We report results of molecular-dynamics simulations for a glassy polymer melt consisting of short, linear bead-spring chains. It was shown in previous work that this onset of the glassy slowing down is compatible with the predictions of the mode coupling theory. The physical process of `caging' of a monomer by its spatial neighbors leads to a distinct two step behavior in the particle mean square displacements. In this work we analyze the effects of this caging process on the Rouse description of the melt's dynamics. We show that the Rouse theory is applicable for length and time scales above the typical scales for the caging process. Futhermore, the monomer displacement is compared with si…
Indeterminacy relations in random dynamics
2007
We analyze various uncertainty measures for spatial diffusion processes. In this manifestly non-quantum setting, we focus on the existence issue of complementary pairs whose joint dispersion measure has strictly positive lower bound.
Density functional study of two-dimensionalHe4clusters
2005
Binding energies and density profiles of two-dimensional systems of liquid He-4 with different geometries are studied by means of a zero-range density functional adjusted to reproduce the line tension obtained in a previous diffusion Monte Carlo calculation (lambda_{DMC}=0.121 K/A). It is shown that this density functional provides accurate results for the binding energy of large clusters with a reasonable computational effort.
Heavy quark momentum diffusion coefficient in 3D gluon plasma
2020
We study the heavy-quark momentum diffusion coefficient in far from equilibrium gluon plasma in a self-similar regime using real-time lattice techniques. We use 3 methods for the extraction: an unequal time electric field 2-point correlator integrated over the time difference, a spectral reconstruction (SR) method based on the measured equal time electric field correlator and a kinetic theory (KT) formula. The time-evolution of the momentum diffusion coefficient extracted using all methods is consistent with an approximate $t^{\frac{-1}{2}}$ power law. We also study the extracted diffusion coefficient as a function of the upper limit of the time integration and observe that including the in…
The errant life of a heavy quark in the quark–gluon plasma
2011
In the high-temperature phase of QCD, the heavy-quark momentum diffusion constant determines, via a fluctuation–dissipation relation, how fast a heavy quark kinetically equilibrates. This transport coefficient can be extracted from thermal correlators via a Kubo formula. We present a lattice calculation of the relevant Euclidean correlators in the gluon plasma, based on a recent formulation of the problem in heavy-quark effective field theory (HQET). We find a ≈20% enhancement of the Euclidean correlator at maximal time separation as the temperature is lowered from 6Tc to 2Tc, pointing to stronger interactions at lower temperatures. At the same time, the correlator becomes flatter from 6Tc …
Mesoscopic gels at low agarose concentration: perturbation effects of ethanol
1997
Aqueous agarose solutions at low concentrations (0.5 g/liter) were temperature quenched below the spinodal line to form mutually disconnected mesoscopic gels. In the presence of 6% ethanol, these solutions, obtained by quenching at the same temperature depth as in pure water, appear much more fluid, as determined by probe diffusion experiments. We show by static and dynamic light scattering that this can be explained by the solvent-mediated effects of ethanol, leading to a globular shape of mesoscopic agarose gels, rather than to an extended rodlike structure observed in pure water. Our findings show the significant effects of solvent perturbations on particle condensation and, therefore, m…
A combined molecular dynamics and Monte Carlo study of the approach towards phase separation in colloid-polymer mixtures.
2011
A coarse-grained model for colloid-polymer mixtures is investigated where both colloids and polymer coils are represented as point-like particles interacting with spherically symmetric effective potentials. Colloid-colloid and colloid-polymer interactions are described by Weeks-Chandler-Andersen potentials, while the polymer-polymer interaction is very soft, of strength k(B)T/2 for maximum polymer-polymer overlap. This model can be efficiently simulated both by Monte Carlo and molecular dynamics methods, and its phase diagram closely resembles that of the well-known Asakura-Oosawa model. The static and dynamic properties of the model are presented for systems at critical colloid density, va…
Immunonephelometric determination of the apolipoprotein A-II.
1989
A fully mechanized immunonephelometric method is described for the rapid and specific determination of apolipoprotein A-II in serum. The method utilizes commercially available sheep antiserum against human apolipoprotein A-II. Nephelometry was performed with the Behring Nephelometer Analyzer (BNA). A single determination can be performed in 12 minutes, requiring 10 microliters sample volume. The measuring range is about 0.08 to 1.25 g/l apolipoprotein A-II. Precision is characterized by intra-assay coefficients of variation of 3.37%, 3.93% and 4.49% for apolipoprotein A-II concentrations of 1.22 g/l, 0.376 g/l and 0.185 g/l, and inter-assay coefficients of variation of 4.27% for an apolipop…
Diffusion of Oxygen in Thermally Grown Oxide Scales
2009
High temperature reactivity of materials under oxidizing atmospheres is based on the formation of protective oxide scales. The protectiveness is obtained when the thermally grown oxide scales are dense, continuous and adherent to the metallic substrates (even during thermal shocks); as a matter of fact, the growth of the scale has to be governed by diffusion of species across the growing scale. The diffusing species are coming from the substrate (metallic ions) and/or from the oxidizing atmosphere (oxygen ions). The understanding of growth mechanisms can be reached by making two stage oxidation experiments, using oxygen isotopes. The experiment consists in oxidizing first the metallic subst…
Numerical Determination of Intrinsic Diffusion in Fe-Cr-Al Systems
2010
The intrinsic diffusion coefficients in diffusion aluminide coatings based on Fe-30Cr were determined at 1000oC. The diffusion fluxes were given by the Nernst Planck formulae and the Darken method for multicomponent systems was applied. This paper summarizes some numerical results to determine the composition dependent diffusivities in Fe-Cr-Al systems. The method presented in this study to obtain average intrinsic diffusion coefficients is as an alternative to the Dayananda method. Our method based on empirical parameters allowed us to predict the concentration profile during the interdiffusion process.