Search results for "Diss"

Re: Technique of internal mammary dissection using pectoralis major flap to prevent contour deformities

2009

Batch-to-Melt Conversion Kinetics in Sodium Aluminosilicate Batches Using Different Alumina Raw Materials

2016

The batch-to-melt conversion in batches of sand, soda ash and corundum (C), alumina spinel (A), boehmite (B), or gibbsite (G) as Al2O3 carrier are studied using thermal analysis, X-ray diffraction, and 27Al nuclear magnetic resonance spectroscopy. Laboratory-scaled batches are either heated continuously or quenched from 1600°C in a series of increasing dwell times. The results show that the conversion from the raw materials to the fresh melt proceeds in two kinetic stages. During the first stage (3–5 min), fast conversion of nearly 95% by mass occurs and the conversion coefficient increases in the order G < C ≈ A < B. The second stage is controlled by the slow dissolution of intermediate cr…

Modeling self-sustaining waves of exothermic dissolution in nanometric Ni-Al multilayers

2016

Abstract The self-sustained propagating reaction occurring in nanometric metallic multilayers was studied by means of molecular dynamics (MD) and numerical modeling. We focused on the phenomenon of the exothermic dissolution of one metallic reactant into the less refractory one, such as Ni into liquid Al. The exothermic character is directly related to a negative enthalpy of mixing. An analytical model based on the diffusion-limited dissolution [1] coupled with heat transfer was derived to account for the main aspects of the process. Together, several microscopic simulations were carried out. The first series were set up to obtain all the parameters governing the process, including the heat…

Experimental and numerical investigation on a new FSW based metal to composite joining technique

2018

Abstract In the last decades, different techniques were proposed to join aluminum sheets with composites materials. Each of them has advantages and weak points over the others and new techniques and patents are continuously developed to overcome these difficulties. In this paper an experimental and numerical investigation on a new Friction Stir Welding based approach to mechanically join AA6082-T6 to self-reinforced polypropylene is presented. The aluminum sheet is pre-holed along both the sides of the weld line and a pinless tool generates the heat and pressure needed to prompt back-extrusion of the composite. New experimental fixtures and hole designs were investigated in order to enhance…

Study of the multipactor phenomenon using a full-wave integral equation technique

2017

Abstract Multipactor effect is a well-known phenomenon of RF breakdown in satellite payloads which degrades components, generates undesirable harmonics, contributes to power dissipation and increases noise in communications. Traditionally, multipactor has been investigated with the aim of obtaining the so-called multipactor threshold voltage, or to present different multipaction detection methods. However, very little attention has been focused on analysing this phenomenon using a multimodal approach. The main goal of this work is to analyse the interaction between a multipactor current and a realistic microwave cavity by means of a rigorous and accurate formulation. For the first time to t…

A comparative study on the compatibility of liquid lead–gold eutectic and liquid lead–bismuth eutectic with T91 and SS 316LN steels

2012

Abstract Liquid lead–gold eutectic (LGE) is considered as a potential target material for high power spallation sources. In the present work, the corrosion effects of LGE on T91 and SS 316LN steels have been investigated in comparison with that of liquid lead–bismuth eutectic (LBE) under the same testing conditions. Two tests were conducted at 400 °C for 1800 h and at 450 °C for 1300 h, in which specimens of the two steels were exposed to 1 m/s flowing LGE and LBE. Surface inspections showed that the specimens underwent a mixed corrosion mode of dissolution and oxidation. The results obtained from the SS 316LN specimens are very interesting. Firstly, EDX (electron energy dispersion X-ray sp…

Multiphysical Modeling of Transport Phenomena During Laser Welding of Dissimilar Steels

2016

Abstract The success of new high-strength steels allows attaining equivalent performances with lower thicknesses and significant weight reduction. The welding of new couples of steel grades requires development and control of joining processes. Thanks to high precision and good flexibility, laser welding became one of the most used processes for joining of dissimilar welded blanks. The prediction of the local chemical composition in the weld formed between dissimilar steels in function of the welding parameters is essential because the dilution rate and the distribution of alloying elements in the melted zone determines the final tensile strength of the weld. The goal of the present study i…

Ab initio multi-reference perturbation theory calculations of the ground and low-lying electronic states of the KRb molecule

2016

The potential energy curves of the low-lying electronic states correlating up to the limit K(4p) + Rb(5s) of KRb molecule have been calculated using the multi-reference perturbation theory method at the CASSCF/ XMCQDPT2 level of theory without and with spin–orbit coupling. The calculated parameters of the ground X 1 R + state are in the best agreement among all previously performed ab initio calculations for the KRb molecule. The calculated vibrational intervals of the ground electronic term of the 39 K 85 Rb molecule describe the experiment with the accuracy within ±1 cm ?1 . The calculated intensities of the 2 1 R + (v 0 = 3, J 0 = 26) ? X 1 R + (v 00 = 0...24, J 00 = 25, 27) transitions …

On the N1-H and N3-H Bond Dissociation in Uracil by Low Energy Electrons: A CASSCF/CASPT2 Study.

2015

The dissociative electron-attachment (DEA) phenomena at the N1-H and N3-H bonds observed experimentally at low energies (<3 eV) in uracil are studied with the CASSCF/CASPT2 methodology. Two valence-bound π(-) and two dissociative σ(-) states of the uracil anionic species, together with the ground state of the neutral molecule, are proven to contribute to the shapes appearing in the experimental DEA cross sections. Conical intersections (CI) between the π(-) and σ(-) are established as the structures which activate the DEA processes. The N1-H and N3-H DEA mechanisms in uracil are described, and experimental observations are interpreted on the basis of two factors: (1) the relative energy of …

Hexacarbonyls of Mo, W, and Sg: Metal–CO Bonding Revisited

2017

Calculations of the first bond dissociation energies (FBDEs) and other molecular properties of M(CO)6, where M = Mo, W, and Sg, have been performed using a variety of nonrelativistic and relativistic methods, such as ZORA-DFT, X2c+AMFI-CCSD(T), and Dirac–Coulomb density functional theory. The aim of the study is to assist experiments on the measurements of the FBDE of Sg(CO)6. We have found that, different from the results published earlier, the metal–CO bond in Sg(CO)6 should be weaker than that in W(CO)6. A comparison of the relativistic and nonrelativistic FBDE values, as well as molecular orbital and vibrational frequency analyses within both the nonrelativistic and relativistic approac…