Search results for "Diffusion"

Modeling of Growth and Dissolution of Nanotubular Titania in Fluoride-Containing Electrolytes

2009

In this paper, model calculations of diffusion processes and pH profiles inside TiO 2 nanotubes are performed in order to explore key factors in the growth mechanism of this system in aqueous electrolytes. An electrochemical steady state featured by an equivalent rate between oxide growth and dissolution is reached for a given current efficiency. Electrochemical oxide growth is found to be exclusively located at the pore bottom, whereas chemical oxide dissolution is uniformly distributed over the whole nanotube. It can be deduced from the results that electrolyte resistance or diffusion processes in the electrolyte inside the tubes are not limiting.

Sedimentation of halloysite nanotubes from different deposits in aqueous media at variable ionic strengths

2019

Abstract Halloysite clay is a natural nanomaterial that is attracting a growing interest in colloidal science. The halloysite aqueous dispersion stability is a key aspect for the configuration of a purification protocol as well as to establish the durability of a formulation. A physico-chemical study demonstrated the role of ionic strength and nanotube characteristic sizes on the sedimentation behavior. We highlighted the importance of the electrostatic repulsions exercised between the particles in the settling process. A protocol for image analysis has been proposed to provide robust information from time resolved optical images on the suspensions. In conclusion, we managed to correlate mi…

A direct comparison of 2D versus 3D diffusion analysis at nanowire electrodes: A finite element analysis and experimental study

2022

In electroanalysis, the benefits accrued by miniaturisation are a key driver in sensor development. Finite element simulations of electrochemical processes occurring at ultramicro- and nano-electrodes are used to provide key insight into experimental design in relation to diffusion profiles and expected currents. The most commonly used method, the diffusion domain approach (DDA) offers a means of reducing a three dimensional design to two dimensions to ease computational demands. However, the DDA approach can be limited when using basic assumptions which can be incorrect, for example that all electrodes in an array are equivalent. Consequently, to get a more realistic view of molecular diff…

Experimental Investigations on Hair Fibers as Diffusion Bridges and Opiates as Solutes in Solution

1996

Diffusion experiments were performed using clipped hair fibers as diffusion bridges and aqueous solutions of morphine, codeine and dihydrocodeine. Natural as well as predamaged hair fibers were investigated. The test series were conducted at ambient temperature and at high humidity. After 312 or 372 hours the middle segments of the strands were clipped, washed and analyzed by GC/MS. Only when virgin hair samples were used the solutes passed along the fiber at full length resulting in a positive immunological finding at the end of the diffusion bridge. Most of the washing fluids were positive for opiates. All centerpieces had a high opiate content. The opiate concentration in damaged hair wa…

Sbarchi

2021

During 2020, the Mediterranean Sea was again the testing ground for migration flows from North Africa and the Middle East to Italy, Greece and Spain. 2020 was also a complex year due to the spread of the COVID-19 pandemic. Movements between countries were affected by the spread of the virus that spared no one and imposed the need to reflect on 'global health' and the consequences that this has, also in the relationship between countries and in travel.

Local and nonlocal weighted pLaplacian evolution equations with Neumann boundary conditions

2011

In this paper we study existence and uniqueness of solutions to the local diffusion equation with Neumann boundary conditions and a bounded nonhomogeneous diffusion coefficient g ≥ 0, {ut = div (g|∇u|p-2∇u) in ]0; T[×Ωg|∇u|p-2u·n = 0 on ]0; T[×∂Ω; for 1 ≤ p < ∞. We show that a nonlocal counterpart of this diffusion problem is ut(t; x)= ∫ω J(x-y)g(x+y/2)|u(t; y)-u(t; x)| p-2 (u(t; y)-u(t; x)) dy in ]0; T[× Ω,where the diffusion coefficient has been reinterpreted by means of the values of g at the point x+y/2 in the integral operator. The fact that g ≥ 0 is allowed to vanish in a set of positive measure involves subtle difficulties, specially in the case p = 1.

A nonlocal p-Laplacian evolution equation with Neumann boundary conditions

2008

In this paper we study the nonlocal p-Laplacian type diffusion equation,ut (t, x) = under(∫, Ω) J (x - y) | u (t, y) - u (t, x) |p - 2 (u (t, y) - u (t, x)) d y . If p &gt; 1, this is the nonlocal analogous problem to the well-known local p-Laplacian evolution equation ut = div (| ∇ u |p - 2 ∇ u) with homogeneous Neumann boundary conditions. We prove existence and uniqueness of a strong solution, and if the kernel J is rescaled in an appropriate way, we show that the solutions to the corresponding nonlocal problems converge strongly in L∞ (0, T ; Lp (Ω)) to the solution of the p-Laplacian with homogeneous Neumann boundary conditions. The extreme case p = 1, that is, the nonlocal analogous t…

Functional relevance and diagnostic utility of ROI-based and voxel-based diffusion-tensor imaging analyses in mild cognitive impairment

2007

Dynamic nuclear polarisation of biological matter

1986

Polarised targets as used in high energy physics experiments may be of considerable interest in biological structure research using polarized neutrons. So far, this promising method has been facing difficulties in getting reasonable polarization of the target nuclei. We report on a polarized "frozen spin" target which has been prepared from an enzyme dissolved in a mixture of heavy water and deuterated propanediol doped with a completely deuterated paramagnetic radical. Clusters of 700 protons defined by the structure of lysozyme embedded in a fully deuterated matrix were polarized to 75% within an hour by 4 mm microwave irradiation in a magnetic field of 2.5 tesla at a temperature of 0.3 K…

Solubility and diffusion of nitrogen in maltodextrin/protein tablets.

2002

The gas transport properties of compacted tablets consisting of an amorphous mixture of maltodextrin and sodium caseinate were studied by dissolving nitrogen gas in the tablets and then determining the gas release over time as a function of temperature and water activity. Gas was dissolved in the tablet matrix by heating the tablets under pressure, generally to temperatures above the glass transition temperature of the matrix, holding them at these conditions for a specified time and then rapidly cooling them while maintaining the external pressure. The solubility of nitrogen was found to be largely determined by the free volume of the matrix, which in turn can be influenced to some degree …