Search results for "Dimension"

showing 10 items of 2766 documents

Correlating Solution‐ and Solid‐State Structures of Conformationally Flexible Resorcinarenes: Significance of a Sulfonyl Group in Intramolecular Self…

2020

Abstract The synthesis of tetramethoxyresorcinarene podands bearing p‐toluene arms connected by ‐SO3‐ (1) and ‐CH2O‐ (2) linkers is presented herein. In the solid state, the resorcinarene podand 1 forms an intramolecular self‐inclusion complex with the pendant p‐toluene group of a podand arm, whereas the resorcinarene podand 2 does not show self‐inclusion. The conformations of the flexible resorcinarene podands in solution were investigated by variable‐temperature experiments using 1D and 2D NMR spectroscopic techniques as well as by computational methods, including a conformational search and subsequent DFT optimisation of representative structures. The 1H NMR spectra of 1 and 2 at room te…

Supramolecular chemistryself-inclusionCrystal structure010402 general chemistry01 natural sciencessupramolecular chemistryCatalysissupramolekulaarinen kemiasolution structuresMoleculesolution structureX-ray crystallographySulfonylchemistry.chemical_classificationresorcinareneFull PaperResorcinarenes010405 organic chemistryChemistryinclusion compoundsOrganic ChemistryGeneral ChemistryFull PapersResorcinareneX-ray diffraction0104 chemical sciencesCrystallographyIntramolecular forceProton NMRTwo-dimensional nuclear magnetic resonance spectroscopyröntgenkristallografiaChemistry – A European Journal
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Multiscale analyses and characterizations of surface topographies

2018

International audience; This work studies multiscale analyses and characterizations of surface topographies from the engineering and scientific literature with an emphasis on production engineering research and design. It highlights methods that provide strong correlations between topographies and performance or topographies and processes, and methods that can confidently discriminate topographies that were processed or that perform differently. These methods have commonalities in geometric characterizations at certain scales, which are observable with statistics and measurements. It also develops a semantic and theoretical framework and proposes a new system for organizing and designating …

Surface (mathematics)0209 industrial biotechnologyComputed-TomographyComputer scienceArea Structure-FunctionComputed tomography02 engineering and technologyWavelet Transformcomputer.software_genreMetrologyIndustrial and Manufacturing Engineering[SPI]Engineering Sciences [physics]020901 industrial engineering & automationmedicineProduction engineeringDimensional MetrologyQuantitative-AnalysisPhysics::Atmospheric and Oceanic Physicsmedicine.diagnostic_testRough SurfacesMechanical EngineeringFractal Analysis021001 nanoscience & nanotechnologyEngineering SurfacesFractal analysisRoughnessSurfaceMetrology; Roughness; Surface; Mechanical Engineering; Industrial and Manufacturing EngineeringData miningUbm Laser Profilometry0210 nano-technologyDental Microwear Texturecomputer
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Hybrid approach to surface roughness evaluation in multistage machining processes

2003

Abstract An assessment of surface quality in turned, ground and honed specimens is made by means of a computer-based processing of digitised surface profiles. Three different methods of surface finish characterisation, i.e. statistical, fractal and neural network-based approaches are examined and compared. Correlations between some representative roughness parameters and the fractal dimension (D) values estimated were found. Consequently, they can be converted to their corresponding roughness parameters, i.e. Ra, Rz and RΔa. Finally, a set of parameters including the minimum surface finish data for machining of external cylindrical surfaces when using complex technological process, is propo…

Surface (mathematics)EngineeringArtificial neural networkbusiness.industryMetals and AlloysProcess (computing)Mechanical engineeringSurface finishFractal dimensionIndustrial and Manufacturing EngineeringComputer Science ApplicationsFractalMachiningModeling and SimulationCeramics and CompositesElectronic engineeringSurface roughnessbusinessJournal of Materials Processing Technology
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Principal configurations and umbilicity of submanifolds in $\mathbb R^N$

2004

We consider the principal configurations associated to smooth vector fields $\nu$ normal to a manifold $M$ immersed into a euclidean space and give conditions on the number of principal directions shared by a set of $k$ normal vector fields in order to guaranty the umbilicity of $M$ with respect to some normal field $\nu$. Provided that the umbilic curvature is constant, this will imply that $M$ is hyperspherical. We deduce some results concerning binormal fields and asymptotic directions for manifolds of codimension 2. Moreover, in the case of a surface $M$ in $\mathbb R^N$, we conclude that if $N>4$, it is always possible to find some normal field with respect to which $M$ is umbilic and …

Surface (mathematics)Euclidean spaceGeneral MathematicsMathematical analysisOrder (ring theory)Vector fieldMathematics::Differential GeometryCodimensionCurvatureNormalManifoldMathematicsBulletin of the Belgian Mathematical Society - Simon Stevin
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Vassiliev invariants for braids on surfaces

2000

We show that Vassiliev invariants separate braids on a closed oriented surface, and we exhibit an universal Vassiliev invariant for these braids in terms of chord diagrams labeled by elements of the fundamental group of the considered surface.

Surface (mathematics)Fundamental groupLow-dimensional topologyGeneral MathematicsBraid groupGroup Theory (math.GR)braidMathematics::Algebraic TopologyCombinatoricsMathematics - Geometric TopologyMathematics::Group TheoryMathematics::Category TheoryMathematics::Quantum Algebra20F36 (Primary) 57M2757N05 (Secondary)BraidFOS: MathematicssurfaceMathematicsApplied MathematicsGeometric Topology (math.GT)Mathematics::Geometric TopologyFinite type invariantVassiliev Invariantfinite type invariantIsomorphismMathematics - Group TheoryGroup theory
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Deducing a Drain Spacing Formula by Applying Dimensional Analysis and Self-Similarity Theory

2016

For designing a steady state drainage system a drain flow formula coupled with the Dupuit-Forcheimer form of the differential equation of groundwater flow is used. At first, in this paper the most applied drain flow formulas in steady-state conditions are reviewed and compared using as dependent variable the ratio between the maximum water table height and the distance between two lines of parallel drains. These equation are also tested using experimental field data measured in three plot drained by surface pipe drains having different value of drain spacing. Then, applying the dimensional analysis and the self-similarity theory, a new drain spacing formula is theoretically deduced and comp…

Surface (mathematics)Groundwater flowSelf-similarityDifferential equationField data0208 environmental biotechnologyGeometryDrains Drain spacing formula dimensional analysis self-similarity04 agricultural and veterinary sciences02 engineering and technologyCondensed Matter::Mesoscopic Systems and Quantum Hall EffectAgricultural and Biological Sciences (miscellaneous)020801 environmental engineeringFlow (mathematics)040103 agronomy & agricultureSettore AGR/08 - Idraulica Agraria E Sistemazioni Idraulico-Forestali0401 agriculture forestry and fisheriesWater Science and TechnologyCivil and Structural EngineeringMathematicsJournal of Irrigation and Drainage Engineering
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Study on Interfacial Surface in Modified Spray Tower

2019

This paper presents an analysis of the changes in interfacial surface and the size of droplets formed in a spray tower. The interfacial surface and the size of droplets formed are of fundamental importance to the performance of the equipment, both in terms of pressure drop and process efficiency. Liquid film and droplet sizes were measured using a microphotography technique. The confusors studied were classical, with profiled inside surface, and with double profiled inside surface. The liquids studied were water and aqueous solutions of high-molecular polyacrylamide (PAA) of power-law characteristics. The ranges of process Reynolds number studied were as follows: ReG &isin

Surface (mathematics)Materials science020209 energyPolyacrylamideBioengineering02 engineering and technologylcsh:Chemical technologyconfusorlcsh:ChemistryPhysics::Fluid Dynamicschemistry.chemical_compoundsymbols.namesake020401 chemical engineering0202 electrical engineering electronic engineering information engineeringChemical Engineering (miscellaneous)lcsh:TP1-11850204 chemical engineeringComposite materialinterfacial surfacePressure dropAqueous solutionProcess Chemistry and TechnologySauter mean diameterReynolds numberSauter mean diameterlcsh:QD1-999chemistrymodified spray towerSpray towersymbolsDimensionless quantityProcesses
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MESH COMPARISON USING ATTRIBUTE DEVIATION METRIC

2004

We propose a mesh comparison method using a new attribute deviation metric. The considered meshes contain geometrical and appearance attributes (material color, texture, temperature, etc.). The proposed deviation metric computes local differences between the attributes of two meshes. A mesh comparison assessment can be done easily and quickly using this metric. The techniques proposed are applicable in a number of ways, e.g. 3D matching and registration, and the example described in the paper is the simplification of a surface by iteratively reducing its complexity according to an error metric. The results are presented showing the success of the algorithm through comparisons with other me…

Surface (mathematics)Mathematical optimizationMetric (mathematics)3-dimensional matchingPolygon meshComputer Vision and Pattern RecognitionTexture (music)Computer Graphics and Computer-Aided DesignAlgorithmComputingMethodologies_COMPUTERGRAPHICSComputer Science ApplicationsMathematicsInternational Journal of Image and Graphics
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Vectorized ‘‘TOPO’’ Program for the Theoretical Simulation of Molecular Shape

1991

The TOPO program for theoretical simulation of molecular shape is presented here. Molecular shape is characterized by a set of electrostatic and geometrical descriptors and topological indices including the fractal dimension of the accessible surface. An atom-atom analysis of all descriptors has been implemented. The program has been adapted for the realization of high-performance computing. Results are reported for porphine and phthalocyanine molecules.

Surface (mathematics)PhysicsMolecular modelbusiness.industryComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISIONElectrostaticsBiochemistryFractal dimensionSet (abstract data type)FractalArtificial intelligenceBiological systembusinessRealization (systems)Topology (chemistry)ComputingMethodologies_COMPUTERGRAPHICSAIP Conference Proceedings
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Critical behavior of the surface-layer magnetization at the extraordinary transition in the three-dimensional Ising model.

1990

We have used a vectorized multispin-coding Monte Carlo method to determine the behavior of the surface-layer magnetization ${\mathit{m}}_{1}$ at the bulk transition in a simple-cubic Ising film with strongly enhanced surface coupling, i.e., at the extraordinary transition. In contrast to recent renormalization-group calculations we find no evidence for a discontinuous slope in the temperature dependence of ${\mathit{m}}_{1}$; the data are consistent with a free-energy-like (T-${\mathit{T}}_{\mathit{c}}$${)}^{2\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\alpha}}}$ behavior plus background terms.

Surface (mathematics)PhysicsStatistics::TheoryMagnetizationStatistics::ApplicationsCondensed matter physicsExchange interactionMonte Carlo methodIsing modelSurface layerCoupling (probability)Three dimensional modelPhysical review. B, Condensed matter
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