Search results for "Diffusivity"

Moisture ingress in photovoltaic modules: A review

2021

Abstract Moisture ingress in photovoltaic (PV) modules is the core of most degradation mechanisms that lead to PV module power degradation. Moisture in EVA encapsulant can lead to metal grids corrosion, delamination and discolouration of encapsulants, potential induced degradation, optical and adhesion losses. The present work is a review of literature on the causes, effects, detection, and mitigation techniques of moisture ingress in PV modules. Literature highlights on determining the diffusivity, solubility, and permeability of polymeric components of PV modules via water vapour transmission rate tests, gravimetric, and immersion methods, have been presented. Electroluminescence, photolu…

Nanosecond thermo-optical dynamics of polymer loaded plasmonic waveguides

2013

The thermo-optical dynamics of polymer loaded surface plasmon waveguide (PLSPPW) based devices photo-thermally excited in the nanosecond regime is investigated. We demonstrate thermo-absorption of PLSPPW modes mediated by the temperature-dependent ohmic losses of the metal and the thermally controlled field distribution of the plasmon mode within the metal. For a PLSPPW excited by sub-nanosecond long pulses, we find that the thermo-absorption process leads to modulation depths up to 50% and features an activation time around 2ns whereas the relaxation time is around 800ns, four-fold smaller than the cooling time of the metal film itself. Next, we observe the photo-thermal activation of PLSP…

Dynamic Model Metallo‐Supramolecular Dual‐Network Hydrogels with Independently Tunable Network Crosslinks

2020

ESTIMATION OF INJECTION PRESSURE DURING MOLD FILLING.

1982

Dimensionless diagrams for estimating the bulk temperature of the flow front and injection pressure in the limit of small viscous generation are obtained. Also, a criterion for neglecting viscous generation is identified, The diagrams, based on the Lord and Williams model, refer to rectangular geometry and amorphous materials. A satisfactory comparison is obtained with literature data taken on polystyrene. A reasonable estimate of polyethylene injection pressure was obtained by roughly accounting for latent heat of crystallization through modified thermal diffusivity.

PET/PEN Blends of Industrial Interest as Barrier Materials. Part I. Many-Scale Molecular Modeling of PET/PEN Blends

2006

Mesoscale molecular simulations, based on parameters obtained through atomistic molecular dynamics and Monte Carlo calculations, have been used for modeling and predicting the behavior of PET/PEN blends. Different simulations have been performed in order to study and compare pure homopolymer blends with blends characterized by the presence of PET/PEN block copolymers acting as compatibilizer. A many-scale molecular modeling strategy was devised to evaluate PET/PEN blend characteristics, simulate phase segregation in pure PET/PEN blends, and demonstrate the improvement of miscibility due to the presence of the transesterification reaction products. The behavior of distribution densities and …

Assigning ionic properties in perovskite solar cells; a unifying transient simulation/experimental study

2021

Kinetic modelling has proven to be essential to understand the time and spatial dependence of charge carriers in solar cells. Traditional drift–diffusion simulations have generally been employed to describe static steady-state conditions, whereas recently the transient counterpart has been able to reveal more detailed information regarding carrier kinetics. In addition to customary electron and hole dynamics, perovskite materials are known to also be strongly affected by the displacement of lattice vacancies, charged atoms or even entire molecules. Such ionic motion transpires on vastly different time scales compared to free charges and are generally not straightforward to simultaneously ac…

Heterogeneous and Homogeneous Diffusivity in an Ion-Conducting Glass

1999

The nature of ion diffusivity in the vitreous conductor 2Ca NO3 2 ? 3KNO3 (CKN) was studied by nonresonant dielectric hole burning. Spectral holes in the electric field relaxation are probed subsequent to a high electric sinusoidal burn field. For sufficiently high pump frequencies we are able to induce spectrally selective modifications in the relaxation of the electric modulus, indicating that ionic diffusivity is a spatially varying quantity in glassy CKN. Homogeneous behavior occurs in the regime of low pump frequencies, in which the resistivity approaches its steady state value. Thus, longer-ranged ionic motions lead to a spatial averaging over the heterogeneity of local ion diffusivit…

Heat transport of helium II in restricted geometries

1979

The linear heat transport of helium II contained in porous powder samples with mean pore diameters of 1.25µm, 0.17µm and 0.02µm was systematically studied in the temperature range between 0.8 K and 2 K. The effective thermal conductivity was determined by steady-state heat flow measurements and the effective thermal diffusivity by transitory temperature measurements. The experimental results are interpreted by a simple theoretical model. In the framework of this model the linear heat transport consists of two contributions: the laminar flow of the normal fluid (T≳1.4 K) and a diffusion mechanism (T≲1.4 K). At low temperatures (T≲1.2 K) the mean free paths of the elementary excitations of he…

Xenon Recovery by DD3R Zeolite Membranes: Application in Anaesthetics.

2019

Xe is only produced by cryogenic distillation of air, and its availability is limited by the extremely low abundance. Therefore, Xe recovery after usage is the only way to guarantee sufficient supply and broad application. Herein we demonstrate DD3R zeolite as a benchmark membrane material for CO2 /Xe separation. The CO2 permeance after an optimized membrane synthesis is one order magnitude higher than for conventional membranes and is less susceptible to water vapour. The overall membrane performance is dominated by diffusivity selectivity of CO2 over Xe in DD3R zeolite membranes, whereby rigidity of the zeolite structure plays a key role. For relevant anaesthetic composition ( 320 h). Thi…

Estimation of the effective diffusivity of blowing agents in closed-cell low-density polyurethane foams based on thermal aging data

2021

Abstract Low-density closed-cell polyurethane (PU) foams are applied as thermal insulation materials due to their low thermal conductivity imparted by that of the physical blowing agent (PBA) used in foam production. However, foam conductivity tends to gradually increase with time, primarily due to changes in the gas composition in foam cells brought about by gas diffusion. To enable predicting the variation of conductivity during the service life of foam insulation, gas diffusivities are usually determined by measuring the gas composition in foams at different aging times. This study considers an alternative approach of estimating the effective diffusivities of gases in PU foams, which is …